Experimental Investigation of the Density of Molten Lead–Bismuth Eutectic

The density of molten Pb–Bi eutectic is measured by the pycnometer method in a temperature range of 410–726 K. The confidence of error of measurement, made up by the systematic and random components, does not exceed 0.1%. The experimental results are compared with the experimental data on the density of a liquid lead–bismuth alloy of eutectic composition available in the literature.     

Athermalised monolithic VMUX employing silica arrayed waveguide grating multiplexer

The realisation of a monolithic athermalised variable-optical-attenuator-integrated multiplexer (VMUX) implemented in silica-on-silicon waveguide technology is reported. The VMUX incorporates an athermal arrayed waveguide grating, providing <0.05 nm of peak transmission wavelength shift over 20-70/spl deg/C operating ambient independent of attenuator settings.     

Nonholonomic Mobile Manipulators: Kinematics, Velocities and Redundancies

We consider nonholonomic mobile manipulators built from an n _a joint robotic arm and a nonholonomic mobile platform with two independently driven wheels. Actually, there is no efficient kinematic formalism for these systems which are generally characterized by their high number of actuators. So, kinematic modelling is presented with particular emphasis on redundancy. Whereas kinematic redundancy is well known in the holonomic case, it is pointed out that it is necessary to define velocity redundancy in the case of nonholonomic systems. Reduced velocity kinematics based on quasi-velocities are shown to provide an efficient formalism. Two examples of mobile manipulators are presented. Finally, reduced velocity kinematics and velocity redundancy are shown to be adequate tools in order to realize operational task while optimizing criteria such as manipulability.     

Circular core polarization-maintaining optical fibers withelliptical stress-induced cladding

The reproducible technology for producing high-birefringence fibers with stress-induced elliptical cladding and circular core is described. The authors have obtained fibers that have a birefringence of about (1-3) 10^-4, a mode coupling parameter of about (2-7) 10 ^-5 m^-1, and loss of less than 0.5 dB/km at 1.6 μm. The authors have found effects restricting the capability of test fibers to maintain the state of linear polarization     

Low cycle fatigue and creep behavior of recrystallized Molybdenum near room termperature

The deformation behavior of pure recrystallized molybdenum under cyclic and static loads was investigated in the temperature range between 30°C and 10O°C, for stress amplitudes between 100 MPa and 250 MPa and for static loads up to 200 MPa. The results show that in spite of the low test temperatures and stress levels the Mo material exhibits considerable plastic strains which depend sensitively on frequenez and small changes in temperature.The activation energy deduced for the static and dynamic deformation is less than 0.98 eV which indicates thermally activated processes, to be explained by a dislocation kink model as described in the literature. The low-temperature fatigue behavior appears strongly influenced by creep-fatigue interaction phenomena.     

Action of chelators on solid iron in phosphate-containing aqueous solutions

To study the effect of strong iron-ligands on steel corrosion, mild steel electrodes were immersed in solutions containing 20 mM phosphate buffer (pH=7.2) and between 0.01 mM and 1 M of either the iron(II)-chelators 2,2^′-bipyridine or FerroZine, or the iron(III)-chelators citrate or acetylacetonate. Resulting surface reactions were investigated by quantifying the electrochemical potential (E), the electrochemical polarization resistance (R_p), the corrosion current (I_corr) and the release of iron into solution. The surface was further analyzed by scanning electron microscopy (SEM/SEM-EDAX) and atomic force microscopy. Concentrations of 0.1 mM of any of the chelators led to slight, temporary changes in E, I_corr and R_p. Concentrations of 10 mM resulted in characteristic changes of E, which were the same for all chelators and in the precipitation of FePO₄ in the case of citrate and acetylacetonate, or vivianite [Fe₃(PO₄)₂ · 8H₂O] in the case of bipyridine and FerroZine. Concentrations of 1 mM of both iron(III)-chelators led to a temporary drop of E similar to that found with 0.1 mM chelator. With iron(II)-chelators, E dropped to about −500 mV before oscillating for several days. The amplitudes of the oscillations were up to 200 mV with periods of 30 and 20-25 min for bipyridine and FerroZine, respectively.     

The electropolymerization of pyrrole at a CuNi electrode: corrosion protection properties

Pyrrole was successfully electropolymerized at a copper–nickel electrode in a near-neutral sodium oxalate solution containing Cu²⁺ cations to generate a homogenous and adherent polypyrrole film. The presence of the Cu²⁺ ions increased both the rate of the electropolymerization reaction and the adherence of the polymer at the CuNi interface. In the absence of these cations, oxidation of the electrode occurred generating a nickel-rich layer that was not sufficiently conducting, under the electropolymerization conditions employed, to facilitate the electron-transfer reaction and the electropolymerization of pyrrole.These films remained stable and exhibited significant corrosion protection properties in acidified and neutral 0.1 mol dm⁻³ NaCl solutions even on polarization of the electrodes to high anodic potentials.     

Electrophysiologic and electrocardiographic aspects of the transplanted heart

The authors suggest that academic institutions build business-oriented policies and practices into the development of any nurse-run clinic to set the stage for financial independence when special or development funding ends. One university-affiliated program that provides 4,000 to 5,000 annual visits drastically changed its strategies when threatened with closure after free rent and other subsidies were withdrawn. The growing emphasis on ambulatory care roles for nurses at all levels makes such clinics critical to the success of the broad-based curricula of nursing education programs, as well as the clinic's value to communities they serve. Funding difficulties frequently threaten the existence of such nurse-run clinics once the initial grant funding is no longer available. This has caused a new emphasis on running such clinics in a business-wise manner. Among the strategies initiated were: direct full-pay at the time of service; a realistic business management plan; aggressive planned marketing; contracts and agreements with other agencies; obtaining provider status with selected HMOs.