Very Low Degree of Energetic Disorder as the Origin of High Mobility in an n‐channel Polymer Semiconductor

Charge transport is investigated in high‐mobility n‐channel organic field‐effect transistors (OFETs) based on poly{[N,N′‐bis(2‐octyldodecyl)‐naphthalene‐1,4,5,8‐bis(dicarboximide)‐2,6‐diyl]‐alt‐5,5′‐(2,2′‐bithiophene)} (P(NDI2OD‐T2), Polyera ActivInk? N2200) with variable‐temperature electrical measurements and charge‐modulation spectroscopy. Results indicate an unusually uniform energetic landscape of sites for charge‐carrier transport along the channel of the transistor as the main reason for the observed high‐electron mobility. Consistent with a lateral field‐independent transport at temperatures down to 10 K, the reorganization energy is proposed to play an important role in determining the activation energy for the mobility. Quantum chemical calculations, which show an efficient electronic coupling between adjacent units and a reorganization energy of a few hundred meV, are consistent with these findings.     

Self-Adaptive Fault Tolerance in Multi-/Many-Core Systems

This paper presents a novel approach to the design of multi-/many-core systems with an adaptive level of reliability. The approach defines a layer at the operating system level that achieves fault detection/tolerance/diagnosis properties by means of thread replication and re-execution mechanisms. The layer applies the most convenient hardening mechanism to achieve the desired trade-off between reliability and performance by adapting at run-time to the changes of the working scenario. The proposed strategy has been applied in a set of experimental sessions considering a real-world parallel application, to evaluate its benefits on the final system with respect to various strategies selected at design time.     

Crystal Size,Morphology, and Growth Mechanism in Bio‐Inspired Apatite Nanocrystals

Bio‐inspired apatite nanoparticles precipitated in the presence of citrate ions at increasing maturation times are characterized in terms of structure, size, morphology, and composition through advanced X‐ray total scattering techniques. The origin of the platy crystal morphology, breaking the hexagonal symmetry, and the role of citrate ions is explored. By cross‐coupling the size and shape information of crystal domains with those obtained by atomic force microscopy on multidomain nanoparticles, a plausible mechanism underlying the amorphous‐to‐crystal transformation is reconstructed. In the present study, citrate plays the distinct roles of inducing the platy morphology of the amorphous precursor and controlling the thickness of the Ca‐deficient apatite nanocrystals. These findings can open new scenarios also in bone mineralization, where citrate might have a broader role to play than has been thought to date.     

Millimeter wave inductive post filters,theory and results

This paper briefly details the work carried out on the modelling of inductive post filters. This type of filter approach is particularly attractive at millimeter wave frequencies due to its ease of manufacture, however for modelling no true wide band equivalent circuit would seem to be available. In order to overcome this limitation we have developed a rigorous wide band model. The accuracy of the model has been confirmed by numerous experimental measurements and the resulting computer program quickly enables both analysis and synthesis to be carried out. The speed and efficiency of this approach has allowed the effect of mechanical tolerances to be taken into account, thus reducing cost, complexity and assembly times.     

“In‐field” cell temperature evaluation in solar modules through time‐dependent open circuit voltage measurements

A method for the evaluation of p–n junction cell temperature in PV modules operating in the maximum power point (MPP) mode has been proposed. The method does not require specialized equipment and (for the concentrator modules) the data on the open circuit (OC) voltage temperature coefficients measured under pulse illumination. It consists of measuring several open circuit voltage magnitudes together with temperature measurements on the external module surface near one of the cells. In this procedure, a fast transition from MPP to OC operational mode is carried out, during which a time‐dependent voltage measurement is carried out with the help of a memory oscilloscope. A “reference” OC voltage magnitude in a “cold” module (a condition, as if the cells are kept at ambient temperature) is obtained by calculations, so that there is no necessity in a fast mechanical shuttering of the module aperture area. In the case of the concentrator modules, the module OC voltage temperature coefficient can be measured, if heat sinking process is artificially modified during outdoor measurements. Copyright © 2015 John Wiley & Sons, Ltd.     

Uniform Virus‐Like Co–N–Cs Electrocatalyst Derived from Prussian Blue Analog for Stretchable Fiber‐Shaped Zn–Air Batteries

Zn‐air batteries (ZABs) offer promising commercialization perspectives for stretchable and wearable electronic devices as they are environment‐friendly and have high theoretical energy density. However, current devices suffer from limited energy efficiency and durability because of the sluggish oxygen reduction and evolution reactions kinetics in the air cathode as well as degenerative stretchability of solid‐state electrolytes under highly alkaline conditions. Herein, excellent bifunctional catalytic activity and cycling stability is achieved by using a newly developed Co–N–C nanomaterial with a uniform virus‐like structure, prepared via a facile carbonization of a prussian blue analogue (PBA). Furthermore, a solid‐state dual‐network sodium polyacrylate and cellulose (PANa‐cellulose) based hydrogel electrolyte is synthesized with good alkaline‐tolerant stretchability. A solid‐state fiber‐shaped ZAB fabricated using this hydrogel electrolyte, the virus‐like Co–N–Cs air cathode, and a zinc spring anode display excellent stretchability of up to 500% strain without damage, and outstanding electrochemical performance with 128 mW cm^?2 peak power density and good cycling stability for >600 cycles at 2 mA. The facile synthesis strategy demonstrated here opens up a new avenue for developing highly active PBA‐derived catalyst and shows, for the first time, that virus‐like structure can be favorable for electrochemical performance.     

A scanning electron microscopy study of diseased root surfaces conditioned with EDTA gel plus Cetavlon after scaling and root planing

In the present investigation, a scanning electron microscopy analysis was performed to evaluate the effects of the topical application of ethylenediaminetetraacetic acid (EDTA) gel associated with Cetavlon (EDTAC) in removing the smear layer and exposing collagen fibers following root surface instrumentation. Twenty-eight teeth from adult humans, single rooted and scheduled for extraction due to periodontal reasons, were selected. Each tooth was submitted to manual (scaling and root planing) instrumentation alone or combined with ultrasonic instruments, with or without etching using a 24% EDTAC gel. Following extraction, specimens were processed and examined under a scanning electron microscope. A comparative morphological semi-quantitative analysis was performed; the intensity of the smear layer and the decalcification of cementum and dentinal surfaces were graded in 12 sets using an arbitrary scale ranging from 1 (area covered by a smear layer) to 4 (no smear layer). Root debridement with hand instruments alone or combined with ultrasonic instruments resulted in a similar smear layer covering the root surfaces. The smear layer was successfully removed from the surfaces treated with EDTAC, which exhibited numerous exposed dentinal tubules and collagen fibers. This study supports the hypothesis that manual instrumentation alone or instrumentation combined with ultrasonic instrumentation is unable to remove the smear layer, whereas the subsequent topical application of EDTAC gel effectively removes the smear layer, uncovers dentinal openings and exposes collagen fibers.     

Novel Low‐Power High‐dB Range CMOS Pseudo‐Exponential Cells

In this paper, novel CMOS pseudo‐exponential circuits operating in a class‐AB mode are presented. The pseudo‐exponential approximation employed is based on second order equations. Such terms are derived in a straightforward way from the inherent nonlinear currents of class‐AB transconductors. The cells are appropriate to be integrated in portable equipment due to their compactness and very low power consumption. Measurement results from a fabricated prototype in a 0.5 μm technology reveal a range of 45 dB with errors lower than ±0.5 dB, a power consumption of 100 μW, and an area of 0.01 mm².