Structural and magnetic properties of erbium doped nanocrystalline Li–Ni ferrites

A series of nanocrystalline Li_0.25Ni_0.5Fe_2.25−xEr_xO₄ (x=0.00, 0.02, 0.06, 0.08, and 0.10) ferrite powders, having a cubic spinel crystal structure and a low value of coercivity, was synthesized by the sol–gel auto-combustion route. The structure, morphology and magnetic properties of the prepared nanoferrites were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the magnetic property measurement system (MPMS). A well-defined single phase spinel structure is confirmed in all the samples by X-ray diffraction analysis. The lattice parameters of the samples increase slightly with increasing the erbium content. The crystallite size of the Er-doped samples is smaller than that of pure Li–Ni ferrite, and decrease regularly in the range of 36.0–14.5 nm. It has been observed that the magnetic properties of these ferrites are strongly influenced by the added erbium content. The magnetic measurements indicate that saturation magnetization (M_s) and coercivity (H_c) decrease gradually with the increase of Er content in the lattice.     

Performance analysis of three advanced controllers for polymerization batch reactor: An experimental investigation

The performances of three advanced non-linear controllers are analyzed for the optimal set point tracking of styrene free radical polymerization (FRP) in batch reactors. The three controllers are the artificial neural network-based MPC (NN-MPC), the artificial fuzzy logic controller (FLC) as well as the generic model controller (GMC). A recently developed hybrid model (Hosen et al., 2011a. Asia-Pac. J. Chem. Eng. 6(2), 274) is utilized in the control study to design and tune the proposed controllers. The optimal minimum temperature profiles are determined using the Hamiltonian maximum principle. Different types of disturbances are introduced and applied to examine the stability of controller performance. The experimental studies revealed that the performance of the NN-MPC is superior to that of FLC and GMC.     

A collaborative approach for urban underground space development toward sustainable development goals: Critical dimensions and future directions

The utilization of urban underground space (UUS) offers an effective solution to urban problems but may also negatively affect urban development. Therefore, UUS development needs better concerted guidelines to coordinate various urban systems and the multiple components of the underground world. Sustainable Development Goals (SDGs), which should be viewed as important yardsticks for UUS development, do not explicitly mention urban underground space, although many of them are affected by both the positive and negative consequences of its development. To fill this gap, this review lays the foundations of relevant UUS concepts and uses exemplary cases to reveal that 11 out of 17 SDGs can be linked with UUS uses. These linkages also manifest that land administration, integrated planning, architectural design, and construction technology are critical dimensions for increasing the contributions of UUS to the realization of SDGs. To achieve multi-disciplinary synergies among these four critical dimensions, a collaborative approach framework based on spatial data infrastructure is required. Thus, this work provides academics and practitioners with a holistic view of sustainable UUS development.     

Recent Developments in Predicting Impact and Shock Sensitivities of Energetic Materials （英）

Empirical, quantum mechanical and artificial neural network methods are three usual methods in recent years that were used to predict sensitivity of different classes of high explosives. Some recent developments in predicting sensitivity by various methods are reviewed and discussed for various classes of energetic materials.     

New syntheses of pyrazolo[3,4-d]pyrimidine,pyrazolo[3,4-d]pyridazine,isoindolinedione and pyrazole derivatives

Phenacylmalononitriles 2 react with hydrazines, acetic-hydrochloric acid and with diazotised primary aromatic amines to afford phenacylpyrazole ( 5a,b ), aminofurans ( 6a,b ) and aminopyrazole derivatives ( 3a,d ) respectively. The synthesised derivatives ( 3d, 6a ) were the key materials for the synthesis of isoindolinedione, ( 7a – c ) pyrazolopyrimidine ( 9, 10 ), and pyrazolopyridazine derivatives ( 11 ). The structures of the newly synthesised heterocycles were established on the basis of elemental analyses and spectral data besides synthesis via other routes.     

Biofilm and Small Colony Variants—An Update on Staphylococcus aureus Strategies toward Drug Resistance

Recently, the drawbacks arising from the overuse of antibiotics have drawn growing public attention. Among them, drug-resistance (DR) and even multidrug-resistance (MDR) pose significant challenges in clinical practice. As a representative of a DR or MDR pathogen, Staphylococcus aureus can cause diversity of infections related to different organs, and can survive or adapt to the diverse hostile environments by switching into other phenotypes, including biofilm and small colony variants (SCVs), with altered physiologic or metabolic characteristics. In this review, we briefly describe the development of the DR/MDR as well as the classical mechanisms (accumulation of the resistant genes). Moreover, we use multidimensional scaling analysis to evaluate the MDR relevant hotspots in the recent published reports. Furthermore, we mainly focus on the possible non-classical resistance mechanisms triggered by the two important alternative phenotypes of the S. aureus, biofilm and SCVs, which are fundamentally caused by the different global regulation of the S. aureus population, such as the main quorum-sensing (QS) and agr system and its coordinated regulated factors, such as the SarA family proteins and the alternative sigma factor σB (SigB). Both the biofilm and the SCVs are able to escape from the host immune response, and resist the therapeutic effects of antibiotics through the physical or the biological barriers, and become less sensitive to some antibiotics by the dormant state with the limited metabolisms.     

Evaluation of alumina reinforced oil fly ash composites prepared by spark plasma sintering

The thermomechanical behavior of micro/nano-alumina (Al₂O₃) ceramics reinforced with 1-5 wt.% of acid-treated oil fly ash (OFA) was investigated. Composites were sintered using spark plasma sintering (SPS) technique at a temperature of 1400°C by applying a constant uniaxial pressure of 50 MPa. It was evaluated that the fracture toughness of micro- and nanosized composites improved in contrast with the monolithic alumina. Highest fracture toughness value of 4.85 MPam^1/2 was measured for the nanosized composite reinforced with 5 wt.% OFA. The thermal conductivity of the composites (nano-/microsized) decreased with the increase in temperature. However, the addition of OFA (1-5 wt.%) in nanosized alumina enhanced the thermal conductivity at an evaluated temperature. Furthermore, a minimum thermal expansion value of 6.17 ppm*K⁻¹ was measured for nanosized Al₂O₃/5 wt.% OFA composite. Microstructural characterization of Al₂O₃-OFA composites was done by x-ray diffraction and Raman spectroscopy. Oil fly ash particles were seen to be well dispersed within the alumina matrix. Moreover, the comparative analysis of the nano-/microsized Al₂O₃/OFA composites shows that the mechanical and thermal properties were improved in nanosized alumina composites.     

Synthesis of Architectural-Cubic Porous Silicon by Electroless Stain Etching in V2O5 and HF Solution

Silicon - Porous silicon (PSi) samples were prepared via electroless stain etching of silicon substrates in HF using V2O5 as an oxidant and ethanol as a surfactant for different etching times. The...     

Liaison of phenolic acids and biological activity of escalating cultivars of Daucus carota

The objective of the present study was to analyze and compare the phenolic compounds and their antioxidant capacities of new lines of Dacus carota. The selected cultivars showed high variation in the contents of total phenolics (30.26–65.39 mg/100 g FW) and total ascorbic acid (41.12–58.36 mg/100 g FW). Analysis on RP-HPLC revealed that hydroxycinnamic acids and its derivatives were major phenolic compounds present in D. carota extracts, whereas 5-caffeolquinic acid was a major hydroxycinnamic acid (ranged from 30.26 to 65.39 mg/100 g FW). DCP cultivar showed high total antioxidant capacity (77.69 mg/100 g), 2,2-diphenyl-1-picrylhydrazyl (DPPH) scavenging capacity (52.36 mg/100 g), superoxide radical scavenging capacity (53.69 mg/100 g), and hydroxyl radical scavenging capacity (51.91 mg/100 g). A linear relationship was found between total phenolic acid contents and antioxidant capacity. Both phenolic compounds and antioxidant capacities varied significantly (ρ < 0.05) among cultivars. DCP cultivar was found to be a rich source of phenolics and ascorbic acid with high antioxidant activity.