Manipulate the Electronic and Magnetic States in NiCo2O4 Films through Electric‐Field‐Induced Protonation at Elevated Temperature

Ionic‐liquid‐gating‐ (ILG‐) induced proton evolution has emerged as a novel strategy to realize electron doping and manipulate the electronic and magnetic ground states in complex oxides. While the study of a wide range of systems (e.g., SrCoO_2.5, VO₂, WO₃, etc.) has demonstrated important opportunities to incorporate protons through ILG, protonation remains a big challenge for many others. Furthermore, the mechanism of proton intercalation from the ionic liquid/solid interface to whole film has not yet been revealed. Here, with a model system of inverse spinel NiCo₂O₄, an increase in system temperature during ILG forms a single but effective method to efficiently achieve protonation. Moreover, the ILG induces a novel phase transformation in NiCo₂O₄ from ferrimagnetic metallic into antiferromagnetic insulating with protonation at elevated temperatures. This study shows that environmental temperature is an efficient tuning knob to manipulate ILG‐induced ionic evolution.     

GO-modified flexible polymer nanocomposites fabricated via 3D stereolithography

Graphene oxide (GO) induced enhancement of elastomer properties showed a great deal of potential in recent years, but it is still limited by the barrier of the complicated synthesis processes. Stereolithography (SLA), used in fabrication of thermosets and very recently in “flexible” polymers with elastomeric properties, presents itself as simple and user-friendly method for integration of GO into elastomers. In this work, it was first time demonstrated that GO loadings can be incorporated into commercial flexible photopolymer resins to successfully fabricate GO/elastomer nanocomposites via readily accessible, consumer-oriented SLA printer. The material properties of the resulting polymer was characterized and tested. The mechanical strength, stiffness, and the elongation of the resulting polymer decreased with the addition of GO. The thermal properties were also adversely affected upon the increase in the GO content based on differential scanning calorimetry and thermogravimetric analysis results. It was proposed that the GO agglomerates within the 3D printed composites, can result in significant change in both mechanical and thermal properties of the resulting nanocomposites. This study demonstrated the possibility for the development of the GO/elastomer nanocomposites after the optimization of the GO/“flexible” photoreactive resin formulation for SLA with suitable annealing process of the composite in future.     

Interplay of wrinkles, strain, and lattice parameter in graphene on iridium

Following graphene growth by thermal decomposition of ethylene on Ir(111) at high temperatures we analyzed the strain state and the wrinkle formation kinetics as function of temperature. Using the moiré spot separation in a low energy electron diffraction pattern as a magnifying mechanism for the difference in the lattice parameters between Ir and graphene, we achieved an unrivaled relative precision of ±0.1 pm for the graphene lattice parameter. Our data reveals a characteristic hysteresis of the graphene lattice parameter that is explained by the interplay of reversible wrinkle formation and film strain. We show that graphene on Ir(111) always exhibits residual compressive strain at room temperature. Our results provide important guidelines for strategies to avoid wrinkling.     

Alternative radical pairs for cryptochrome-based magnetoreception

There is growing evidence that the remarkable ability of animals, in particular birds, to sense the direction of the Earth''s magnetic field relies on magnetically sensitive photochemical reactions of the protein cryptochrome. It is generally assumed that the magnetic field acts on the radical pair [FAD^•− TrpH^•+] formed by the transfer of an electron from a group of three tryptophan residues to the photo-excited flavin adenine dinucleotide cofactor within the protein. Here, we examine the suitability of an [FAD^•− Z^•] radical pair as a compass magnetoreceptor, where Z^• is a radical in which the electron spin has no hyperfine interactions with magnetic nuclei, such as hydrogen and nitrogen. Quantum spin dynamics simulations of the reactivity of [FAD^•− Z^•] show that it is two orders of magnitude more sensitive to the direction of the geomagnetic field than is [FAD^•− TrpH^•+] under the same conditions (50 µT magnetic field, 1 µs radical lifetime). The favourable magnetic properties of [FAD^•− Z^•] arise from the asymmetric distribution of hyperfine interactions among the two radicals and the near-optimal magnetic properties of the flavin radical. We close by discussing the identity of Z^• and possible routes for its formation as part of a spin-correlated radical pair with an FAD radical in cryptochrome.     

Simulating the Schrödinger functional with two pseudo-fermions

We report on simulations with two flavors of O(a) improved degenerate Wilson fermions with Schrödinger functional boundary conditions. The algorithm which is used is Hybrid Monte Carlo with two pseudo-fermion fields as proposed by M. Hasenbusch. We investigate the numerical precision and sensitivity to reversibility violations of this algorithm. A gain of a factor two in CPU cost is reached compared with one pseudo-fermion field due to the larger possible step-size.     

Coexistence of Low Damping and Strong Magnetoelastic Coupling in Epitaxial Spinel Ferrite Thin Films

Low‐loss magnetization dynamics and strong magnetoelastic coupling are generally mutually exclusive properties due to opposing dependencies on spin–orbit interactions. So far, the lack of low‐damping, magnetostrictive ferrite films has hindered the development of power‐efficient magnetoelectric and acoustic spintronic devices. Here, magnetically soft epitaxial spinel NiZnAl‐ferrite thin films with an unusually low Gilbert damping parameter (<3 × 10^?3), as well as strong magnetoelastic coupling evidenced by a giant strain‐induced anisotropy field (≈1 T) and a sizable magnetostriction coefficient (≈10 ppm), are reported. This exceptional combination of low intrinsic damping and substantial magnetostriction arises from the cation chemistry of NiZnAl‐ferrite. At the same time, the coherently strained film structure suppresses extrinsic damping, enables soft magnetic behavior, and generates large easy‐plane magnetoelastic anisotropy. These findings provide a foundation for a new class of low‐loss, magnetoelastic thin film materials that are promising for spin‐mechanical devices.     

Evaluation of the wound healing efficacy of chemical and phytogenic silver nanoparticles

Wound healing requires a series of cellular events and a cascade of co‐ordinated and systemic biochemical events. Silver nanoparticles possess many beneficial properties for wound management including antibacterial, anti‐inflammatory and pro‐healing properties. In this study, the authors investigated the wound healing properties of Cinnamomum verum extract mediated nanosilver (CENS) particles in comparison with 1% povidone iodine, citrate mediate NS and CE treatments. The topical application of CENS showed good antibacterial activity and accelerated wound healing with complete epithelialisation and normal re‐growth of hair in all three models of study: namely, excision, incision and dead space models in rats compared with all other treatments. CENS was also found to promote collagen synthesis, stabilise wound besides countering oxidative stress and stimulating cellular proliferation CENS could be a novel therapeutic agent for wound management.Inspec keywords: silver, nanoparticles, nanomedicine, wounds, antibacterial activity, biomedical materials, biochemistry, cellular biophysics, proteinsOther keywords: wound healing efficacy, chemical nanoparticles, phytogenic silver nanoparticles, cellular events, systemic biochemical events, wound management, antibacterial properties, anti‐inflammatory properties, pro‐healing properties, Cinnamomum verum extract mediated nanosilver particles, CENS, complete epithelialisation, normal hair regrowth, excision model, incision model, dead space model, rats, collagen synthesis, oxidative stress, cellular proliferation, therapeutic agent, Ag     

暑促先别急下手CFan帮你摸门道

每年的暑期,都是IT产品的销售旺季,因为在这个时候,学生、教师都进入了假期,为了打发漫长无聊的假期,人们通常会选择上网娱乐。此外,进入7月以来,天气炎热,上班族下班或周末时,都不愿意出门,呆在家里吹空调、上网、打游戏,电脑需求量自然暴涨。厂商们也在暑促前卯足劲发布了多款新产品以刺激用户的购买欲望。     

Effect of different N fertilizer forms on antioxidant capacity and grain yield of rice growing under Cd stress

Cadmium contamination in soil has become a serious issue in sustainable agriculture production and food safety. A pot experiment was conducted to study the influence of four N fertilizer forms on grain yield, Cd concentration in plant tissues and oxidative stress under two Cd levels (0 and 100 mg Cd kg(-1)soil). The results showed that both N form and Cd stress affected grain yield, with urea-N and NH(4)(+)-N treatments having significantly higher grain yields, and Cd addition reducing yield. NO(3)(-)-N and NH(4)(+)-N treated plants had the highest and lowest Cd concentration in plant tissues, respectively. Urea-N and NH(4)(+)-N treatments had significantly higher N accumulation in plant tissues than other two N treatments. Cd addition caused a significant increase in leaf superoxide dismutase (SOD) and peroxidase (POD) activities for all N treatments, except for NO(3)(-)-N treatment, with urea-N and NH(4)(+)-N treated plants having more increase than organic-N treated ones. The results indicated that growth inhibition, yield reduction and Cd uptake of rice plants in response to Cd addition varied with the N fertilizer form.