Electrodeposited Co–Ni Films: Electrolyte pH—Property Relationships

The effect of electrolyte pH on structural, magnetic, and magnetoresistive properties of Co–Ni films was studied. The films were deposited on a titanium substrate from the electrolytes with 4.10±0.05, 3.14±0.05, and 2.14±0.05 pH values. The Co–Ni system exhibited anomalous codeposition. Structural analysis indicated that the films had (220) preferential oriented face-centered cubic structure and their surface became smoother as the electrolyte pH decreased. The compositional and magnetic analysis revealed that an increase of the Co content in the films resulted in an increase in saturation magnetization and coercivity. Magnetoresistance curves indicated that the films show anisotropic magnetoresistance. Longitudinal and transversal magnetoresistances were found to be the highest values of 8 % and 7 %, respectively, for the film deposited at a low electrolyte pH. The variation of the Co:Ni ratio in deposits caused by the change of the electrolyte pH has a considerable effect on the properties of the films.     

Electrodeposited Cobalt Films: Alteration Caused by the Electrolyte pH

Cobalt (Co) films were electrodeposited on polycrystalline copper substrates at different pH values. It is observed that the crystal structure of the films converts from hexagonal close-packed (hcp) to a mixed phase of face centered cubic and hcp as the electrolyte pH decreases. The grain size calculated from the X-ray diffraction patterns decreases with the decrease of electrolyte pH. The surface of the films grown at a high pH is more uniform than that of the films grown at a low pH. The saturation magnetization and the coercivity decrease as the electrolyte pH decreases. The high coercivity value at high pH corresponds to the hcp crystal structure of the films as well as the large grain size of Co clusters. Magnetic measurements also reveal that the easy axis direction of magnetization is parallel to the film plane for all films since the higher remanent magnetization and lower saturation field are observed in parallel hysteresis loops.     

Behavior of FRP-Retrofitted Joints Built with Plain Bars and Low-Strength Concrete

Two series of tests on eight full-scale exterior beam-column joint subassemblages built with plain bars and low-strength concrete were conducted. No transverse reinforcement was present in the joint cores. In the first series of tests, which included three specimens, the behavior of joints before fiber-reinforced polymer (FRP) retrofitting was investigated. In the second series, which included five specimens, the behavior of the FRP-retrofitted joints was investigated. The six specimens consisted of a column, an in-plane beam, a transverse beam, and a slab part, and two specimens were plane members without transverse beams and slabs. The utilized retrofitting scheme is easily applicable for actual exterior beam-column joints, even in the presence of a transverse beam and a slab. Two types of strength limitation were observed for specimens in the first series. The strength of the specimen with beam longitudinal bars sufficiently anchored to the joint core was limited by the shear strength of the joint. The strengths of the other two specimens were limited by the slip of the beams’ longitudinal bars at their anchorages. In the second series of tests, significantly better performance was obtained both in terms of shear strength and ductility, provided that the slip of the beam bars was prevented. Furthermore, by using a simple theoretical algorithm based on truss analogy, the strength and deformability characteristics of the tested reference and FRP-retrofitted joints are predicted with reasonable accuracy. The same algorithm is used for predicting the joint shear strength of specimens tested by other researchers, and satisfactory agreement is obtained between the predictions and test results.     

Preparation and characterization of superhydrophobic surfaces based on hexamethyldisilazane-modified nanoporous alumina

Superhydrophobic nanoporous anodic aluminum oxide (alumina) surfaces were prepared using treatment with vapor-phase hexamethyldisilazane (HMDS). Nanoporous alumina substrates were first made using a two-step anodization process. Subsequently, a repeated modification procedure was employed for efficient incorporation of the terminal methyl groups of HMDS to the alumina surface. Morphology of the surfaces was characterized by scanning electron microscopy, showing hexagonally ordered circular nanopores with approximately 250 nm in diameter and 300 nm of interpore distances. Fourier transform infrared spectroscopy-attenuated total reflectance analysis showed the presence of chemically bound methyl groups on the HMDS-modified nanoporous alumina surfaces. Wetting properties of these surfaces were characterized by measurements of the water contact angle which was found to reach 153.2 ± 2°. The contact angle values on HMDS-modified nanoporous alumina surfaces were found to be significantly larger than the average water contact angle of 82.9 ± 3° on smooth thin film alumina surfaces that underwent the same HMDS modification steps. The difference between the two cases was explained by the Cassie-Baxter theory of rough surface wetting.     

Methods to improve efficiency of four stroke, spark ignition engines at part load

The four stroke, spark ignition (SI) engine pressure–volume diagram (p–V) contains two main parts. They are the compression–combustion–expansion (high pressure loop) and the exhaust-intake (low pressure or gas exchange loop) parts. The main reason for efficiency decrease at part load conditions for these types of engines is the flow restriction at the cross sectional area of the intake system by partially closing the throttle valve, which leads to increased pumping losses and to increased low pressure loop area on the p–V diagram. Meanwhile, the poorer combustion quality, i.e. lower combustion speed and cycle to cycle variations, additionally influence these pressure loop areas. In this study, methods for increasing efficiency at part load conditions and their potential for practical use are investigated. The study also includes a review of the vast literature on the solution of this problem. This investigation shows that the potential for increasing the efficiency of SI engines at part load conditions is not yet exhausted. Each method has its own advantages and disadvantages. Among these, the most promising methods to decrease the fuel consumption at part load conditions are stratified charge and variable displacement engines. When used in combination, the other listed methods are more effective than their usage alone.     

Synthesis of Alcohols via a Rhodium‐Catalyzed Hydroformylation– Reduction Sequence using Tertiary Bidentate Amine Ligands

The synthesis of alcohols from aromatic olefins is described using a rhodium‐catalyzed hydroformylation–reduction sequence with the assistance of a tertiary diamine ligand. The alcohols are produced in excellent branched to linear ratios and in good to excellent isolated yields. In all cases no aldehyde product, from hydroformylation, or alkyl product, from olefin reduction, was detected.     

Effect of pre-slaughter management regarding transportation and time in lairage on certain stress parameters, carcass and meat quality characteristics in Kivircik lambs

Thirty Kivircik lambs were used to investigate effect of pre-slaughter treatment on certain haematological and biochemical parameters, carcass and meat quality characteristics. Lambs were divided into three treatments: 75 min transport and lairage for 18 h (TS-L18 h); 75 min transport and lairage for 30 min (TS-L30 min) and no pre-slaughter transport and lairage for 30 min (NTS). Treatment, as a main effect, did not influence haematological and biochemical parameters, but sampling time significantly affected these parameters, except total protein. Plasma cortisol concentration at exsanguination in TS-18 h, TS-30 min and NTS treatments were 117.34, 119.23 and 72.51 ng/ml, respectively. pH of longissimus dorsi muscle was higher in TS-L30 min than other treatments. TS-L30 min lambs had the highest shear force value, the lowest WHC and cooking loss. TS-L30 min treatment yielded the darkest meat immediately after cutting and 1 h later. Meat redness, yellowness and chroma values were similar in treatments.