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21.
Abstract

We present an experimental realization of discrimination between non-orthogonal polarization states at the Helstrom bound for minimum probability of error. The experiment was performed with highly attenuated laser light with a mean number of about 0·1 photons per pulse.  相似文献   
22.
When a psychologist is diagnosed with a serious medical condition and faces the prospect of an arduous treatment regimen and perhaps a bleak prognosis, it may be difficult to attend to one's level of professional competence. Like their clients, psychologists are vulnerable to distress and diminished functioning caused by a life-threatening illness. Psychologists have an ethical responsibility to monitor and ensure professional competence, yet the distress and distraction that accompany serious health problems can inhibit and undermine self-assessments of competence in many ways; distressed psychologists may react with denial, shame, fear, and problematic countertransference responses. The limitations associated with evaluating competence in the context of distress are discussed and several recommendations are offered for psychologists who deliver services, support gravely ill colleagues, and serve in credentialing and regulatory capacities. (PsycINFO Database Record (c) 2011 APA, all rights reserved)  相似文献   
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College student alcohol abuse remains a significant public health problem, and there is a need for theory-driven and empirically based models to guide prevention efforts. Behavioral theories of choice assume that the decision to consume alcohol is influenced by the relative value of alcohol versus other available activities. In the present study, a sample of college student drinkers (N=108; 56% female, 44% male) who had previously completed a mandatory alcohol intervention completed a measure of alcohol-related and alcohol-free activity participation and enjoyment. The goals of the study were to examine the influence of drinking quantity and contextual variables on activity enjoyment and to identify enjoyable alcohol-free activities that take place on evenings when students might otherwise be drinking. Overall, students found alcohol-related activities more enjoyable than alcohol-free activities, and drinking quantity was positively related to enjoyment. However, alcohol-free activities such as watching movies, going to the theater or museums, going to bars or parties, hanging out with friends, eating at restaurants, and engaging in creative activity were generally as enjoyable as drinking. Alcohol-free activities that included peers or dates were more enjoyable than solitary activities. Men were less likely to engage in alcohol-free activities that included peers and reported less enjoyment related to alcohol-free activities than did women. Further research is required to identify procedures for increasing participation in alcohol-free activities and to determine whether increased alcohol-free activity participation results in decreased alcohol consumption. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
25.
A combination of electrospray ionization, high-field asymmetric waveform ion mobility spectrometry, and mass spectrometry (ESI-FAIMS-MS) was used for the analysis of a solution containing a mixture of the nine chlorinated and brominated haloacetic acids. For a carrier gas of nitrogen in the FAIMS analyzer, haloacetate anions of the mono- and dihalogenated acids and the decarboxylated anions of three of the trihalogenated acids were detected. No signal was observed for bromodichloroacetic acid (BDCAA) at a dispersion voltage of -3400 V. The addition of a small amount of carbon dioxide to the nitrogen carrier gas resulted in the detection of the pseudomolecular trihaloacetate anions, including BDCA-, and significant increases in sensitivities for the trihalogenated species. The addition of carbon dioxide to the nitrogen carrier gas had little effect on the mono- and dihalogenated anions. Quantitative analysis of the nine haloacetic acids, using flow injection, gave detection limits between 5 and 36 parts-per-trillion in 9/1 methanol/water (v/v) containing 0.2 mM ammonium acetate.  相似文献   
26.
Carboxylate and sulfate groups were introduced at the surface of poly(ethylene) (PE) samples. This was accomplished by coating and immobilizing sodium 10-undecenoate (C11(:)) and 10-undecene sulfate (S11(:)) on the polymer by means of an argon plasma treatment. The composition of the coated surfactant layer was proportional to the composition of the coating solution. The thickness of the surfactant layer on the surface of PE samples, which were precoated from an aqueous solution with a total surfactant concentration of 0.30 M, was about 55 A. The presence of carboxylate and sulfate groups after plasma treatment of the precoated surfaces was confirmed by X-ray photoelectron spectroscopy (XPS). About 20% of the initial amount of functional groups of the coated surfactants was retained at the PE surface. The ratio of carboxylate/sulfate groups at the plasma treated surfaces was dependent on the composition of the precoated surfaces. The minimum surface density of these groups on the resulting samples was about one group per 40 A2.  相似文献   
27.
An analytical system consisting of an analytical cantrifuge coupled 'on-line' to a computer was assembled and tested. Collection of records from up to 9 solutions was achieved through programmes which sum readings to reduce noise as well as controlling the positioning of the scanner. With this system it was found that the limit on accuracy for molecular weights at concentrations less than 0.01 g cm-3 was +/- 3% estimated from sedimentation equilibrium experiments. The same system was used to collect records for similar concentrations from velocity experiments by employing a scanning schlieren. In this case the accuracy in estimating sedimentation coefficients was similar to those found when measuring photographs. Since the collection yields detailed information about the shape of the sedimenting boundary, the centroids of the boundary were routinely computed by second moment analysis rather than relying on the position of the maximum of the schlieren peak. In the same analysis estimates of diffusion coefficients were made routinely by calculating corrected height/area ratios for each scan. These calculations were made during the real-time of the experiment, so making available molecular parameters rather than records which must be evaluated some time after stopping the experiment.  相似文献   
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29.
Comments are made on the closed-form solution of the linear matrix equation AX+XB = C using Kronecker-product representations.  相似文献   
30.
Develops a time-series methodology for approaching data in a range of research settings and presents a design package using the time series as a method to eliminate major sources of rival hypotheses. A mathematical model with special considerations for application is offered which maximizes the utility of time-series data for generating and testing hypotheses. (21 ref.) (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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