Photochemical degradation of glassy polyesters of low softening point

The photodegradation of polyesters prepared by the reaction of o-phthalic, adipic, and “dimer” acids with ethylene glycol has been studied. The polyesters softened at temperatures in the range of 25–50°C. Polymer films were irradiated in air by means of a medium pressure mercury lamp and the extent of formation of COOH groups determined by infrared spectroscopy. The films were also irradiated in vacuo and in air by means of a high-pressure mercury lamp, and the volatile products, consisting mainly of carbon monoxide and carbon dioxide, were determined by gas chromatography. The results are interpreted in terms of simultaneous Norrish type I and type II decompositions of the polyesters. The type I process accounts for the formation of carbon monoxide and carbon dioxide in the absence of air. The enhanced yield of carbon dioxide in irradiations performed in air is ascribed to the formation of hydroperoxide which undergoes further photolysis. The type II process accounts for the formation of COOH groups. The photodegradation of these glassy polyesters parallels that of crystalline poly(ethylene terephthalate) and is relatively unaffected by changes in composition of the aromatic polyester.     

Length preferences and periodicity in {beta}-strands. Antiparallel edge {beta}-sheets are more likely to finish in non-hydrogen bonded rings

We analysed the length distributions of different types of ß-strandin a high resolution, non-homologous set of 500 protein structures,finding differences in their mean lengths. Antiparallel edgestrands in strand–turn–strand motifs show a preferencefor an even number of residues. This propensity is enhancedif the length is corrected for ß-bulges, which insertan extra residue into the strand. Residues in antiparallel edgeß-strands alternate between being in hydrogen bondedand non-hydrogen bonded rings. Antiparallel edges with an evennumber of residues are more likely to have their final ßresidue in a non-hydrogen bonded ring. This suggests that non-hydrogenbonded rings are intrinsically more stable than hydrogen bondedrings, perhaps because its side chain packing is closer. Therefore,we suggest that a simple way to increase ß-hairpinstability, or the stability of an antiparallel edge strand,is to have a non-hydrogen bonded ring at the end of the strand. Received June 19, 2003; revised October 25, 2003; accepted November 7, 2003     

Orientation effects during the flow of short-fibre reinforced thermoplastics

A study has been carried out to investigate molecular orientation in injection moulded bars of short glass fibre reinforced polypropylene and polyethylene. For the range of fibre concentrations encountered commercially, the fibres do not appear to have any direct effect on the matrix orientation. As the fibre concentration increases, however, the matrix orientation becomes dominated by the orientation of the fibres. These effects are interpreted in terms of current ideas of the rheology of polymer melts during injection moulding and the crystallization of polymers at fibre surfaces.     

Effects of composition and phase relations on mechanical properties and crystallization of silicate glasses

Crystallization, mechanical properties, and workability are all important for the commercialization and optimization of silicate glass compositions. However, the inter-relations of these properties as a function of glass composition have received little investigation. Soda-lime-silica glasses with Na₂O-MgO-CaO-Al₂O₃-SiO₂ compositions relevant to commercial glass manufacture were experimentally studied and multiple liquidus temperature and viscosity models were used to complement the experimental results. Liquidus temperatures of the fabricated glasses were measured by the temperature gradient technique, and Rietveld refinements were applied to X-Ray powder diffraction (XRD) data for devitrified glasses, enabling quantitative determination of the crystalline and amorphous fractions and the nature of the crystals. Structural properties were investigated by Raman spectroscopy. Acoustic echography, micro-Vicker's indentation, and single-edge-notched bend testing methods were used to measure Young's moduli, hardness, and fracture toughness, respectively. It is shown that it is possible to design lower-melting soda-lime-silica glass compositions without compromising their mechanical and crystallization properties. Unlike Young's modulus, brittleness is highly responsive to the composition in soda-lime-silica glasses, and notably low brittleness values can be obtained in glasses with compositions in the wollastonite primary phase field: an effect that is more pronounced in the silica primary phase field. The measured bulk crystal fractions of the glasses subjected to devitrification at the lowest possible industrial conditioning temperatures indicate that soda-lime-silica glass melts can be conditioned close to their liquidus temperatures within the compositional ranges of the primary phase fields of cristobalite, wollastonite, or their combinations.     

The supremacy of online white supremacists – an analysis of online discussions by white supremacists

A content analysis was conducted on five different white supremacist online forums to observe the discourse and types of activities occurring within. In addition, web link analysis was conducted on the forums to identify the presence of external links being posted and discussed by members. We found that members used the forums primarily for information provision, recruitment and networking. Based on these results, we discuss the implications that online hate speech have within offline settings, and the affects these activities have on Canadian citizens in light of the recent repeal of section 13 of the Canadian Human Rights Act (1985), the primary tool in Canada with which to deal with hate speech and other activities observed. The insights extracted from this research have provided novel insight into the sentiments and activities of the white supremacist movement online, a relatively unexplored venue of hate speech and propaganda online.     

Clustering high dimensional data: A graph-based relaxed optimization approach

There is no doubt that clustering is one of the most studied data mining tasks. Nevertheless, it remains a challenging problem to solve despite the many proposed clustering approaches. Graph-based approaches solve the clustering task as a global optimization problem, while many other works are based on local methods. In this paper, we propose a novel graph-based algorithm “GBR” that relaxes some well-defined method even as improving the accuracy whilst keeping it simple. The primary motivation of our relaxation of the objective is to allow the reformulated objective to find well distributed cluster indicators for complicated data instances. This relaxation results in an analytical solution that avoids the approximated iterative methods that have been adopted in many other graph-based approaches. The experiments on synthetic and real data sets show that our relaxation accomplishes excellent clustering results. Our key contributions are: (1) we provide an analytical solution to solve the global clustering task as opposed to approximated iterative approaches; (2) a very simple implementation using existing optimization packages; (3) an algorithm with relatively less computation time over the number of data instances to cluster than other well defined methods in the literature.     

Applications of wavelet data reduction in a recommender system

Memory-based collaborative filtering (CF) recommender systems have emerged as an effective technique for information filtering. CF recommenders are being widely adopted for e-commerce applications to assist users in finding and selecting items of interest. As a result, the scalability of CF recommenders presents a significant challenge; one that is particularly resilient because the volume of data these systems utilize will continue to increase over time. This paper examines the impact of discrete wavelet transformation (DWT) as an approach to enhance the scalability of memory-based collaborative filtering recommender systems. In particular, a wavelet transformation methodology is proposed and applied to both synthetic and real-world recommender ratings. For experimental purposes, the DWT methodology’s effect on predictive accuracy and calculation speed is evaluated to compare recommendation quality and performance.     

Description and evaluation of a new 3-D computerized treatment planning dose compensator system

Evaluation has been performed of compensators generated by means of a computerized three-dimensional treatment planning system that can utilize either digitized slice profiles or CT scans. Two methods of calculating compensator thickness are used: the modified Batho power law (dSAR) method for digitized profiles and the equivalent TAR (eqTAR) method for CT scans. This system not only compensates for patient surface contours but also compensates for internal inhomogeneities. In addition, any required wedging will be incorporated in the compensator generation. This system has been tested for a number of extreme cases with inhomogeneities and sloping contours. Good agreement was obtained between the measured and computer calculated dose profiles especially along the central axis of the beam. A "Profile Uniformity Index" was defined to quantify the goodness of dose compensation in three dimensions. Compensation using this system can achieve good dose uniformity within the target volume in all clinical cases and is definitely an improvement over systems based solely on tissue deficit.