HZSM-5型分子筛催化乙醇溶液脱水制备乙烯的工艺

以稀乙醇溶液为原料、自制分子筛HZSM-5为催化剂,催化脱水制备乙烯.考察了硅铝比、反应温度、质量空速及乙醇的质量浓度对该反应的影响,得到了较优化的反应工艺条件为:催化剂为HZSM-5(硅铝比30)分子筛,ρ(乙醇)为100~200 g/L,质量空速为2~6 h-1,反应温度为300℃.乙醇的转化率可达99%,乙烯的选择性达99%以上.     

Corrosion-resistant lightweight metallic bipolar plates for PEM fuel cells

Corrosion resistant treated metal bipolar plates with higher rigidity and electrical conductivity than graphite were developed and tested for PEM fuel cell applications. Six replicas of single cells were used three of which were made of graphite composites bipolar plates and the other three of the treated metallic plates. A Membrane Electrode Assembly (MEA) with 5.55 cm² active electrode areas, 0.3 mg cm^–2 Pt loading and Nafion membrane 115 was fitted to each cell and operated under identical conditions. The experimental testing was conducted at room temperature (20 °C). The average value of the data obtained for the three graphite cells was plotted. Similarly, the average value of the data obtained for the three treated metal cells was plotted on the same graph for comparison. Generally, the treated metal bipolar plate provided at least 12% saving in hydrogen consumption in comparison to graphite. This is attributed to the lower bulk and surface contact resistance of the metal used in this study in relation to graphite. The results of lifetime testing, conducted at room temperature under variable loading showed no indication of power degradation due to metal corrosion for at least 1500 hours.     

基于关联分析的数据挖掘在体检CRM中的应用

运用关联分析方法对体检中心数据进行挖掘。首先分析了关联规则的原理和方法,然后对待挖掘数据进行集成、变换等预处理,得到能进行挖掘的原始数据.采用挖掘工具WEKA,选用关联规则中的Apriori算法对处理后数据进行分析,得到了与某一病症相关的各个症状之间的关联关系,以及各个症状与健康之间的关联关系。     

基于改进PSO算法的自适应均衡算法

传统的自适应均衡算法存在收敛速度慢,稳定性差、均衡效果不理想等缺点,从而使自适应均衡器在高速光纤通信系统中的应用受到限制.具有梯度搜索因子的Grads-PSO算法,结合了传统数值优化方法在计算速度和计算精度上的优势,将梯度法引入粒子群算法中.在梯度搜索因子的指导下,PSO算法的运算过程显得更加有规则,从而提高了算法的收敛速度和运算精度.因此,本文提出将改进PSO算法用作自适应均衡器均衡算法.通过仿真实验表明,改进PSO算法具有收敛速度快,计算精度高的优点,将其作为自适应均衡器的控制算法可收到很好的均衡效果,优于传统的控制算法.     

Enhancement of radiation‐resistant effect in ethylene–vinyl acetate copolymers by the formation of ethylene–vinyl acetate copolymers/clay nanocomposites

Ethylene–vinyl acetate (EVA) copolymers/clay nanocomposites, prepared by using nonreactive organophilic clay and reactive organophilic clay, were characterized by X‐ray diffraction and by high‐resolution transmission electron microscopy. The influence of gamma irradiation on the structure and properties of the pure EVA and EVA/clay nanocomposites was systematically investigated. In the presence of gamma radiation, the clay can effectively restrain the increase of the storage modulus of EVA/clay nanocomposites, which was supported by dynamical mechanical analysis. Gamma irradiation had almost no effect on the thermal properties of EVA/clay nanocomposites by using nonreactive organophilic clay, but it obviously improved the thermal stability of EVA/clay nanocomposites by using reactive organophilic clay. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2532–2538, 2005     

基于可操作度的虚拟人手部避障运动控制算法

研究复杂作业环境中虚拟人手部避障运动的高精度控制问题,问题的关键是解决虚拟人手的设计.为了灵活操作能在操作的末端临时变换姿态,给控制过程中手臂转动路线,速度,加速度等参数的控制带来较大困难.传统的控制方法通过增加控制自由度来解决这个问题,但是一旦自由度增加,会带来冗余控制影响,弊端较为明显.提出一种采用可操作度矩阵的逆向运动学控制算法,引入可操作度模型进行肢体末端效应器运动路径的生成,与HAL链IK分析求解方法相结合,实现了真实感较强的肢体实时运动控制.通过仿真和动作捕获实验验证了算法的有效性,可应用于人机工程仿真中的避障控制和干涉检查.     

Mathematical model of shear rate of polymer melt dynamic extruding through capillary

With superimposing a sine vibration of displacement on the extruding direction of a polymer melt, the characterization formula of the shear rate of a polymer melt within a capillary was set up. By making use of the experimental equipment of a constant velocity type dynamic rheometer of capillary (CVDRC) designed by the authors, the calculating steps of the shear rate of the polymer melt at the wall of the capillary under a vibration force field were established. Through measuring and analyzing the instantaneous data of capillary entry pressure, capillary volume rate, and their phase‐difference under the superimposed vibration, the polymer melt's shear rate at the wall of the capillary can thus be calculated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1056–1061, 2005     

基于麦克风阵列的语音增强算法研究

语音通信为最普通的一种通信模式,在我们的日常生活中发挥着极为关键的效果.然而,在客观场景内,声音势必会因噪音而产生影响.此类噪声与干扰不但会影响声音的可知性,还使声音处理系统的性能急剧恶化.但是,在现实环境中,声音受到噪音和干扰是不可避免的.这些噪声和干扰不仅影响声音的可知性,还使声音处理系统的性能急剧恶化.麦克风阵列语音增强为语音增强中最普遍的一种模式.文章具体讲解了几类比较普遍的麦克风阵列增强算法以及语音扩展算法的仿真处理结果,语音扩展算法可以从噪音声音中尽可能地提取清晰的声音,从而提高语音质量和主观舒适性.     

基于信息物理融合的骨折复位机器人系统构建

针对骨折治疗中传统复位方法（手法复位、牵引复位、手术复位）存在的二次损伤、肌能失调、患肢僵硬、破坏血运及术后矫正动态性能差等问题,提出了一种人-机-物融合的信息物理系统（CPHS）用于指导机器人的复位动作。首先,从CPHS的数字孪生、信息感知、系统集成、手术流程、模拟复位等方面论证了并联机器人信息物理系统的构成,将机器人的高定位精度及可重复性与微创方法有效结合,从而指导医生完成仿真规划及术中监控等一系列操作;其次,根据临床骨折复位过程,在机器人操作下对5组不同骨折姿态的模拟骨折病例进行了复位实验;最后,计算出每组实验复位后的移位残余及角度误差,并与传统复位方法的相应数据进行对比。实验结果表明,CPHS骨折复位机器人相较于传统复位方法,在骨折复位过程和患者术后康复上均有着明显的优势。     

小说人物的分布表示及其应用研究

小说是以刻画人物为中心,通过完整的故事情节和具体的环境描写反映社会生活的一种文学体裁。对小说人物进行建模,是小说文本理解和小说文本挖掘的基础性工作。该文构建了大规模的小说语料库,抽取人物及其依存特征,提出基于skip-gram的人物向量训练方法,以人物为目标,以依存特征为上下文,基于训练出的人物向量,探索了小说人物相似度计算、小说人物聚类分析及小说人物画像等应用。实验结果表明,小说人物的分布表示有较好的应用效果。