Nitrate and chloride concentrations in the high plains aquifer,Texas

Groundwater nitrate and chloride concentrations were compiled for 122 wells in a rural, three‐county area of northwest Texas. The counties are located on the High Plains aquifer, a major source of groundwater in the region. Cropland/pasture is the predominant land use in the study area. The area also contains numerous cattle feedlots. Fertilizer and manure associated with those land uses are potential sources of ground‐water contamination. Although locally elevated above background levels, none of the chemical concentrations exceeded the primary drinking water standard of 44.27 mg/L for nitrate (10mg/L for NO₃ — N) or secondary standard of 250mg/L for chloride. Rank correlations between nitrate and chloride were statistically significant in two of the three counties, where the solutes may have originated from a common surface source. Denitrification and scant precipitation recharge may account for an absence of nitrate levels above the drinking water standard.     

Cities as planning models

A key feature of modern planning history has been the identification of cities admired for their ‘good planning’. In varying degrees, they have stimulated emulation, selective or partial borrowing, or even direct copying of their admired planning features. Model cities at different phases of planning history include Paris, Frankfurt, Vienna, Moscow, London, Stockholm, Barcelona, Chicago, New York, Portland and Vancouver. In recent years, new models have emerged, such as Singapore or Curitiba. The article considers how such cities became or are becoming models. It examines the methods by which the knowledge and reputation of the ‘model’ are promoted and disseminated. The importance of key actors, and visits, conferences and exhibitions focused on planning issues are considered. So too are less specific factors which help draw the gaze of a wider world. The article also considers whether such cities were/are places where new planning approaches have been invented or where they were implemented on a larger scale. Overall the paper discusses a key and strengthening feature in the circulation of contemporary planning knowledge. It does not answer all the surrounding questions in any definitive sense but opens up new debates about planning and the processes behind its historical evolution.     

Developing toughened aromatic polybenzoxazines using thermoplastic oligomers and telechelics,part 1: Preparation and characterization of the functionalized oligomers

The preparation and characterization of three families of thermoplastic oligomers (M_n = 2918–13263 g mol^?1) based on polyarylsulfone (PSU) differing in both molecular weight and terminal functionality and one series of polyarylethersulfone (PES) of different molecular weights is reported. Infrared and nuclear magnetic resonance spectroscopy data support the formation of both the hydroxyl terminated oligomers and conversion (67–89% depending on molecular weight) to the telechelic PSU oligomer bearing reactive benzoxazine groups. Differential scanning calorimetry reveals that the onset of homopolymerization in the telechelic PSU oligomer occurs at around 100°C (peak maximum 125°C at 10 K/min) and rescans show values of the glass transition (for the homopolymers) ranging from 124 to 167°C depending on molecular weight. The influence on the oligomer backbone and terminal functionality is examined using thermal analysis. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40875.     

A cathode support structure for use in a magnetron oscillator experiment

A low temperature co-fired ceramic (LTCC) material system has been used to develop a protype field emission cathode structure for use in an experimental magnetron oscillator. The structure is designed for used with 30 gated field emission array (GFEA) die electrically connected through silver metal traces and electrical vias. To approximate a cylinder, the cathode structure (48 mm long and 13.7 mm in diameter) is comprised of 10 faceted plates which cover the GFEA dies. Slits in the facet plates allow electron injection. The GFEA die (3 mm × 8 mm) are placed in axial columns of 3 and spaced azimuthally around a cylindrical support structure in a staggered configuration resulting in 10 azimuthal locations. LTCC manufacturing techniques were developed in order to fabricate the newly designed cathode with seven layers wrapped to form the cylinder with electrical traces and vias. Two different cathode wrapping techniques and two different via filling techniques were studied and compared. Two different facet plate manufacturing techniques were studied. Finally, four different support stand configurations for firing the cylindrical structure were also compared with a square post stand having the best circularity and linearity measurements of the fired structure.     

A small-scale comparison of the equivalence of paper-and-pencil and computerized versions of student end-of-course evaluations

This study compared responses to two versions of an end-of-course evaluation instrument completed by graduate students: the traditional printed form completed using pencil and paper, and a microcomputer-based form that presented equivalent items and accepted student responses. A finding of no significant difference in favorableness of composite ratings between the two versions prompted the researcher to perform item-by-item analyses of the two instruments. These analyses revealed that ratings of the individual items on one instrument were highly correlated with the ratings of their matched corresponding items on the other instrument. The paper-and-pencil and computerized evaluation instruments were found to be of almost identically high reliability. Possible limitations of the findings and areas for future research are discussed.     

Synthesis and Evaluation of Water‐Soluble Prodrugs of Ursodeoxycholic Acid (UDCA), an Anti‐apoptotic Bile Acid

Ursodeoxycholic acid (UDCA) is a bile acid with demonstrated anti‐apoptotic activity in both in vitro and in vivo models. However, its utility is hampered by limited aqueous solubility. As such, water‐soluble prodrugs of UDCA could have an advantage over the parent bile acid in indications where intravenous administration might be preferable, such as decreasing damage from stroke or acute kidney injury. Five phosphate prodrugs were synthesized, including one incorporating a novel phosphoryloxymethyl carboxylate (POMC) moiety. These prodrugs were highly water‐soluble, but showed significant differences in chemical stability, with oxymethylphosphate prodrugs being the most unstable. In a series of NMR experiments, the POMC prodrug was bioactivated to UDCA by alkaline phosphatase (AP) faster than a prodrug containing a phosphate directly attached to the alcohol at the 3‐position of UDCA. Both of these prodrugs showed significant anti‐apoptotic activity in a series of in vitro assays, although the POMC prodrug required the addition of AP for activity, while the other compound was active without exogenous AP.     

Comment on Fossil-fuel constraints on global warming by A. Zecca and L. Chiari [Energy Policy 38 (2010) 1–3]

Zecca and Chiari (2010) have sought to challenge the findings of Nel and Cooper (2009), who argued that the impending peak and decline of fossil fuel production will most likely lead to a lower emissions trajectory than the majority of scenarios offered by the IPCC. Zecca and Chiari used their own model to produce a higher projection of atmospheric CO₂ concentration, drawing on the conclusions of Archer (2005) to do so.     

Transfer between pose and illumination training in face recognition.

The relationship between pose and illumination learning in face recognition was examined in a yes–no recognition paradigm. The authors assessed whether pose training can transfer to a new illumination or vice versa. Results show that an extensive level of pose training through a face–name association task was able to generalize to a new illumination (Experiments 1 and 3), but an equal level of illumination training failed to generalize to a new pose (Experiment 2). The transfer of pose training was likely to depend on a relatively extensive level of training because the same faces with reduced level of exposure (Experiment 4) were unable to reproduce the transfer effect. The findings suggest that generalization of pose training may be extended to different types of image variation, whereas generalization of illumination training may be confined within the trained type of variation. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Modeling the pH dependent hydrolysis of VX for aqueous releases

The fate of chemical warfare agents (CWAs) in aqueous environments is not well characterized. Limited physical and kinetic data are available in the open literature for this class of chemicals, in part due to the dangers associated with exposure to these compounds. As a result, the development of methods for determining the persistence and extent of impact of a waterborne chemical agent release remains largely unanswered. In this study a basic hydrolysis model was developed to track the fate of VX (O-ethyl S-(2-diisopropylaminoethyl) methylphosphonothiolate) from an instantaneous point source aqueous release. Hydrolysis product generation tracking was developed to determine the instantaneous pH within the local dispersive environment. Using instantaneous local pH values, the impact of pH on the persistence of VX hydrolysis rate was investigated for three different aqueous environments with varying dispersive conditions. Modeling results indicate that an accurate characterization of the pH dependence of the hydrolysis rate constant becomes more important in lower pH and lower turbulence environments. With this basic model, estimates of the time and extent of lethality of a VX release can be made.