Polarity Effect in a Sn3Ag0.5Cu/Bismuth Telluride Thermoelectric System

This study investigates electromigration in Bi₂Te₃ thermoelectric (TE) material systems and the effectiveness of the diffusion barrier under current. The Peltier effect on the interfacial reaction was decoupled from the effect of electromigration. After connecting p- and n-type Bi₂Te₃ to Sn3Ag0.5Cu (SAC305) solders, different current densities were applied at varying temperatures. The Bi₂Te₃ samples were fabricated by the spark plasma sintering technique, and an electroless nickel-phosphorous (Ni-P) layer was deposited at the solder/TE interfaces. The experimental results confirm the importance of the Ni diffusion barrier in joint reliability. Intermetallic compound layers (Cu,Ni)₆Sn₅ and NiTe formed at the solder/Ni-P and Ni-P/substrate interfaces, respectively. The experimental results indicate that the mechanism of NiTe and (Cu,Ni)₆Sn₅ compound growth was dominated by the Peltier effect at high current density. When the current density was low, the growth of NiTe was affected by electromigration but the changes of thickness for (Cu,Ni)₆Sn₅ were not obvious.     

Reducing Encoder Bit-Rate Variation in MPEG Video

A shortcoming of current video transmission using the MPEG standard is that its encoder produces a variable bit rate (VBR). Due to this, the encoder output has to be buffered and released over the network at a constant rate. This buffering of the encoder output introduces an additional delay between the encoding and decoding phases of the video transmission. To remedy this problem, we present a strategy to distribute the load produced by the encoder as evenly as possible, i.e., try to have a constant bit rate (CBR). This is done by treating the slices in each frame separately while compressing them and then mixing the different kinds of slices that are sent over the network. The resulting load variation is much more uniform, reducing the buffering delay and making future bandwidth requirement estimates more accurate.This material is based upon work supported in part by the National Science Foundation under Award No. IRI-9526004, by the Texas Advanced Research Program under Grant No. 3652270, and by a grant from the University of Houston Institute of Space Systems Operations. Rajat Agarwal is now with Lucent Technologies. This paper is an extended version of a shorter paper presented at IEEE ICMCS 1999.Albert Mo Kim Cheng received the B.A. with Highest Honors in Computer Science at age 19, graduating Phi Beta Kappa, the M.S. in Computer Science with a minor in Electrical Engineering at age 21, and the Ph.D. in Computer Science at age 25, all from The University of Texas at Austin, where he held a GTE Foundation Doctoral Fellowship. Dr. Cheng is currently a tenured Associate Professor in the Department of Computer Science at the University of Houston, where he is the founding Director of the Real-Time Systems Laboratory. He has served as a technical consultant for several organizations, including IBM, and was also a visiting faculty in the Departments of Computer Science at Rice University (2000) and at the City University of Hong Kong (1995).He is the author/co-author of over seventy refereed publications in IEEE Transactions on Software Engineering, IEEE Transactions on Knowledge and Data Engineering, Real-Time Systems Symposium, Real-Time and Embedded Technology and Applications Symposium, and other leading conferences. One of his recent work presents a timing analysis of the NASA X-38 Space Station Crew Return Vehicle Avionics, which contains a fault-tolerant distributed system.Dr. Cheng has received numerous awards, including the National Science Foundation Research Initiation Award (now known as the NSF CAREER award). He has been invited to present seminars and tutorials at over 30 conferences, and has given invited seminars/keynotes at over 20 universities and organizations, most recently at ICEIS, Ecole Superieure de l Ouest (ESEO), Angers, France, April 2003. His next invited keynote speech will be at the 1st Intl. Conf. on Informatics in Control, Automation and Robotics (ICINCO), Setubal, Portugal, August 2004.He is an Associate Editor of the IEEE Transactions on Software Engineering (1998-2003), a Guest Co-Editor of two IEEE TSE Special Issues on Software and Performance (Nov. and Dec. 2000), an Associate Editor of the International Journal of Computer and Information Science, the work-in-progress program chair of the 2001 IEEE-CS Real-Time Technology and Applications Symposium, the work-in-progress session chair of the 2003 IEEE-CS Real-Time Systems Symposium, and the invited special panel chair for the software engineering for multimedia session at the 1999 IEEE-CS International Conference on Multimedia Computing Systems (ICMCS). Currently, he is a member of the program committees of RTSS, RTAS, ICEIS, ICECCS, RTAS, LCN, COMPSAC, ICCCN, AIA, DBA, PDCN, SE, and ICINCO. Dr. Cheng is an Honorary Member of the Institute for Systems and Technologies of Information, Control and Communication (INSTICC). He is a Senior Member of the IEEE.Dr. Cheng is the author of several book chapters on E-commerce/Enterprise Information Systems, and an article entitled Embedded OS, in the upcoming Encyclopedia of Computer Science and Engineering (John Wiley & Sons). He is the author of the new senior/graduate-level textbook entitled Real-Time Systems: Scheduling, Analysis, and Verification (John Wiley & Sons). cheng@cs.uh.eduRajat Agarwal received the M.S. in Computer Science from the University of Houston. He is currently a Member of the Technical Staff at Lucent Technologies. His research interest is in real-time multimedia systems.     

Photoresponsive Sponge‐Like Coating for On‐Demand Liquid Release

Many publications report on stimuli responsive coatings, but only a few on the controlled release of species in order to change the coating surface properties. A sponge‐like coating that is able to release and absorb a liquid upon exposure to light has been developed. The morphology of the porous coating is controlled by the smectic liquid crystal properties of the monomer mixture prior to its polymerization, and homeotropic order is found to give the largest contraction. The fast release of the liquid can be induced by a macroscopic contraction of the coating caused by a trans to cis conversion of a copolymerized azobenzene moiety. The liquid secretion can be localized by local light exposure or by creating a surface relief. The uptake of liquid proceeds by stimulating the back reaction of the azo compound by exposure at higher wavelength or by thermal relaxation. The surface forces of the sponge‐like coating in contact with an opposing surface can be controlled by light‐induced capillary bridging revealing that the controlled release of liquid gives access to tunable adhesion.     

Cray/Blitz—1984 chess champion

The chess program “Cray Blitz” is the current World Computer Chess Champion and North American Computer Chess Champion (ACM). The program has also played in human chess tournaments and is a chess master. At speed chess, where its ability to perform very accurate analysis is particularly important, it has maintained a performance rating of over 2600 for the past two years. This indicates that at speed chess, the program is one of the top players, electronic or human, in the world. It is currently running on a Cray XMP-48 computer system and has been designed around the parallelism that the XMP architecture provides.     

Modified Goodness-of-Fit Tests for Gamma Distributions with Unknown Location and Scale Parameters

The common Kolmogorov-Smirnov, Anderson-Darling, and Cramer-von Mises goodness-of-fit tests require continuous underlying distributions with known parameters. This paper gives tables of critical values for these tests for gamma distributions with unknown location and scale parameters and known shape parameters. The powers of these tests are given for a number of alternative distributions. A relation between the critical values and the inverse square of the shape parameter is presented. For larger sample sizes, the modified CvM test is usually the most powerful of the three tests. One exception is for the alternative of a lognormal distribution where the modified AD test is most powerful. The equation, C = ao + a1(1/?2) describes the relation between critical value and shape parameter quite well.     

Intracranial Pressure Telemetry System Using Semicustom Integrated Circuits

A new generation of implantable, telemetric transmitters for intracranial pressure (ICP) measurements have been developed. A unique technique used in packaging the silicon piezoresistive pt essure transducer provides excellent long-term stability. Pulse code modulation is used for data transmission over a radio frequency (RF) link. To minimize the component count, two semicustom, bipolar integrated circuits are used. The transmitter electronics are housed inside a 29 ×20 ×7 mm titanium package along with the pressure transducer and two lithium batteries. Even though the transmitter consumes less than 0.4 mW of power, it is turned on remotely via RF signal transduction only on demand in order to extend the lifetime of the batteries to years. The pressure input of the transmitter has a dynamic range of ?100- +200 mmHg with a 0.3 mmHg resolution and a 1 mmHg accuracy. Long-term in vitro and in vivo pressure baseline stabilities of better than 1 and 2 mmHg per month, respectively, have been achieved.     

Atomic layer deposition of aluminum oxide films for carbon nanotube network transistor passivation

Ultra-thin (2-5 nm thick) aluminum oxide layers were grown on non-functionalized individual single walled carbon nanotubes (SWCNT) and their bundles by atomic layer deposition (ALD) technique in order to investigate the mechanism of the coating process. Transmission electron microscopy (TEM) was used to examine the uniformity and conformality of the coatings grown at different temperatures (80 degrees C or 220 degrees C) and with different precursors for oxidation (water and ozone). We found that bundles of SWCNTs were coated continuously, but at the same time, bare individual nanotubes remained uncoated. The successful coating of bundles was explained by the formation of interstitial pores between the individual SWCNTs constituting the bundle, where the precursor molecules can adhere, initiating the layer growth. Thicker alumina layers (20-35 nm thick) were used for the coating of bottom-gated SWCNT-network based field effect transistors (FETs). ALD layers, grown at different conditions, were found to influence the performance of the SWCNT-network FETs: low temperature ALD layers caused the ambipolarity of the channel and pronounced n-type conduction, whereas high temperature ALD processes resulted in hysteresis suppression in the transfer characteristics of the SWCNT transistors and preserved p-type conduction. Fixed charges in the ALD layer have been considered as the main factor influencing the conduction change of the SWCNT network based transistors.     

Permeability of high-performance concrete subjected to elevated temperature (600 °C)

Permeability is one of the most important parameters to quantify the durability of high-performance concrete. Permeability is closely related with the spalling phenomenon in concrete at elevated temperature. This parameter is commonly measured on non-thermally damaged specimens. This paper presents the results of an experimental investigation carried out to study the effect of elevated temperature on the permeability of high-performance concrete. For this purpose, three types of concrete mixtures were prepared: (i) control high-performance concrete; (ii) high-performance concrete incorporating polypropylene fibres; and (iii) high-performance concrete made with lightweight aggregates. A heating–cooling cycle was applied on 160 × 320 mm, 110 × 220 mm, and 150 × 300 mm cylindrical specimens. The maximum test temperature was kept as either 200 or 600 °C. After the thermal treatment, 65 mm thick slices were cut from each cylinder and dried prior to being subjected to permeability test. Results of thermal gradients in the concrete specimens during the heating–cooling cycles, compressive strength, and splitting tensile strength of concrete mixtures are also presented here. A relationship between the thermal damage indicators and permeability is presented.     

Tow impregnation during resin transfer molding of bi-directional nonwoven fabrics

A model has been developed for analyzing resin impregnation of fiber tows during resin transfer molding of bi-directional nonwoven fiber performs. The model is based on the existence of two main regions of resin flow: the macropore space formed among fiber tows and the micropore space formed among individual fiber filaments within a tow. The large difference in permeability between these two regions of flow leads to the potential for void formation during resin transfer molding. The model was formulated for both constant flow rate and constant pressure mold filling. For ambient pressure mold filling, the model predicts a difference in the size of the voids and distribution between axial tows (oriented along the flow direction) and transverse tows (oriented in the transverse direction). When vacuum is imposed on the mold, the model predicts the same resin impregnation behavior for both axial and transverse tows. Furthermore, given sufficient time, voids generated under vacuum mold filling will eventually collapse because of the absence of an opposing internal void pressure. In addition to insights on void formation, the model also provides a basis for the study of the relationship between resin transfer molding parameters and the resin impregnation process.     

Diazoverbindungen. 72. (Diazoalkyl)phosphane – Synthese durch elektrophile Diazoalkansubstitution und oxidative Additionsreaktionen am Phosphor

Diazo Compounds. 72. Diazoalkylphosphanes – Synthesis by Electrophilic Diazoalkane Substitution and Oxidative Addition Reactions at Phosphorus Electrophilic diazoalkane substitution of the diazomethyl compounds 1a,b with the chloro phosphanes 2a-o in the presence of lithium diethylamide yields the diazoalkyl phosphanes 3a-z . Oxidative addition of oxygen, sulfur and selenium at phosphorus leads into the series of oxo, thioxo and selenoxo phosphanes having diazoalkyl substituents ( 4a-d, 5a-m and 7a-d ). The silyl group of 5n,o is cleaved by chromatography on aluminium oxide to yield the (diazomethyl)phosphane sulfides 6a,b .