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31.
Yves Denizot Laurence Michel Jacques Benveniste Alain Meybeck Yolène Thomas Louis Duberfret 《Lipids》1991,26(12):1093-1094
Paf is a phospholipid mediator present in human skin which induces inflammatory events such as neutrophil infiltration and
increased vascular permeability. Recent data suggest that cutaneous cells, such as fibroblasts and keratinocytes, produce
paf and that paf is released during allergic cutaneous reactions. It is tempting to speculate that paf may contribute to the
development of various skin disorders with acute and chronic skin inflammation. Paf antagonists may help in bringing answers
to this hypothesis and may offer new prospects for the treatment of cutaneous inflammatory diseases.
Based on a paper presented at the Third International Conference on Platelet-Activating Factor and Structurally Related Alkyl
Ether Lipids, Tokyo, Japan, May 1989. 相似文献
32.
Antoine T Priem B Heyraud A Greffe L Gilbert M Wakarchuk WW Lam JS Samain E 《Chembiochem : a European journal of chemical biology》2003,4(5):406-412
Two metabolically engineered Escherichia coli strains have been constructed to produce the carbohydrate moieties of gangliosides GM2 (GalNAcbeta-4(NeuAcalpha-3)Galbeta-4Glc; Gal = galactose, Glc = glucose, Ac = acetyl) and GM1 (Galbeta-3GalNAcbeta-4(NeuAcalpha-3)Galbeta-4Glc. The GM2 oligosaccharide-producing strain TA02 was devoid of both beta-galactosidase and sialic acid aldolase activities and overexpressed the genes for CMP-NeuAc synthase (CMP = cytidine monophosphate), alpha-2,3-sialyltransferase, UDP-GlcNAc (UDP = uridine diphosphate) C4 epimerase, and beta-1,4-GalNAc transferase. When this strain was cultivated on glycerol, exogenously added lactose and sialic acid were shown to be actively internalized into the cytoplasm and converted into GM2 oligosaccharide. The in vivo synthesis of GM1 oligosaccharide was achieved by taking a similar approach but using strain TA05, which additionally overexpressed the gene for beta-1,3-galactosyltransferase. In high-cell-density cultures, the production yields for the GM2 and GM1 oligosaccharides were 1.25 g L(-1) and 0.89 g L(-1), respectively. 相似文献
33.
The modification of the interface in immiscible polymer blends is critical in order to optimize physical properties. Despite the great commercial importance of polymer blends, many aspects of the emulsification process remain unclear In this paper, it will be shown that an emulsification curve can be used to estimate the influence of the architecture molar mass of styrene/hydrogenated butadiene block copolymer interfacial modifiers on the emulsifion of polystyrene/ethylene-propylene rubber blends under melt processing conditions. An expression for eing the critical amount of copolymer to saturate the interface, as well as aspects concerning the localisation of the modifier in the blend system will also be addressed. 相似文献
34.
Topics in Catalysis - This Synthetic Gas Bench (SGB) study focuses on the effect of cell geometry and wall thickness on the gasoline NO x trap functionality. The data show that besides a NO x trap... 相似文献
35.
Alain A Vertès Masayuki Inui Hideaki Yukawa 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2007,82(8):693-697
The challenges of implementing biorefineries on a global scale include socioeconomic, financial, and technological constraints. In particular, the development of biorefineries is tightly linked to the continued availability of fermentation raw materials. These constraints can be relaxed by the use of diverse raw materials, while advances that confer higher flexibility would enable biotechnological plant managers to swiftly react to volatile markets. In conventional processes, Saccharomyces cerevisiae grows on a relatively limited range of substrates, and produces only a single product—ethanol. Given the observed maturity of the S. cerevisiae fermentation technology, alternatives to baker's yeast may be needed to tip the economic balance in favour of biotechnological ethanol. These alternative fermentation technologies may allow a greater diversity of substrates to be used to produce an individually tailored mix of ethanol and other chemicals. Copyright © 2007 Society of Chemical Industry 相似文献
36.
Said Ghaout Alain Louveaux Anne Marie Mainguet Max Deschamps Youssef Rahal 《Journal of chemical ecology》1991,17(8):1499-1515
A field study of the food eaten by solitary desert locusts was carried out in a winter breeding area in Mauritania. The food eaten, determined by the plant epidermis found in fecal pellets, was compared to the plant's availability in the habitat.Schouwia purpurea, well represented in the diets, was dominant at the study site. Adults had a preference forTribulus terrester. Growth and feeding on these two plants were compared. The high water content ofS. purpurea leaves limited the dry matter eaten and slowed down growth. Glucosinolates were separated and quantified by gas chromatography. There are 132mol/g dry matter in green leaves. In multiple choice tests, with paper disks, glucosinolate extracts were phagostimulant at a low concentration (21mol/g dry matter) and repulsive at a higher one (214mol/ g dry matter). Biting behavior onS. purpurea was recorded and analyzed on video. The importance ofSchouwia purpurea in desert locust habitats and its defenses is discussed. 相似文献
37.
Ana Paula Vieira Soares Manuel Farinha Portela Alain Kiennemann 《Catalysis Reviews》2005,47(1):125-174
This review deals with the important industrial reaction of formaldehyde manufacture by methanol oxidation over iron molybdate catalysts. Detailed reference is made to the used catalyst, preparation techniques (coprecipitation, sol-gel like, mechanical mixing, etc.) including unsupported and supported catalysts, promoters and characterization methods. The controversial active phase assignment (stoichiometric versus Mo rich iron molybdate) is discussed. The proposed reaction mechanisms and kinetic laws for the main and side reactions are examined. The catalyst deactivation processes are reviewed and the role of Mo excess on these processes is underlined. Finally conclusions and perspectives are presented. 相似文献
38.
A kinetic study of the anionic polymerization of ethylene oxide has been made in tetrahydrofuran at 20°C, with the cryptate Cs+ + [TC] as counterion, [TC] being a spheroidal macrotricyclic ligand. Conductance measurements have been made on THF solutions of ?4BCs + [TC]. Ionic associations higher than cryptated ion pairs are negligible for living end concentrations lower than 3 × 10?4 moll?1. k± and the alkoxide ion pair dissociation constant KD were determined from both sets of kinetic data obtained with and without added salt knowing the value of k? from kinetic data performed with K+ + [222] as counterion. Free alkoxide ions are about twenty times more reactive than cryptated caesium ion pairs. 相似文献
39.
Alain Le Mehaute Gilles Crepy Georges Marcellin Thierry Hamaide Alain Guyot 《Polymer Bulletin》1985,14(3-4):233-237
Summary The room temperature conductivity of lithium salts dissolved in polyethylene oxide, proposed as polymer electrolytes, is shown to decrease drastically upon storage. The crystallization process, which is responsible for that ageing, can be blocked, if two further components are added : an elastomer copolymer butadiene-acrylonitrile and a macromer of polyoxyethylene. In addition, a crosslinking process must be carried out. 相似文献
40.
Racemic -methyl--n-propyl--propiolactone is readily polymerized with zinc and cadmium chiral glycolates leading to optically active polyesters. The stereoelectivities observed are lower than for oxiranes and thiiranes with the same initiator system. A value of rotatory power for pure enantiomer o, is deduced from NMR measurements in the presence of chiral solvent. The structure of polymers is discussed on the basis of NMR results. 相似文献