Mechanical and thermal properties of potassium salts of poly(ethylene‐co‐ethylacrylate): Polyolefin ionomers in the absence of acid groups

The thermal and mechanical properties of ionomers prepared by partial saponification of poly(ethylene‐co‐ethylacrylate) (EEA) with potassium were investigated by using differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The Vicat softening temperature (VST) and bending modulus were also evaluated. Molecular design of the present EEA‐based ionomers eliminates acid groups, which affect ionic aggregates for conventional ionomers. The DSC results showed that the melting enthalpy and main crystallization temperature decreased as the ion content increased, whereas on the other hand, the crystal melting temperature at about 360 K did not depend on the ion content, and a secondary exothermal peak was observed in the cooling process. The variance of the VST increased as the crystallinity decreased. The temperature‐dependent curves of DMA data of the EEA‐based potassium ionomers with a higher ion content showed elastic plateau even at temperatures above their crystal melting points. Our results indicate the existence of strong cross‐linking mediated by ion aggregates. The quadratic increase of stiffness as a function of ion content, increasing VST with decreasing crystallinity, and elastic plateau of temperature‐dependent moduli above crystal melting temperature are significant characteristics of the EEA‐based potassium ionomers, which contain ionic aggregations without acid group presence. POLYM. ENG. SCI., 55:1843–1848, 2015. © 2014 Society of Plastics Engineers     

Investigation of false triggering mechanism

This paper discusses a problem that a half‐bridge circuit can generate, namely a false trigger by high‐speed switching transition. In general, a false trigger occurs by charging a gate–source capacitance because of high‐speed voltage transition and influx of current via a reverse transfer capacitance. Therefore, it is thought that the ratio of the input capacitance and the reverse transfer capacitance is important to check whether a false trigger occurs. However, we find another reason and propose a novel assumption. A novel false triggering mechanism appears by considering the source‐side parasitic inductance. © 2013 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Heat transfer characteristics of the latent heat thermal energy storage capsule

The characteristic variation of the rate of heat transfer to and from a latent heat thermal energy storage capsule was investigated analytically and experimentally. Basic experiments were carried out to simulate a solar energy storage capsule, using a horizontal cylindrical capsule (300 mm length, 40 mm o.d.) filled with naphthalene as the phase change material. The variation of heat flux during the processes of heat storage and removal was measured by a heat flow meter wrapped around the capsule, as the capsule was subjected to stepwise variations of the surface temperature. Finite difference calculations based on heat conduction were also carried out to compare with the experimental results. For the heat removal process, the experimental results and the calculated heat flux agreed well with each other. They showed different characteristic trends for the heat storage process, due to the effects of natural convection.     

Over 27% efficiency GaAs/InGaAs mechanically stacked solar cell

We have applied an InGaAs solar cell (band GAP = 0.75 eV) to the bottom cell of the super-high-efficiency tandem solar cell aiming an over 35% conversion efficiency. The InGaAs cell which is lattice-matched to the InP substrate showed the efficiency of 5.5% under the GaAs substrate with low carrier concentration. Combining with the GaAs cell by means of a mechanically stacking technique, we obtained an efficiency of 28.8% at air mass (AM) 1.5, 1-sun. This result suggests the possibility of the cells with the efficiency of over 35% with combining a GalnP/GaAs monolithic tandem cell and the InGaAs cell (or InGaAsP cell).     

Regional determinants of total factor productivity in Japan: stochastic frontier analysis

As Japan’s birthrate declines and its society ages, governmental policies need to improve the productivity of regional economies in order to sustain regional growth. This study examines social overhead capital and population agglomeration as drivers of total factor productivity (TFP) growth in Japan. The use of stochastic frontier analysis demonstrates that social overhead capital contributes to TFP growth and, especially, influences productive efficiency. Furthermore, the findings reveal that population agglomeration underpins TFP growth in regional economies. Empirical results also indicate that productive efficiency is high in regions where manufacturing is concentrated and that productive efficiency improves when internationally competitive manufacturers concentrate in regional economies. This study endorses the development of social overhead capital to spur Japan’s regional TFP growth. As such, it indicates that providing social infrastructure and enhancing regional productivity are important strategies for the government to consider in its efforts to achieve sustainable regional growth.     

User-assisted in-network caching in information-centric networking

In information-centric networking, in-network caching has the potential to improve network efficiency and content distribution performance by satisfying user requests with cached content rather than downloading the requested content from remote sources. In this respect, users who request, download, and keep the content may be able to contribute to in-network caching by sharing their downloaded content with other users in the same network domain (i.e., user-assisted in-network caching). In this paper, we examine various aspects of user-assisted in-network caching in the hopes of efficiently utilizing user resources to achieve in-network caching. Through simulations, we first show that user-assisted in-network caching has attractive features, such as self-scalable caching, a near-optimal cache hit ratio (that can be achieved when the content is fully cached by the in-network caching) based on stable caching, and performance improvements over in-network caching. We then examine the caching strategy of user-assisted in-network caching. We examine three caching strategies based on a centralized server that maintains all content availability information and informs each user of what to cache. We also examine three caching strategies based on each user’s content availability information. We first show that the caching strategy affects the distribution of upload overhead across users and the number of cache hits in each segment. One interesting observation is that, even with a small storage space (i.e., 0.1% of the content size per user), the centralized and distributed approaches improve the cache hit ratio by 50% and 45%, respectively. With an overall view of caching information, the centralized approach can achieve a higher cache hit ratio than the distributed approach. Based on this observation, we discuss a distributed approach with a larger view of caching information than the distributed approach and, through simulations, confirm that a larger view leads to a higher cache hit ratio. Another interesting observation is that the random distributed strategy yields comparable performance to more complex strategies.     

Flow structure around the intake of a vertical pump

The flow structure around the intake of a vertical pump is investigated experimentally and numerically in order to obtain a guideline in designing the optimum shape of the intake of vertical pumps, in which their installation area is demanded to be minimum without losing the high performance. We concentrate our attention on the expansion ratio of the intake as a representative characteristic of the shape of the pumps and investigate the effect of the expansion ratio on pump performance. It is concluded that the optimum expansion ratio ranges in 1.1-1.2 if we take into consideration that the area needed for the installation of the pump should be minimum.     

Measurement and analysis of feedback reactivity in the Monju restart core

The purpose of this study is to develop a feedback reactivity measurement technique in the Japanese prototype fast breeder reactor Monju and to validate calculation methodology to forecast the nuclear feedback phenomena. A feedback reactivity measurement technique has been developed based on a reactivity model featuring components that depend on the reactivity coefficients, denoted as reactor power (K_R) and reactor vessel inlet temperature (K_in). This technique can precisely measure the two reactivity components simultaneously and was applied to the feedback reactivity experiment conducted in the Monju system start-up test in May 2010. A thorough evaluation considering all possible biases and uncertainties demonstrated that the reactivity coefficients can be evaluated with a measurement uncertainty smaller than 3%. The evaluated reactivity coefficients were simulated considering the temperature distribution in the core. The calculated and measured values of K_R agreed within 1%, and the value of K_in was consistent with that reported in a previous isothermal temperature coefficient experiment. The measured and calculated fuel subassembly outlet temperatures also agreed well within 0.2°C, which supports the validity of the temperature calculation.     

基于混合方法的PWM逆变器下永磁同步电动机的温升研究

提出一种新型基于等效热网络与有限元相结合的混合方法,建立了三维磁热耦合模型,对一台在脉宽调制(PWM)逆变器驱动下的30 kW/50 Hz表贴式永磁同步电动机进行了仿真研究.首先用场路紧密耦合方法分析电机的分布热源.包括涡流损耗、铁损和铜损.利用该热源分布,结合适当的热网络,研究了耦合温升问题.仿真结果表明,由于载波谐波的影响导敛永磁体中涡流损耗的大量增加,其温升也非常显著.试验验证表明,磁块表面和机壳的测量温度与分析结果栩吻合,因此该分析方法能准确预测水磁体温度.     

Effect of degree of neutralization of sodium-based ionomers on hot-tack properties

The hot-tack properties of ethylene-methacrylic acid copolymers neutralized with sodium (Na) cations to produce ionomers were investigated. Specimens with neutralization degrees of 20%, 54%, and 70% were examined. After testing at low sealing temperatures (<130°C), the highest hot-tack strength was obtained from a specimen with a neutralization degree of 20%. In contrast, at high sealing temperatures (>140°C), the hot-tack strength increased with an increasing degree of neutralization. Observations of the surfaces of samples tested at low sealing temperatures after hot-tack tests showed that specimens having a neutralization degree of 20% exhibited cohesive breakdown while the 54% and 70% specimens underwent interfacial delamination. The effect of sealing temperature on hot-tack strength was determined by assessing the rheological properties of molten ionomers. The results suggested that, when testing at low sealing temperatures, a low melt viscosity provided high hot-tack strength by allowing flow diffusivity of the resin at the sealed interface. At high sealing temperatures, uniaxial elongational viscosity related to strain hardening contributed to the high hot-tack strength of these Na-based ionomers. The present study highlights the important effect of ionic aggregates on hot-tack properties.