Toxic metals in the atmosphere in Lahore, Pakistan

Aerosol mass (PM₁₀ and PM_2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m^− 3), Zn (12 μg m^− 3), Cd (0.077 μg m^− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM_2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM₁₀ mass concentration was 340 μg m^− 3, which is well above the WHO guideline of 20 μg m^− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM₁₀ mass and 14% (29%) of PM_2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM₁₀. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment.     

Microanalysis of anionic surfactants in waste water by infrared spectroscopy

Infrared spectroscopy was applied to identify and determine microamounts of anionic surfactants contained in sewage or river waters. The surfactants tested were linear alkylbenzene sulfonate (LAS), branched alkylbenzene sulfonate (ABS), alpha olefine sulfonate (AOS), fatty alcohol sulfate (AS) and fatty alcohol ethoxy sulfate (AES).Anionic surfactants in waters were extracted by chloroform as methylene blue complexes and sulfate type surfactants, i.e. AS and AES were then removed by subsequent hydrolysis. Residual sulfonate type surfactants were first released from methylene blue complexes by ion exchange technique and then changed to sulfonyl chloride derivatives for infrared spectroscopy. Key bands for the identification of sulfonate type surfactants are 640, 618 and 524 cm⁻¹ for LAS, ABS and AOS, respectively. Sulfate type surfactants was calculated from the difference of methylene blue active substance contents before and after hydrolysis.     

Impact wave propagation in tall buildings using advanced spectral element method

One of the major divisions in analysis and design of tall buildings is to account for forces induced by flying‐object impact and the subsequent progressive collapse. During the past three decades, problems of contact mechanics have been considered by some authors, and special attention has been devoted to high‐speed impact. Impact wave propagation in tall buildings may be analysed using the conventional finite element method. However, in order to guarantee stability and accuracy of the solution, the number of elements used to model the structure may be very large indeed; more precisely, accurate results can be obtained after a substantial computational effort. In this respect, an improved complex spectral element method is developed for analysing the wave propagation problems in large structures. The purpose of this paper is to obtain the resulting dynamic responses of a tall building induced by a high‐speed impact of a flying object. Copyright © 2003 John Wiley & Sons, Ltd.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...     

Thermorheological model of a frozen-soil continuum

A method of evaluating the stress-strain state of frozen soils, which takes into account the existence of elastoviscoplastic and temperature deformations over time under variable external effects, is described. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 10–13, July–August, 1997.     

Long-term geophysical observations on the inguri dam rock foundation

Bulletin of Engineering Geology and the Environment - It has been found that during construction of the dam, prior to the filling of the reservoir, compaction and loading of the rocks under the...     

Experience with algal blooms and the removal of phosphorus from sewage

The growth of algae and occurrence of algal “blooms” in a number of different waters are described.They cover the period 1930–1940 when only natural phosphates would be present.The waters were drawn from either protected catchments or from a fully treated domestic supply.Spasmotic blooms in a fully treated domestic supply suggest that the mechanism which “triggers” the start of an algal bloom may be neither nutrient concentration nor the concentration of organic matter.It is considered that the pH, alkalinity, carbon dioxide equilibrium condition is a major factor, not only in promoting, but also in maintaining algal blooms.     

Earthquake analysis of isotropic asymmetric multistory buildings

Isotropic multistory buildings are the ones characterized by the property: all load‐resisting planar frames have proportional lateral stiffness matrices. In the present paper it is proved that the modal analysis of an N‐story isotropic asymmetric, torsionally coupled, building (a problem of order 3N) can be separated into two independent sub‐problems: (a) a sub‐problem that corresponds to a single‐story asymmetric, torsionally coupled, building (a problem of order 3); and (b) a sub‐problem that corresponds to an N‐story, torsionally uncoupled, planar frame (a problem of order N). It is also demonstrated that the orientation of peak modal seismic forces of the building is independent of the orientation of seismic excitation, which affects only their size. The separation provides a better insight into the structural behavior of asymmetric multistory buildings under earthquake ground motion. Copyright © 2006 John Wiley & Sons, Ltd.     

Experimental studies on the weatherability of the capivara dam basalts,rio paranapanema,brazil

The weatherability of the basalts in the Capivara Dam site, Rio Paranapanema, São Paulo State, Brazil, has been studied by means of saturation-drying tests. A great number of samples have disaggre — gated intensively with production of fines. The behavior of these rocks is related to their petrography, especially to their content in expansive clay minerals. These studies were performed in order to obtain data for the utilization of this material as rock fill, including ripraps.