IMPROVING THE QUALITY OF TIMBER FROM RED BEECH (N. FOSCA) BY INTERMITTENT DRYING

The effect of cycling the external conditions on the timber quality and drying time during seasoning has been studied for red beech (Nothofagus fusca), a difficult-to-dry New Zealand hardwood, inalaboratorybatchdryer. Intermittent drying at anair temperature of 45°C and a wet-bulb depression of 10°C takes longer to yield a given moisture content than continuous drying under the same conditions, but produces timber without honeycomb or severe case-hardening as observed in continuous drying. The experiments also indicate that the timber can tolerate a higher air temperature (55°C) in intermittent drying at the same wet-bulb depression with less case-hardening and without showing honeycomb compared with continuous drying at 45°C, having a similar total drying time. Intermittent drying at a slightly higher dry-bulb temperature (60°C) and a much higher wet-bulb depression (18°C) gives a similar degree of case-hardening to that found in samples dried continuously at a dry-bulb temperature of 45°C.     

Interfacial chemistry and adhesive durability

The improved understanding of adsorption chemistry which has arisen from the development of new surface analytical techniques during the last twenty years has had a major effect on the understanding of catalytic reaction mechanisms. However, there are many other areas of technology where Interfacial chemistry has a determining role but where the understanding is much less developed. In this paper examples are presented of the role of interfacial chemistry in adhesion. In particular, It Is shown that modification of a surface to the extent of just a few atomic layers in depth can have dramatic effects on the performance of adhesive bonds, particularly when exposed to hostile environmental conditions. These examples will be used to highlight a need for greater fundamental understanding of the interfacial chemistry of adhesion and also other technologies where interface effects are dominant.     

Unexpected relations between matrix elements of the three-body scalar operators ti in the f shell

It has been known for some time that crystal-field matrix elements (i.e., matrix elements of sums over spherical harmonics involving the coordinates of the individual electrons) are often unexpectedly proportional to one another in the f shell. To see whether similar relations hold for more complicated operators than those provided by the crystal field, we examined the matrix elements of the three-electron scalar operators t_i for all configurations f^N, as calculated by W. T. Carnall on the basis of the computer program of Hannah Crosswhite. These operators are widely used to take configuration interaction into account, and we found a surprising number of proportionalities that go beyond what would be expected on a straightforward application of the Wigner-Eckart theorem, as applied to the irreducible representations of the classic groups SO(7), G₂ and SO(3) used by Racah in defining the f-electron states. A listing of such relations is provided.     

Surface electronic structure of rare earth metals

Angle-resolved UV photoemission has been used to investigate the electronic structure of the (0001) surfaces of scandium, yttrium, praseodymium and gadolinium. Off-normal emission spectra were recorded with high angular resolution, enabling detailed mapping of the dispersion of valence band features. Yttrium and gadolinium show similar results to published data from Ho(0001), suggesting minimal 4f influence in the lanthanide bandstructures. Differences seen on praseodymium and scandium may be due to 4f derived states and surface states respectively.     

Kinetics of the inhibition of ascorbic acid browning by sulphite.

Despite differences in the structures of aldoses and ascorbic acid, ASA, the non-enzymic browning of the latter involves intermediates similar to those found in Maillard browning. The kinetics of the sulphite-inhibited browning of ASA suggest that, under anaerobic conditions, the rate of reaction of sulphite species, S(IV), is of first order with respect to S(IV). The possibility that S(IV) could catalyse the hydrolysis of the lactone ring of ASA is considered by reference to D-glucono-delta-lactone. Evidence is presented to suggest that, under aerobic conditions, autoxidation of ASA leads to the oxidation of S(IV). The composition of melanoidins from ASA-glycine mixtures is compared with that from arabinose-glycine; the former contain 2 x 5 times more ASA-derived residues per glycine molecule than arabinose-derived residues per glycine molecule in the latter. The implications of these findings to the mechanism of ASA browning are discussed.     

In vitro model for the evaluation of toxicity and antinutritional effects of sulphites.

The food preservatives, sulphur dioxide and its salts, are known to present some toxic, mutagenic and antinutritional effects; in fact they interact with a number of nutrients, e.g. some vitamins, notably thiamine (Th) and folic acid (FA). The effect of different concentrations of sodium bisulphite in cell culture media has been studied in vitro on a human cell line, HEp-2, deriving from a carcinoma of the larynx. Moreover, the sulphites have been tested with different levels of Th and FA with the aim of elucidating how much the cellular response depended on either the anti-nutritional effect or the toxicity of sulphites. Cell growth has been taken as an index of cytotoxicity and measured both as total protein content and as colony-forming ability. With no Th and FA in the culture medium, a clear decrease of cell growth was observed either with or without addition of sodium bisulphite. A dose-dependent reduction of protein content was detected in cells treated with 10, 50, 100, 200, 250 or 500 microM sodium bisulphite. Moreover, when the cells were treated with 10 or 100 microM of this compound, the colony-forming ability was reduced both in number and colony size. As far as the interaction of the two vitamins with sodium bisulphite is concerned, when these nutrients were present in the medium at 0.5, 1.0, 1.5, 2.0 or 2.5 mg/l, a similar growth profile, determined from their concentration, was observed in treated and control cells, the growth levels being affected by the sodium bisulphite contents. At higher levels of Th and FA, the growth index was still increasing only in treated cells, this phenomenon being particularly evident in cultures treated with 200 microM sodium bisulphite. The colony-forming ability was reduced in controls but still increased in treated cells at the highest concentration of vitamins.     

Occurrence of the mycotoxins ochratoxin A, zearalenone and deoxynivalenol in feed components.

The mycotoxin contamination of feed components used by the Dutch cooperative feed industry was surveyed to estimate the risk for animal production losses. Of 89 randomly and 6 selectively taken samples of raw materials harvested in 1988 and 1989 27% were contaminated with ochratoxin A (OCHRA), 31% with zearalenone (ZEA) and 20% with deoxynivalenol (DON). The mean content (microgram/kg) of all positive randomly taken samples was 18 (OCHRA), 62 (ZEA) and 630 (DON). The highest level (microgram/kg) for all samples was 120 (OCHRA) in barley, 3100 (ZEA) in corn cob mix and 1900 (DON) in maizegluten feed. The results of this survey show that feed components are often contaminated with mycotoxins. However, the contamination level could only sporadically cause production losses in animal husbandry.