Immobilization of Metalloporphyrin on Functionalized MCM-48 Nanoporous Silica as a Catalyst in Oxidation of Cyclohexene: The Effects of Nanoporous Structure of MCM-48 on Its Catalytic Efficiency

MCM-48 nanoporous silica were prepared by the sol–gel method and functionalized by pyridine using a silane agent. With the aid of pyridines on the surface, the nanoporous material was used as a support for immobilization of metalloporphyrin. The formation of this material was confirmed by infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, inductively coupled plasma atomic emission spectroscopy analysis and specific surface area measurement. The application of this metalloporphyrin-immobilized MCM-48 was investigated as a heterogeneous catalyst in cyclohexene oxidation. Various parameters such as solvent and time were optimized. Also the effect of nanoporous structure on the efficiency of the catalyst was investigated by comparing the results with the same composite using nonporous silica (SiO₂). The result showed that the MCM-48 immobilized metalloporphyrin is a better catalyst for cyclohexene oxidation, which can be attributed to its nanoporous structure. The nanoporous structure increases the surface area of MCM-48 and leads to more metalloporphyrin immobilization.     

Mathematical Behavior of Optical Density of γ-Ray Radiography Images of Steel Pipes

Russian Journal of Nondestructive Testing - The purpose of this article is to determine the mathematical function of the optical behavior of radiographic films/images produced by gamma-ray...     

Robust metaheuristics for group scheduling with sequence-dependent setup times in hybrid flexible flow shops

This paper considers group scheduling problem in hybrid flexible flow shop with sequence-dependent setup times to minimize makespan. Group scheduling problem consists of two levels, namely scheduling of groups and jobs within each group. In order to solve problems with this context, two new metaheuristics based on simulated annealing (SA) and genetic algorithm (GA) are developed. A design procedure is developed to specify and adjust significant parameters for SA- and GA-based metaheuristics. The proposed procedure is based on the response surface methodology and two types of objective function are considered to develop multiple-objective decision making model. For comparing metaheuristics, makespan and elapsed time to obtain it are considered as two response variables representing effectiveness and efficiency of algorithms. Based on obtained results in the aspect of makespan, GA-based metaheuristic is recommended for solving group scheduling problems in hybrid flexible flow shop in all sizes and for elapsed time SA-based metaheuristic has better results.     

A novel imperialist competitive algorithm for bi-criteria scheduling of the assembly flowshop problem

This paper deals with the two-stage assembly flowshop scheduling problem with minimisation of weighted sum of makespan and mean completion time as the objective. The problem is NP-hard, hence we proposed a meta-heuristic named imperialist competitive algorithm (ICA) to solve it. Since appropriate design of the parameters has a significant impact on the algorithm efficiency, we calibrate the parameters of this algorithm using the Taguchi method. In comparison with the best algorithm proposed previously, the ICA indicates an improvement. The results have been confirmed statistically.     

Extraction and purification of penicillin G from fermentation broth by water-compatible molecularly imprinted polymers

Highly selective molecularly imprinted polymer (MIP) was synthesized by using methacrylic acid as functional monomer, trimethylolpropane trimethacrylate as cross-linker, chloroform as porogen and penicillin G potassium as template molecule. These imprinted polymers were used as solid-phase extraction sorbent for the selective extraction of penicillin G from the fermentation broth samples. Various parameters affecting the extraction efficiency of the MIP particles such as; effects of pH, wash and eluent solutions were evaluated. Molecular recognition properties and selectivity of these MIPs were estimated and the obtained results revealed high affinity for the target antibiotic. Equilibrium binding experiments were done to assess the performance of the MIP relative to non imprinted polymer (NIP). After optimizing the extraction parameters in molecularly imprinted solid-phase extraction (MISPE), successful imprinting was confirmed by comparison of the recoveries from the fermentation broth, ranging between 24–26% (RSD 4.1–4.5%, n = 4) for the NIPs and 83–88% (RSD 3.1–3.4%, n = 4) for the MIPs.     

Plasticity modeling of FRP-confined circular reinforced concrete columns subjected to eccentric axial loading

This paper presents a numerical study on FRP-wrap strengthened reinforced concrete columns subjected to eccentric axial loads using ABAQUS®. For modeling of concrete dilation under non-uniform confinement pressure, a smooth cap plasticity model was combined with concrete damaged plasticity model. This model includes different concrete compaction–dilation behaviors which is pressure-dependent. Proposed model has been calibrated and verified for concrete in number of unconfined and full-wrapped columns under combination of axial force and bending moment. Presented numerical predictions are shown to be in close agreement with existing experimental results. The effect of laminate stacking sequences and column slenderness on strength and ductility of members was examined thoroughly. The results of this study recommend taking fiber angles between zero (circumferential) and 30° can improve ultimate strength and ductility of confined short concrete columns. However, for slender concrete columns the optimum fiber orientation can be set between 15° and 30°.