Entwicklung eines Analysenverfahrens zur Bestimmung von metallischem und chemisch gebundenem Calcium in Stahl

Durch Kombination eines Plasmaspektrometers (ICP) mit einer neuen Apparatur zur elektrothermischen Verdampfung konnte der Gehalt an metallischem Calcium in niedrig legiertem, calciumbehandeltem Stahl bestimmt werden. Die kontrollierte Erwärmung von Stahlspänen auf 2 000°C führt zur vollständigen Verdampfung des elementaren Calciums, während das chemisch gebundene Calcium bei dieser Temperatur nicht verdampft. Das verdampfte Calcium wurde mit Argon in das Plasmaspektrometer transportiert, und das erzeugte Emissionsspektrum wurde zur quantitativen Auswertung genutzt.     

A regularized graph layout framework for dynamic network visualization

Many real-world networks, including social and information networks, are dynamic structures that evolve over time. Such dynamic networks are typically visualized using a sequence of static graph layouts. In addition to providing a visual representation of the network structure at each time step, the sequence should preserve the mental map between layouts of consecutive time steps to allow a human to interpret the temporal evolution of the network. In this paper, we propose a framework for dynamic network visualization in the on-line setting where only present and past graph snapshots are available to create the present layout. The proposed framework creates regularized graph layouts by augmenting the cost function of a static graph layout algorithm with a grouping penalty, which discourages nodes from deviating too far from other nodes belonging to the same group, and a temporal penalty, which discourages large node movements between consecutive time steps. The penalties increase the stability of the layout sequence, thus preserving the mental map. We introduce two dynamic layout algorithms within the proposed framework, namely dynamic multidimensional scaling and dynamic graph Laplacian layout. We apply these algorithms on several data sets to illustrate the importance of both grouping and temporal regularization for producing interpretable visualizations of dynamic networks.     

A Distributed Ant Algorithm for\protect Efficiently Patrolling a Network

We consider the problem of patrolling—i.e. ongoing exploration of a network by a decentralized group of simple memoryless robotic agents. The model for the network is an undirected graph, and our goal, beyond complete exploration, is to achieve close to uniform frequency of traversal of the graphs edges. A simple multi-agent exploration algorithm is presented and analyzed. It is shown that a single agent following this procedure enters, after a transient period, a periodic motion which is an extended Eulerian cycle, during which all edges are traversed an identical number of times. We further prove that if the network is Eulerian, a single agent goes into an Eulerian cycle within 2|E|D steps, |E| being the number of edges in the graph and D being its diameter. For a team of k agents, we show that after at most 2( 1 + 1/k) |E|D steps the numbers of edge visits in the network are balanced up to a factor of two. In addition, various aspects of the algorithm are demonstrated by simulations.     

Cross-sectional investigation of task demands and musculoskeletal discomfort among restaurant wait staff

A cross-sectional study of task demands and musculoskeletal discomfort among a sample of 100 wait staff in ten casual dining restaurants was conducted. In addition to answering a questionnaire about musculoskeletal discomfort and symptoms experienced in the past 12 months and attributed to work, subjects were asked about various aspects of their jobs, such as shift length, number of shifts per week and safety training. The managers of the restaurants were also interviewed to gather basic information on factors such as work hours, alternative duty availability and safety practices. When asked to rank the three most important causes of injuries, the responses of both managers and wait staff were congruent with Bureau of Labor Statistics (USA) data for 1999 on the nature of injuries and attributed exposures, with slips and falls, musculoskeletal disorders and acute injuries (e.g. burns, cuts) highlighted. Of the 100 subjects, 42% reported experiencing musculoskeletal symptoms in the past year, with the lower back area (18%) and shoulder (11%) with the most frequent symptoms reported in the responses. Although many of the materials handling tasks were not excessive, the heavier tray lifts and carries are a cause for concern. There are also slip and fall issues that influence the risks of these tasks. Future research needs, including addressing the mismatch between more common materials handling assessment tools and the nature of food serving tasks, are discussed.     

Sex-Based Selectivity of PPARγ Regulation in Th1, Th2, and Th17 Differentiation

Peroxisome proliferator-activated receptor gamma (PPARγ) has recently been recognized to regulate adaptive immunity through Th17 differentiation, Treg functions, and T_FH responses. However, its role in adaptive immunity and autoimmune disease is still not clear, possibly due to sexual differences. Here, we investigated in vitro treatment study with the PPARγ agonist pioglitazone to compare Th1, Th2, and Th17 differentiation in male and female mouse splenic T cells. Pioglitazone treatment significantly inhibited various effector T cell differentiations including Th1, Th2, and Th17 cells from female naïve T cells, but it selectively reduced IL-17 production in male Th17 differentiation. Interestingly, pioglitazone and estradiol (E2) co-treatment of T cells in males inhibited differentiation of Th1, Th2, and Th17 cells, suggesting a mechanism for the greater sensitivity of PPARγ to ligand treatment in the regulation of effector T cell differentiation in females. Collectively, these results demonstrate that PPARγ selectively inhibits Th17 differentiation only in male T cells and modulates Th1, Th2, and Th17 differentiation in female T cells based on different level of estrogen exposure. Accordingly, PPARγ could be an important immune regulator of sexual differences in adaptive immunity.     

Auswirkungen des Pilotversuchs BDA auf die Grundwasserverhältnisse

This study investigates the impact of the sum of the structural measures on groundwater conditions in the context of the pilot test stretch in Bad Deutsch-Altenburg (BDA). The methodological approach was a comparison of the conditions for the exchange processes between groundwater and river water pre and post the selected structural work. The analyses of the groundwater conditions pre and post the structural work in the BDA pilot test show no substantial impact on the groundwater conditions so far. This is largely due to the effluent conditions between groundwater and surface water along this stretch of the Danube. The transfer of these results to other sections of the Danube with other boundary conditions is only partly possible. It appears that the continuous interaction of groundwater with the waters of the Danube and its branches is of significant importance for the conservation of the groundwater conditions. Therefore, from a water-management point of view, further measures against a decline in surface-water levels are essential for conserving the groundwater conditions.     

Outdoor attractancy of males ofMatsucoccus josephi (Homoptera: Matsucoccidae) andElatophilus hebraicus (Hemiptera: Anthocoridae) to synthetic female sex pheromone ofMatsucoccus josephi

The active component of the sex pheromone ofMatsucoccus josephi is (2E,6E,8E)-5,7-dimethyl-2,6,8-decatrien-4-one; the chemical is also a powerful kairomone of adult males and females of the bugElatophilus hebraicus the principal predator ofM. josephi. The presence of theZ isomer (2E,6Z,8E)-5,7-dimethyl-2,6,8-decatrien-4-one does not interfere with the attractancy of the activeE component forM. josephi males or the bug. Our results show a clear dose-response between trap catch ofM. josephi males andE. hebraicus. Conversely, increasing amounts of theZ isomer in the mixture did not affect the attraction of the scale insect males or the bug. The catch ofM. josephi males did not differ significantly among traps of different color, and was significantly higher with traps attached to the tree trunk than those suspended between trees. Comparison of the catch ofM. josephi among the three forests and between pine species suggests that the level of infestation ofPinus halepepsis andPinus brutia ssp.brutia is similar, despite the fact that the latter pine is resistant to the scale insect. Both sexes ofE. hebraicus were trapped in much lower numbers at the more infested sites. This may be related to interference with the activity ofE. hebraicus due to deterioration and drying of parts of the tree crowns and heavy colonization by generalist predators in injured trees.     

Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide

Reduction of a colloidal suspension of exfoliated graphene oxide sheets in water with hydrazine hydrate results in their aggregation and subsequent formation of a high-surface-area carbon material which consists of thin graphene-based sheets. The reduced material was characterized by elemental analysis, thermo-gravimetric analysis, scanning electron microscopy, X-ray photoelectron spectroscopy, NMR spectroscopy, Raman spectroscopy, and by electrical conductivity measurements.     

Inhibiting and deactivating effects of water on the selective catalytic reduction of nitric oxide with ammonia over MnOx/Al2O3

The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnO_x-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water.