Barrier properties of poly(vinyl alcohol) membranes containing carbon nanotubes or activated carbon

Carbon nanotube addition has been shown to improve the mechanical properties of some polymers. Because of their unique adsorptive properties, carbon nanotubes may also improve the barrier performance of polymers used in contaminant containment. This study compares the barrier performance of poly(vinyl alcohol) (PVA) membranes containing single-walled carbon nanotubes (SWCNTs) to that for PVA containing powdered activated carbon (PAC). Raw and surface-functionalized versions of each sorbent were tested for their abilities to adsorb 1,2,4-trichlorobenzene and Cu(2+), representing the important hydrophobic organic and heavy metal contaminant classes, as they diffused across the PVA. In both cases, PAC (for 1,2,4-trichlorobenzene) and functionalized PAC (for Cu(2+)) outperformed SWCNTs on a per mass basis by trapping more of the contaminants within the barrier membrane. Kinetics of sorption are important in evaluating barrier properties, and poor performance of SWCNT-containing membranes as 1,2,4-TCB barriers is attributed to kinetic limitations.     

Retention and Distribution of 1-Naphthol and Naphthol Polymerization Products on Surface Soils

Sorption and extractability of naphthol and naphthol polymerization products (NPP) were evaluated in two surface soils. NPP were generated by the addition of horseradish peroxidase and H2O2 to naphthol solutions in contact with the surface soils. While NPP retention on the forest soil was lower compared to the parent naphthol, no difference in sorption of naphthol and NPP was observed in the agricultural soil. The agricultural soil retained more naphthol and NPP than the forest soil. The NPP sorption behavior noted in this study was in contrast to that of phenol polymerization products observed by other researchers. The presence of phenol and 2,4-dichlorophenol as cosolutes had no significant impact on naphthol or NPP retention on the two soils, and naphthol was more easily extracted from both soils whenever phenol was present as a cosolute. Characterization of the naphthol polymerization products using reverse-phase high-pressure liquid chromatography and octanol-water partitioning indicated that significant fractions of the water-soluble and insoluble NPP were comprised of oligomers that were more polar than the parent 1-naphthol. This decrease in polarity upon polymerization is believed to have been responsible for the NPP retention and binding behavior observed in this study.     

De-agglomeration of thorium oxalate - a method for the synthesis of sinteractive thoria

Thorium oxalate was obtained by precipitation in water and in non-aqueous solvents and de-agglomerated by ultrasonication in both aqueous as well as non-aqueous media. Sinteractive thoria (crystallite size 6-20 nm) obtained from the de-agglomerated thorium oxalate was characterised for residual carbon, crystallite size, specific surface area, particle size distribution and bulk density. Microstructure of the precursor and the product was studied using TEM and HRTEM. The morphology of the sintered pellets was studied using SEM. The reactivity of the calcined powders was determined by measuring the density of the sintered compacts. The solvent used for de-agglomeration was found to have significant influence on the microstructure of the powders. Thoria derived through aqueous precipitation route could be sintered to a density of 9.7 Mg m⁻³ at 1673 K. It was demonstrated that ultrasonic de-agglomeration could be a useful method for obtaining sinteractive thoria.     

Epidemiological studies of blood groups in the district of Bankura with special reference to tribals

Distribution of ABO blood groups was studied in 4301 subjects, both tribals and non-tribals of the district of Bankura in West Bengal. It was observed that group 'O' blood was found in most cases and group 'AB' was seen in least number of cases. It was also found that there was no significant difference in distribution of blood groups between the tribals and non-tribals.     

Use of waste materials--Bottom Ash and De-Oiled Soya, as potential adsorbents for the removal of Amaranth from aqueous solutions

Bottom Ash, a power plan t waste material and De-Oiled Soya, an agriculture waste product were successfully utilized in removing trisodium 2-hydroxy-1-(4-sulphonato-1-naphthylazo)naphthalene-3,6-disulphonate--a water-soluble hazardous azo dye (Amaranth). The paper incorporates thermodynamic and kinetic studies for the adsorption of the dye on these two waste materials as adsorbents. Characterization of each adsorbent was carried out by I.R. and D.T.A. curves. Batch adsorption studies were made by measuring effects of pH, adsorbate concentration, sieve size, adsorbent dosage, contact time, temperature etc. Specific rate constants for the processes were calculated by kinetic measurements and a first order adsorption kinetics was observed in each case. Langmuir and Freundlich adsorption isotherms were applied to calculate thermodynamic parameters. The adsorption on Bottom Ash takes place via film diffusion process at lower concentrations and via particle diffusion process at higher concentrations, while in the case of De-Oiled Soya process only particle diffusion takes place in the entire concentration range.     

Effect of fiber loading and orientation on mechanical and erosion wear behaviors of glass–epoxy composites

For a composite material, its mechanical behavior and surface damage by solid particle erosion depend on many factors. One of the most important factors is the fiber content. Similarly, these properties are also greatly affected by the fiber orientation. In this work, a series of experiments were carried out to investigate the influence of fiber loading and fiber orientation on mechanical and erosion behavior of glass fiber‐reinforced epoxy composites. The composites were fabricated with three different fiber loadings (20, 30, and 40 wt%) and at four different fiber orientations (15°, 30°, 45°, and 60°). The conclusions drawn on the basis of the experimental findings are discussed, and composite with 30° fiber orientation shows better microhardness compared with other fiber orientations irrespective of fiber loading. Similar observations are also noticed for other mechanical properties of the composites, such as tensile strength, flexural strength, interlaminar shear strength, impact strength, etc. Finally, the morphology of eroded surfaces is examined using scanning electron microscopy (SEM), and possible erosion mechanisms are identified. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers     

Soft Error Rate Reduction Using Circuit Optimization and Transient Filter Insertion

This paper describes a tunable transient filter (TTF) design for soft error rate reduction in combinational logic circuits. TTFs can be inserted into combinational circuits to suppress propagated single-event transients (SETs) before they can be captured in latches or flip-flops. TTFs are tuned by adjusting the maximum width of the propagated SET that can be suppressed. A TTF requires 6–14 transistors, making it an attractive cost-effective option to reduce the soft error rate in combinational circuits. A global optimization approach based on geometric programming that integrates TTF insertion with dual-V _DD and gate sizing is described. Simulation results for the 65 nm process technology indicate that a 17–48× reduction in the soft error rate can be achieved with this approach.     

Demineralization of cocoons of Antheraea assamensis Helfer (muga) for effective reeling

Muga cocoons are evidenced of possessing heavy deposition of minerals (such as calcium oxalate) on its surface. This mineral deposition restricts reeling of muga fiber in comparison to the cocoons of mulberry silkworm. In this study, we have attempted to wash out the mineral layer using various chemical and natural agents like ethylenediaminetetraacetic acid (EDTA), potassium carbonate, citric acid, extract of Musa balbisiana (‘kolakhar’), and Citrus limon (lemon), respectively. It is observed that both the natural and chemical agents carefully removes the mineral deposition, leaving the gummy sericin substantially intact, preventing entanglement of fibroin brins, and permitting wet reeling with very minimum number of fiber breaks compared to commercial degumming. The removal of granular minerals was evidenced by surface morphology and FTIR spectroscopy of demineralized cocoon fiber. Further, the tensile strength of demineralized fiber showed superiority in contrast to sodium carbonate degummed fiber. Under the implemented experimental conditions ‘kolakhar’ functioned as the most efficient demineralizing agent amongst all. Therefore, the present study demonstrates an improved method for softening wild silk cocoons in contrast to harsh degumming for obtaining long continuous reeled fiber threads with very less number of fiber breaks and enhanced mechanical strength.