Polyelectrolyte mediated scalable synthesis of highly stable silver nanocubes in less than a minute using microwave irradiation

Silver nanocubes were synthesized for the first time in large quantities on gold seed in the presence of a polyelectrolyte using microwave heating for 60-120?s. Our experiment indicates that the polyelectrolyte directs the growth of the particle in a specified crystallographic direction resulting in the faceted particle, i.e.?a nanocube. The nanocubes are stable for at least 2 months in ambient conditions.     

Generalized Filter Topology Using Grounded Components and Single Novel Active Element

This paper introduces a new active element combining the useful features of differential voltage, dual-X and first generation current conveyors. The new proposed active element is further utilized to introduce a new generalized filter topology employing grounded components only. The proposed single active element-based topology benefits from first-order and second-order filter realization by appropriate impedance specialization. The circuit topology with single current input provides two output currents and voltages in each case. A thorough study of proposed active element along with extensive simulations is carried out to validate the filter topology. A detailed non-ideal study is also given. To further support the usefulness of filter topology, higher-order filters are also realized. The new active element and the new filter structure provide advancement to the existing knowledge; with the scope of active element being further exploited for analog signal processing applications in general. The proposed differential voltage dual-X first generation current conveyor (DV-DXCCI) and its filtering applications are simulated using TSMC 0.25  \(\upmu \) m technology.     

Infrared photodetectors based on reduced graphene oxide and graphene nanoribbons

The use of reduced graphene oxide (RGO) and graphene nanoribbons (GNRs) as infrared photodetectors is explored, based on recent results dealing with solar cells, light-emitting devices, photodetectors, and ultrafast lasers. IR detection is demonstrated by both RGO and GNRs in terms of the time-resolved photocurrent and photoresponse. The responsivity of the detectors and their functioning are presented.     

Techno-economic performance analysis of solar cooling systems

Vapour absorption cooling systems, powered by solar thermal energy, are now commercially manufactured in sizes ranging from 1.5 to over 20 RT (one refrigeration ton = 3.51 kW of cooling). The needed thermal energy at appropriate temperature potential can either be provided by solar thermal collectors or else from a solar pond. The paper gives the assessment criteria and results for technical and economic evaluation of the performance of absorption chiller using a solar pond. These results, based on Kuwait's environmental data and costs, have been compared with three alternate cooling systems, namely:

• 1 Solar thermal collector absorption cooling system.
• 2 Solar photovoltaic cooling system.
• 3 Standard vapour compression cooling system.

The criteria, used for performance evaluation of the solar cooling systems on a technical basis, consists of assessing the extent to which such systems can make a positive contribution in a conserving fossil fuel. This is done by first estimating the total electrical energy needed by the standard system (defined in para. 3 above) to produce one unit of cooling output. Solar cooling systems are then analysed and compared with a standard system to establish their electrical energy saving or generation capability, after accounting for the parasitic electrical energy used in pump/fan motors and equivalent energy needed for the production of soft water (used-up in the cooling tower) from seawater desalination. The economic analysis considers the cost and life of subsystems and that of the electrical and water desalination plants to arrive at the unit cooling cost. The unit cooling is defined as the ratio of amortized capital investments plus operation and maintenance costs over the year and the total yearly cooling production by the system. The results show that the solar pond absorption cooling system is the closest competitor to the conventional cooling system.     

Enhanced biosynthesis of extracellular matrix proteins and TGF-beta 1 by polyinosinic-polycytidylic acid during cutaneous wound healing in vivo

OBJECTIVES: We sought to determine the utility of left ventricular expansion velocities in differentiating constrictive pericarditis from restrictive cardiomyopathy. BACKGROUND: Several studies have shown that left ventricular diastolic expansion is influenced by the elastic recoil forces of the myocardium. These forces are affected by intrinsic myocardial disease but should be preserved when diastole is impaired as a result of extrinsic causes. METHODS: Using Doppler tissue imaging, we measured peak early velocity of longitudinal axis expansion (Ea) in 8 patients with constrictive pericarditis, 7 patients with restriction and 15 normal volunteers. Transmitral early (E) and late (A) Doppler flow velocities, left ventricular systolic and diastolic volumes, ejection fraction and mitral annular M-mode displacement were also compared between the groups. RESULTS: The Ea value was significantly higher in normal subjects (14.5 +/- 4.7 cm/s [mean +/- SD]) and in patients with constriction (14.8 +/- 4.8 cm/s) than in those with restriction (5.1 +/- 1.4 cm/s, p < 0.001 constriction vs. restriction). There was weak correlation between Ea and the extent of annular displacement (r = 0.55, p = 0.004) and the E/A ratio (r = 0.44, p = 0.03). There was no correlation between Ea and E (r = 0.33, p = 0.07) or ejection fraction (r = 0.21, p = 0.26). By multivariate analysis, Ea was the best variable for differentiating constriction from restriction. CONCLUSIONS: Our study indicates that longitudinal axis expansion velocities are markedly reduced in patients with restrictive cardiomyopathy. The poor correlation found with transvalvular flow velocities suggests that Ea may be relatively preload independent. The measurement of longitudinal axis expansion velocities provides a clinically useful distinction between constrictive pericarditis and restrictive cardiomyopathy and may prove to be valuable in the study of diastolic function.     

A new nonlinear directional overcurrent relay coordination technique, and banes and boons of near-end faults based approach

Considerations of weight factors and far-end faults in the directional overcurrent relay coordination problem formulation do not affect the optimal solution. This paper investigates this viewpoint and verifies that indeed by such an approach the optimality is not lost. But, this study reveals that in doing so, the coordination quality is sacrificed to some extent. It is also observed that if all remaining valid constraints (after relaxing few constraints based on the back-up coordination philosophy and strength of fault level generated) are considered and if the objective function is changed to running sum of all violating constraints, all valid considered constraints are satisfied. This study is done by simultaneously optimizing all settings in nonlinear environment by Sequential Quadratic Programming method using Matlab Toolbox. The results of the analysis on a sample 6-bus and IEEE 30-bus systems are presented in this paper.     

Solubility of fatty acids in supercritical carbon dioxide

The solubilities of lauric, linoleic, myristic, oleic, palmitic and stearic acid in supercritical carbon dioxide (SC-CO₂) at different pressures and temperatures were measured. The solubility values obtained in this work were compared with previously published data, and possible causes for observed discrepancies were discussed. The solubilities of the six fatty acids were modeled by Chrastil’s equation, and estimated model parameters were used to plot the solubility isotherms of fatty acids at 313, 323 and 333°K (40, 50 and 60°C) as a function of SC-CO₂ density. The comparison of solubility isotherms of fatty acids and vegetable oil suggests that separation of fatty acids from triglycerides might be possible by using SC-CO₂ at densities less than 700 kg/m³. From the effect of temperature on fatty-acid and vegetable-oil solubility, it seems that the extraction yield could be increased without sacrificing the selectivity of SC-CO₂ for fatty acids by choosing a higher operating temperature. The data also suggest that fractionation of certain fatty acids might be possible by manipulating the processing conditions. Given the values of the constants, Chrastil’s equation could serve as a guideline for choosing appropriate processing conditions and predicting the effect of pressure and temperature of SC-CO₂ on solute solubility.     

Evaluation of elastic moduli of composite materials by linear programming

A method of applying linear programming to evaluate the elastic moduli of unidirectionally fiber-reinforced composite materials is presented. Based on the theory of elasticity, the stresses and displacements of the fiber and of the resin are expressed in terms of harmonic series. The coefficients of the series are determined by the simplex algorithm to minimize the deviations which occur when the stresses and displacements are matched at the fiberresin interface and at the outer boundary of the representative element of the composite. By applying the energy principle, the Young's modulus in the fiber direction and the major Poisson's ratio of the E-glass/resin composite are found to be in good agreement with existing results, while the gap of the bounds for its bulk modulus is considerably narrowed in comparison to earlier results.