Macrosegregation Formation in an Al–Si Casting Sample with Cross-sectional Change During Directional Solidification

A unidirectional solidification experiment of hypoeutectic Al-7.0 wt% Si alloy against gravity direction in a cylindrical mold with cross-sectional change was made, and the macrosegregation in different parts of the as-solidified sample was investigated (Ghods et al. in J Cryst Growth 441:107–116, 2016; J Cryst Growth 449:134–147, 2016). The current study is to use a two-phase columnar solidification model to analyze the segregation mechanisms as used in this experiment. Following flow phenomena and their contributions to the formation of macrosegregation are simulated and compared: (1) solidification shrinkage-induced feeding flow; (2) thermo-solutal convection; and (3) combined thermo-solutal convection and shrinkage-induced feeding flow. The shrinkage-induced feeding flow leads to an inverse (positive) segregation in the bottom part, and a severe negative segregation in the part below cross-sectional change. Thermo-solutal buoyancy leads to a so-called steepling convection in the main part of the sample (away from the bottom and cross-sectional change), and this kind of flow leads to a positive macrosegregation near the sample surface. The calculations have successfully explained the experimental result of macrosegregation.     

Dielectric Strength of Compressed Insulating Gases and their Mixtures

A method is developed for computing the discharge threshold voltages in SF6, N2 as well as their mixtures above atmopheric pressure. In electronegative gases, and for both uniform and nonuniform field gaps of positive polarity, there is a critical pressure above which field emission from the cathode surface has a significant effect. The method of calculation is based on the condition necessary for the onset streamer to propagate. The effect of increased pressure over the critical value is that spark breakdown takes place within the discharge gap unpreceded by any corona. The computed values are in good agreement with those measured experimentally at pressures below and above the critical value for both uniform and nonuniform field gaps. The present calculations confirm those predicted experimentally, namely, there is no significant difference in the behavior of pure SF6 and mixtures up to 50 percent of N2. The fact that mixtures can show a higher breakdown voltage at the same total pressure than pure SF6 is also confirmed.     

Fabrication and Characterization of Ionic Conducting Nanofibers

The electrospinning method was used to fabricate nanostructures of Nafion‐poly(vinyl alcohol) (PVA) and Nafion‐poly(ethylene oxide) (PEO). Depending on the ratio between the two polymers, nanospheres and/or nanofibers could be obtained in a reproducible manner. The Nafion‐PVA mats were found to be more conductive than the Nafion‐PEO ones, possibly because of their better mechanical properties when swollen by water. The fiber morphology was always found to be more conductive than the sphere morphology. However, all electrospun mats presented ionic conductivities slightly lower than extruded Nafion 115 or Nafion‐PVA cast films.

     

Crystal structure and orientation of uniaxially and biaxially oriented PLA and PP nanoclay composite films

Cast films of poly(lactic acid) (PLA) and polypropylene (PP) with 2.5 and 5 wt % organo modified nanoclay were prepared and then uniaxially and biaxially hot drawn at T = 90 and 155°C, respectively, using a biaxial stretcher. The orientation of PLA and PP crystal unit cells, alignment of clay platelets, as well as the extent of intercalation and exfoliation were studied using wide angle X‐ray diffraction (WAXD). The measurement of d‐spacing of the 001 plane (normal to platelets plane) of the clay tactoids indicated the intercalation of the silicate layers for the PLA nanocomposite films, whereas the PP nanofilled films showed only dispersion of the nanoparticles (i.e., neither intercalation nor exfoliation were observed). The intercalation level of the clay platelets in PLA was almost identical for the uniaxially and biaxially drawn films. Our finding showed that the crystallite unit cell alignments are appreciably dependent on uniaxial and biaxial stretching. Moreover, the incorporation of clay to some extent influenced the orientation of the crystal unit cell axes (a, b, and c) of the oriented films. The silicate layers revealed a much higher orientation into the flow direction in the uniaxially stretched films compared to the biaxially drawn samples. In addition, the orientation of the 001 plane of nanoclays was significantly greater in the PLA compared to the PP nanoclay composite films probably due to a better intercalation and stress transfer in the former. Morphological pictograms illustrating the effects of uniaxial and biaxial stretching on the clay orientation are proposed. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Effect of poly(styrene‐co‐maleic anhydride) imidization on the miscibility and phase‐separation temperatures of poly(styrene‐co‐maleic anhydride)/poly(vinyl methyl ether) and poly(styrene‐co‐maleic anhydride)/ poly(methyl methacrylate) blends

The objective of this work was to study the miscibility and phase‐separation temperatures of poly(styrene‐co‐maleic anhydride) (SMA)/poly(vinyl methyl ether) (PVME) and SMA/poly(methyl methacrylate) (PMMA) blends with differential scanning calorimetry and small‐angle light scattering techniques. We focused on the effect of SMA partial imidization with aniline on the miscibility and phase‐separation temperatures of these blends. The SMA imidization reaction led to a partially imidized styrene N‐phenyl succinimide copolymer (SMI) with a degree of conversion of 49% and a decomposition temperature higher than that of SMA by about 20°C. We observed that both SMI/PVME and SMI/PMMA blends had lower critical solution temperature behavior. The imidization of SMA increased the phase‐separation temperature of the SMA/PVME blend and decreased that of the SMA/PMMA blend. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

SEM and XAS characterization at beginning of life of Pd-based cathode electrocatalysts in PEM fuel cells

The fuel cell performance of membrane electrode assemblies with a Pt anode and Pd, PdCu or Pd₅Cu₄Pt cathodes has been tested during 116 h (beginning of life). The incorporation of Cu to Pd increases the fuel cell performance. Incorporation of Pt leads to further improvement. SEM micrographs of the as-prepared and the fuel cell-tested assemblies show the effects of the 116 h of continuous operation. Nafion membranes were characterized by small angle X-ray scattering. The results show a reduction of the size of the lamellar domains in the perfluorinated matrix after fuel cell testing, but no correlation with the cathode electrocatalyst material. The cathode electrocatalysts were characterized by ex-situ synchrotron radiation X-ray diffraction and X-ray absorption spectroscopy at the Pd L₃, Cu K and Pt L₃ edges. Re-organization of Pd₅Cu₄Pt electrocatalyst after fuel cell testing was observed. The Cu in the electrocatalyst can be described as a nano-mixture of metallic Cu, alloyed Cu and CuO. The CuO acts as a promoter of the ORR.     

Performance evaluation of single stand and hybrid solar water heaters: a comprehensive review

In this review, flat plate and concentrate-type solar collectors, integrated collector–storage systems, and solar water heaters combined with photovoltaic–thermal modules, solar-assisted heat pump solar water heaters, and solar water heaters using phase change materials are studied based on their thermal performance, cost, energy, and exergy efficiencies. The maximum water temperature and thermal efficiencies are enlisted to evaluate the thermal performance of the different solar water heaters. It is found that the solar water heaters’ performance is considerably improved by boosting water flow rate and tilt angle, modification of the shape and number of collectors, using wavy diffuse and electrodepositioned reflector coating, application of the corrugated absorber surface and coated absorber, use of turbulent enhancers, using thermal conductive working fluid and nanofluid, the inclusion of the water storage tank, and tank insulation. These items increase the heat transfer area and coefficient, thermal conductivity, the Reynolds and Nusselt numbers, heat transfer rate, and energy and exergy efficiencies. The evacuated tube heaters have a higher temperature compared to the collectors with a plane surface. Their thermal performance increases by using all-glass active circulation and heat pipe integration. The concentrative type of solar water heaters is superior to other solar heaters, particularly in achieving higher water temperatures. Their performance improves by using a rotating mirror concentrator. The integration of the system with energy storage components, phase change materials, or a heat pump provides a satisfactory performance over conventional solar water heaters.

Graphical abstract

Modification of solar water heaters

     

Multiscale aggregation and illumination-aware attention network for infrared and visible image fusion

Image fusion plays a significant role in computer vision since numerous applications benefit from the fusion results. The existing image fusion methods are incapable of perceiving the most discriminative regions under varying illumination circumstances and thus fail to emphasize the salient targets and ignore the abundant texture details of the infrared and visible images. To address this problem, a multiscale aggregation and illumination-aware attention network (MAIANet) is proposed for infrared and visible image fusion. Specifically, the MAIANet consists of four modules, namely multiscale feature extraction module, lightweight channel attention module, image reconstruction module, and illumination-aware module. The multiscale feature extraction module attempts to extract multiscale features in the images. The role of the lightweight channel attention module is to assign different weights to each channel so as to focus on the essential regions in the infrared and visible images. An illumination-aware module is employed to assess the probability distribution regarding the illumination factor. Meanwhile, an illumination perception loss is formulated by the illumination probabilities to enable the proposed MAIANet to better adjust to the changes in illumination. Experimental results on three datasets, that is, MSRS, TNO, and RoadSence, verify the effectiveness of the MAIANet in both qualitative and quantitative evaluations.     

Morphology and thermal properties of poly(ethylene terephthalate)‐modified kaolin nanocomposites

Kaolin particles were dispersed in a PET (poly(ethylene terephthalate)) matrix using a displacement procedure in which kaolin was initially treated with potassium acetate and, subsequently, melt‐blended with PEO and PET. The disappearance of characteristic peaks in XRD patterns of chemically treated particles revealed that the crystalline form and layered structure of kaolin particles were mainly destroyed. Scanning electron microscopy and transmission electron microscopy showed that the thickness of dispersed particles were generally in the range of 10–100 nm. It was also observed that the dispersion level of the chemically treated kaolin was much better than that of “as received” kaolin particles. Rheological studies showed the formation of a network‐like structure in samples containing the chemically treated kaolin as a result of improved dispersion of particles. It was also observed that both the kaolin particles and modifiers could accelerate the degradation process and lower the molecular weight of the PET. The introduction of kaolin particles shifted the crystallization temperatures of PET to higher temperatures. It was observed that the incorporation of a chain extender significantly restricted the crystallization process. The Avrami–Jeziorny analysis confirmed the alteration of the crystalline structure of the filled polymer. Based on TGA thermograms the decomposition temperature of PET–kaolin composites was slightly lower than that of the neat PET. POLYM. COMPOS., 37:1443–1452, 2016. © 2014 Society of Plastics Engineers