Synthesis of carbon nanosheets by inductively coupled radio-frequency plasma enhanced chemical vapor deposition

An ultrathin sheet-like carbon nanostructure, carbon nanosheet, has been effectively synthesized with CH₄ diluted in H₂ by an inductively coupled radio-frequency plasma enhanced chemical vapor deposition. Nanosheets were obtained without catalyst over a wide range of deposition conditions and on a variety of substrates, including metals, semiconductors and insulators. Scanning electron microscopy shows that the sheet-like structures stand on edge on the substrate and have corrugated surfaces. The sheets are 1 nm or less in thickness and have a defective graphite structure. Raman spectra show typical carbon features with D and G peaks at 1350 and 1580 cm⁻¹, respectively. The intensity ratio of these two peaks, I(D)/I(G), increases with methane concentration or substrate temperature, indicating that the crystallinity of the nanosheets decreases. Infrared and thermal desorption spectroscopies reveal hydrogen incorporation into the carbon nanosheets.     

State observability and condition observability for a class of interacting discrete event systems

This paper introduces the concepts of state observability and condition observability for condition systems, a class of systems composed of discrete state components which interact via discrete binary signals called conditions. Given a set of externally observed conditions, state observability implies that the state of the system can be determined from the observations, and condition observability implies that all unobserved input and output conditions of the system can be determined from the observations. In this paper, we present a class of systems which is state observable and condition observable. We present a method to synthesize an observer system to provide state and condition signal estimates for a single component subsystem.     

Evaluating the effectiveness of independent verification andvalidation

The complexity of today's software systems mandates a structured approach to development and a verification and validation process that ensure that the right product is built and that it is built right. A V&V process is critical for those high-consequence systems in which a software failure can result in injury or death or where live testing is not feasible. NASA Langley Research Center funded a study to examine the effectiveness of the Army's Software Engineering Evaluation System (SEES). The project led to a study designed to examine the benefits of using SEES as an independent V&V methodology. The study consisted of two independent-development groups. Each was given an identical set of requirements that outlined a solution to a particular problem. The authors asked both groups to design, code, and test their software. The results indicate that IV&V provides a significant value-added component to the software development process     

Pulsed laser deposition of Y2O3 : Eu thin film phosphors

Thin films of Y₂O₃ : Eu cathodoluminescent (CL) phosphors were deposited using pulsed laser deposition using deposition temperature between 250°C and 800°C, O₂ pressures between residual vacuum (2×10⁻⁵ Torr) and 6 Torr, and post annealing up to 1200° for 1 h in air. The CL efficiency of the best thin film was about one third that of the starting powder. The brightness and efficiency of the thin films improved as the deposition temperature, O₂ pressure and post annealing temperature were increased, except that O₂ pressures above 600 mTorr did not significantly improve the CL properties. At deposition temperatures >600°C, the surface morphology changed from a smooth film to a nodular deposit for O₂ pressures >200 mTorr, with nodule dimensions ≈100 nm. Simultaneously, the CL properties improved dramatically because of enhanced optical scattering out of the thin film. Optical scattering was discussed in terms of anomalous diffraction. The CL properties also improved dramatically with high temperature post annealing. This effect was interpreted in terms of improved crystallinity and activation of the Eu. The low brightness and efficiency of thin films versus powder was affected by depletion of the Eu in the thin films owing to the deposition process.     

Morphology of peripheral airways in current smokers and ex-smokers

To investigate the effect of smoking status on pulmonary function and pathologic changes in the peripheral airways, we studied 97 patients who underwent thoracotomy for coin lesions. The patients were divided into 4 groups: nonsmokers (n = 9), current smokers (n = 51), and those who had ceased smoking for less than (n = 18) or more than (n = 19) 2 yr prior to surgery. We found that current smokers had evidence of air-flow obstruction with abnormal lung volumes when compared with nonsmokers. Ex-smokers had lung volumes similar to those of nonsmokers, but showed evidence of obstruction, with the FEV1/FVC between the values found for nonsmokers and current smokers. Examination of the small airways showed that the membranous bronchioles of current smokers and ex-smokers displayed only increased goblet cell metaplasia when compared with those in nonsmokers; the respiratory bronchioles of current and ex-smokers showed increases in intraluminal and airway wall inflammatory cells, wall fibrosis, and pigment deposition. We conclude that patients who currently smoke cigarettes have reduced lung function that is associated with abnormalities of airway structure. Although those who have stopped smoking have function that is closer to the nonsmoking group, there is no apparent difference in structural change between current and ex-smokers.     

The effect of increased grain moisture content on some life history characters of Sitophilus oryzae (L.) after staining egg plugs with acid fuchsin

Acid fuchsin staining is widely used as a method for easy detection of egg plugs deposited by Sitophilus spp. The effect of increasing grain moisture content through staining on some life history characters of three geographical strains of Sitophilus oryzae was examined. The results show that staining increases development rate and survival from egg to adult and there is also a suggestion of a strain × treatment interaction. Factors requiring consideration if staining is carried out are discussed.     

Qualitative Diagnosis of Condition Systems

A condition system is a collection of Petri nets that interact with each other and the external environment through condition signals. Some of these condition signals may be unobservable. In this paper, a system fault is defined in terms of observed behavior versus expected behavior, where the expected behavior is defined through condition system models. A diagnosis of this fault localizes the subsystem that is the source of the discrepancy between output and expected observations. We show that the structure of the interacting subsystems define a diagnostic causal model that captures the causal structure of subsystem dependencies. The diagnostic causal model can then be used to determine a set of subsystems that might be the source of a fault.