Analysis of the effect of polypyrrole synthesis conditions on its capacity to reduce hexavalent chromium

This paper reports the capacity of polypyrrole to reduce toxic hexavalent chromium (Cr(VI)). The influence of using different electrolytes during the polymer's synthesis has been studied. To improve the reduction of Cr(VI), the parameters considered were the polypyrrole morphology and the amount of conducting polymer. Polypyrrole obtained by cyclic voltammetry at a low sweep rate using KBr as supporting electrolyte showed better performance for Cr(VI) reduction compared to coatings obtained by constant potential or cyclic voltammetry at high sweep rates.     

N-phenyl piprazine-polyester derivative as curing activator of unsaturated resins

An oligomeric compound (Pol-2A) has been synthesized by a Michael-type addition of N-phenyl piperazine to double bonds of the maleic units of a polyester resin. This compound was used as activator (with benzoyl peroxide) in the curing of unsaturated polyester resins and compared in its efficiency with N,N-dimethylaniline (DMA). Pol-2A showed actiator characteristics comparable to those of DMA, with a wider range of gel times, and similar mechanical properties of the end products, with the advantage of a severe lowering of diffusibility and related environmental toxicity.     

In memoriam

Sans résumé

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In memoriam

     

Enhanced Oil Recovery: The Synthesis of Anthraquinone [1, 2-C] Alkylisoxazole

Anthraquinone [1, 2-C] methylisoxazole is synthesized from 2-ethylanthraquinone through nitration and treating with oleum. The different methods of 2-ethylanthraquinone nitrated were discussed. The optimum conditions were determined. The structure of the product was confirmed by MS and ¹H NMR.     

Percutaneous Absorption Enhancement by Nonionic Surfactants

The influence of nonionic surfactants (polysorbates) on hydrocortisone penetration through hairless mouse skin in vitro has been determined. Permeation was quite slow from purely aqueous media containing surfactants following finite dose application. However, if the vehicle contained high propylene glycol concentrations (40% or more), inclusion of a surfactant increased permeation rate significantly. Similar effects were noted following application of a large donor volume (infinite dose). Synergism was attributed to enhancement of surfactant absorption by the stratum corneum leading to changes in skin barrier resistance. With vehicles containing a surfactant, penetration was higher after finite dose application due to compositional changes within the vehicle.     

A chloride method for the determination of the enthalpy of steam/water mixtures discharged from geothermal wells

Chloride concentrations and pressures (or temperatures) in two points of a geothermal test line have been used to determine the enthalpy of the steam/water mixture discharged from Nisyros I geothermal well (Greece). The results are in agreement with those obtained by the Russell James method. The chloride method described in this paper is fast, requires cheap, portable equipment and is thus particularly suitable for short-term well testing during drilling or immediately after well completion, especially in steam-rich mixtures.     

Apple Juice Clarification With the Use of Honey and Pectinase

The clarification of apple juice with the use of honey and enzyme separately and in combinations was studied. The results indicated the existence of a synergistic effect upon the time of initial flocculation when honey was combined with pectinase enzymes. Changes in the rate of flocculation appeared to be an additive effect of enzyme concentration and/or honey concentration. The combined treatment of honey and enzyme was found to induce flocculation very fast as compared to enzyme alone at cold as well as warm temperatures. When used alone, the honey treatment produced a clarified juice with a viscosity similar to cider.     

Preserving poultry feeds in the humid tropics: A trial of calcium propionate under feed mill conditions

Calcium propionate was incorporated into a complete poultry feed and a feed concentrate at levels of 0, 0.3, 0.4 and 0.6%. The feeds were stored in 25 kg woven sacks in a feed mill. Air temperatures ranged from 22 to 34°C and relative humidity was in the range 67 to 93%. Mould growth was measured microbiologically and by measurement of feed temperature. Calcium propionate had a large effect on the microbiological measurements but only a small effect on heating in the feeds. As a preservative, it retained its activity for 6 weeks which extended the storage life by only 1 week in this case. The relative merits of the microbiological and temperature measurements are discussed.