Preparation and characterisation of new-polyaluminum chloride-chitosan composite coagulant

In this study, the formulation of a novel polyaluminum chloride-chitosan composite coagulant that improves the coagulation process for natural organic matter (NOM) removal was investigated. The performance of the composite coagulant was tested using two water sources (synthetic and natural water) to develop a better understanding on the behaviour of the composite coagulant. Fourier Transform-Infra red (FT-IR) spectroscopy, ferron analysis and zeta potential studies were performed to characterise the composite coagulant. FT-IR analysis showed that there is an intermolecular interaction between Al species and chitosan molecules, while ferron analysis indicated that the distributions of Al_a, Al_b, and Al_c in PACl-chitosan are different from those in PACl. At a low Al dosage (2.16 mg L⁻¹), a much higher removal of NOM from synthetic water, as evidenced from UV₂₅₄ and Dissolved Organic Carbon (DOC) measurements, was achieved by the composite coagulants in comparison to that removed by PACl or PACl and chitosan added separately. For natural water from the Myponga Reservoir, both polyaluminum chloride (PACl) and PACl-chitosan composite coagulants demonstrated similar dissolved organic carbon (DOC) percentage removal, whereas PACl-chitosan gave a slight improvement in removing the UV₂₅₄ absorbing components of NOM.     

Escherichia coli, enterococci, and Bacteroides thetaiotaomicron qPCR signals through wastewater and septage treatment

Fecal indicators such as Escherichia coli and enterococci are used as regulatory tools to monitor water with 24 h cultivation techniques for possible input of sewage or feces and presence of potential enteric pathogens yet their source (human or animal) cannot be determined with routine methods. This critical uncertainty has furthered water pollution science toward new molecular approaches. Members of Bacteroides genus, such as Bacteroides thetaiotaomicron are found to have features that allow their use as alternative fecal indicators and for Microbial Source Tracking (MST). The overall aim of this study was to evaluate the concentration and fate of B. thetaiotaomicron, throughout a wastewater treatment facility and septage treatment facility. A large number of samples were collected and tested for E. coli and enterococci by both cultivation and qPCR assays. B. thetaiotaomicron qPCR equivalent cells (mean: 1.8 × 10⁷/100 mL) were present in significantly higher concentrations than E. coli or enterococci in raw sewage and at the same levels in raw septage. The removal of B. thetaiotaomicron target qPCR signals was similar to E. coli and enterococci DNA during the treatment of these wastes and ranged from 3 to 5 log₁₀ for wastewater and was 7 log₁₀ for the septage. A significant correlation was found between B. thetaiotaomicron marker and each of the conventional indicators throughout the waste treatment process for both raw sewage and septage. A greater variability was found with enterococci when compared to E. coli, and CFU and equivalent cells could be contrasted by various treatment processes to examine removal and inactivation via septage and wastewater treatment. These results are compared and contrasted with other qPCR studies and other targets in wastewater samples providing a view of DNA targets in such environments.     

An Assessment of Water Demand Management Options from a Systems Approach

A systems approach is used to model the urban water and wastewater system. Scenarios are developed for the implementation of a range of water demand management measures, including (a) leakage reduction, (b) the increasing use of water metering, (c) the replacement of standard WCs by low-flow WCs, and (d) the introduction of greywater recycling systems. These measures are assessed according to the water saving, cost per unit of water saved, and other indicators of the relative contribution to the sustainability of the system. Preliminary assessments of selected environmental costs and benefits are also included.     

Discharge rate capabilities of alkaline AgCuO2 electrode

A series of AgCuO₂ samples are prepared and tested as alkaline cathode materials for primary batteries. AgCuO₂ discharges via four equivalent-charge reduction processes, the rate capabilities of which are determined. At ambient temperature AgCuO₂ displays superior rate capabilities for the two highest voltage processes. For all samples, the rate capability of the two lower voltage processes is always superior to those at higher voltage. This is due to the electrode intrinsically doping itself with elemental silver during discharge as part of the second reduction process. The electrode compares favourably with commercial electrolytic manganese dioxide but is prone to self-discharge, the kinetics of which are also discussed.     

A Look-Up-Based Universal Real-Time Transformer for Image Coding

A universal transformer for two-dimensional separable linear transforms in image coding is proposed. It is not restricted to fast transforms, and switching between transforms only requires writing the appropriate constants into an internal RAM. Look-up tables are used to reduce computational complexity. The linear transform properties are exploited to reduce the memory requirements by decomposing the input vector into smaller arrays and into bit planes. The input is pipelined into parallel data paths. An implementation example on a single gate array with existing technology achieves real-time transformation of 8 × 8 blocks, with area requirements of around 38K gates.     

High temperature /spl pi//2-SQUID

A new DC-SQUID is proposed that exploits the properties of the grain boundary junctions in high T/sub c/ superconductors. The orientations of the grain boundaries are chosen in such a way to establish a /spl pi//2 (rather than 0 or /spl pi/) phase difference between the equilibrium phases of the two Josephson junctions in the SQUID loop. This property is exploited to increase the sensitivity and direction dependence of the SQUID for measuring magnetic flux without additional flux generating coils.     

MRI demonstration of impairment of the blood-CSF barrier by glucose administration to the thiamin-deficient rat brain

Contrast-enhanced T1-weighted spin-echo magnetic resonance imaging (MRI) has demonstrated that Gd-diethylenetriaminepentaacetate (Gd-DTPA), which normally does not cross the blood-brain or blood-CSF barriers, does so approximately 40 min after administration of glucose to a vitamin B1 deficient rat. The period of the onset of this blood-CSF or blood-brain barrier dysfunction coincides with our previous observations of accumulation of glutamate or glutamate derivatives following an equivalent glucose load under identical conditions of thiamin deficiency, consistent with a relationship between these two observations. The dysfunction was reversed when a thiamin deficient animal was made thiamin replete.