Poly(dithiophosphate)s,a New Class of Phosphorus- and Sulfur-Containing Functional Polymers by a Catalyst-Free Facile Reaction between Diols and Phosphorus Pentasulfide

Novel poly(dithiophosphate)s (PDTPs) were successfully synthesized under mild conditions without any additive in the presence of THF or toluene diluents at 60 °C by a direct, catalyst-free reaction between the abundant phosphorus pentasulfide (P₄S₁₀) and glycols such as ethylene glycol (EG), 1,6-hexanediol (HD) and poly(ethylene glycol) (PEG). GPC, FTIR, ¹H and ³¹P NMR analyses proved the formation of macromolecules with dithiophosphate coupling groups having P=S and P-SH pendant functionalities. Surprisingly, the ring-opening of THF by the P-SH group and its pendant incorporation as a branching point occur during polymerization. This process is absent with toluene, providing conditions to obtain linear chains. ³¹P NMR measurements indicate long-time partial hydrolysis and esterification, resulting in the formation of a thiophosphoric acid moiety and branching points. Copolymerization, i.e., using mixtures of EG or HD with PEG, results in polymers with broadly varying viscoelastic properties. TGA shows the lower thermal stability of PDTPs than that of PEG due to the relatively low thermal stability of the P-O-C moieties. The low T_gs of these polymers, from −4 to −50 °C, and a lack of PEG crystallites were found by DSC. This polymerization process and the resulting novel PDTPs enable various new routes for polymer synthesis and application possibilities.     

基于目标极化特性的人体隐藏危险品检测方法

为解决在站开式距离的人体隐藏危险品检测问题,利用目标对雷达回波的退极化现象实现对枪支等金属物的远距离检测。通过测量待测对象的雷达的不同极化方向的回波并计算出检测参量,就可以据此判断待测对象是否携带有隐藏危险品。为验证该方法有效性,设计并研制了一套140 GHz宽带极化雷达,并进行了实验测量。实验结果表明：一方面,对于枪支,或者简易爆炸物等退极化效应显著的目标,系统具有较好的检测效果;另一方面,对于退极化效应不明显的目标的检测以及检测距离的增加会导致系统的虚警和漏警概率增大, 从而降低检测性能。 通过增大发射天线尺寸可以改善检测效果,并且通过检测参量的优化可以提高同等距离下检测性能。     

发挥资源优势,坚持循环经济,以高新技术打造西部大型氯碱基地

介绍了新疆天业(集团)有限公司利用资源丰富、地理位置独特等优势和国家政策的支持,按循环经济的发展理念,采用先进技术,建设大型氯碱生产基地的情况。     

电渣重熔高温合金渣系对冶金质量的影响

为控制Incoloy825合金中的Al、Ti含量,并减少电渣过程中氟化物的挥发。借助FactSage热力学软件,建立渣−金反应的热力学模型。设计出适宜控制Al、Ti含量的低氟渣系,探究了渣中组元与Al₂O₃和TiO₂活度比的关系,并通过高温渣–金平衡实验进行验证。结果表明：当渣中CaO和Al₂O₃含量增加,导致2O₃ and TiO₂ was studied, the result was verified by a high-temperature slag metal equilibrium experiment. The results show that the CaO and Al₂O₃ contents in slag increases with increase in the 相似文献   

响应面优化重组牛排加工工艺

实验在研究分析牛肥膘比例、天然海藻酸钠添加量和凝胶时间对重组牛排蒸煮损失率及硬度影响的基础上,以重组牛排蒸煮损失率和硬度的综合评价为优化指标,采用响应面法对工艺条件进行优化。单因素实验方差分析结果表明,三个因素对重组牛排蒸煮损失率及硬度都有极显著影响(p<0.05)。通过拟合模型优化,最佳工艺条件为:牛肥膘比例20%、海藻酸钠比例2.36%、凝胶时间8.75 h。在此工艺条件下,牛排的蒸煮损失率23.81%,硬度9.95 kg,综合评价为81.734。此时重组牛排产品保水性明显增强,硬度显著降低,该研究结果为重组牛排加工工艺提供参考依据。      

一类具高阶非线性项的发展方程的准确周期解

本文导出了具高阶非线性项的Lienard方程的准确周期解并从理论上给予了证明,然后利用这些公式得到一大批具高阶非线性项的发展方程的各种Jacobi椭圆函数型的准确周期解,由此避免了一大类非线性发展方程求周期解时求解过程的重复。     

过程质量控制的BP神经网络预测方法研究

利用BP神经网络对过程质量特性值进行预测，建立了预测模型并利用单因素法优化模型参数，实现了过程质量的事前控制。仿真结果表明，神经网络在预测中具有较为明显的优势，对参数的优化提高了网络性能，因此模型符合过程质量智能预测的基本要求。     

改性聚偏氟乙烯接枝苯乙烯/丙烯酸磺酸电解质膜及其在CO传感器中的应用

以过氧化苯甲酰(BPO)作引发剂,通过溶液接枝聚合法把苯乙烯/丙烯酸同时接枝到原硅酸钠改性的聚偏氟乙烯(PVDF)膜上,磺化后得到聚偏氟乙烯接枝苯乙烯/丙烯酸磺酸(PVDF-g-PS/ PASA)膜.FTIR分析表明:苯乙烯和丙烯酸接枝到PVDF膜上;环境的相对湿度在20%～80%范围内,对PVDF-g-PS/ PASA膜电导率的影响基本不变,并达到0.0198S·cm-1,40℃保水率达99%.将膜应用于CO传感器中,传感器电流响应信号与CO气体浓度具有较好的线性关系.     

浅谈济钢新建石灰窑窑型的确定

通过对世界上先进的石灰窑窑型的各项指标比较 ,结合济钢的实际情况 ,确定选择意大利弗卡斯公司的套筒窑为新建石灰窑的窑型     

P3Stor: A parallel, durable flash-based SSD for enterprise-scale storage systems

Driven by data-intensive applications, flash-based solid state drives (SSDs) have become increasingly popular in enterprise-scale storage systems. Flash memory exhibits inherent parallelism. However, existing solid state drives have not fully exploited this superiority. We propose P3Stor, a parallel solid state storage architecture that makes full use of flash memory by utilizing module- and bus-level parallelisms to increase average bandwidth and employing chip-level interleaving to hide I/O latency. To im...