Paradigm change: small machine tools for small workpieces

To overcome current limitations in micro manufacturing a new approach instead of evolutionary small step progress has to take place. Applying small machine tools to manufacture small workpieces allows for a leap of improvements enabled by the small size itself. This miniaturization in comparison to simply down-scaling current concepts qualifies the use of materials and technologies commonly not found in machine tools. This contribution describes the aspects, methodology, qualifications as well as cause and effects pursued by the approach of small machine tools for small workpieces.     

Synthesis and crosslinking of partially disulfonated poly(arylene ether sulfone) random copolymers as candidates for chlorine resistant reverse osmosis membranes

Biphenol-based, partially disulfonated poly(arylene ether sulfone)s synthesized by direct copolymerization show promise as potential reverse osmosis membranes. They have excellent chlorine resistance over a wide range of pHs and good anti-protein and anti-oily water fouling behavior. Crosslinking of these copolymers that have high degrees of disulfonation may improve salt rejection of the membranes for reverse osmosis performance. A series of controlled molecular weight, phenoxide-endcapped, 50% disulfonated poly(arylene ether sulfone)s were synthesized. The copolymers were reacted with a multifunctional epoxy resin and crosslinked thermally. The effects on network properties of various factors such as crosslinking time, copolymer molecular weight and epoxy concentration were investigated. The crosslinked membranes were characterized in terms of gel fraction, water uptake, swelling and self-diffusion coefficients of water. The salt rejection of the cured membranes was significantly higher than that for the uncrosslinked copolymer precursors.     

Pulmonary surfactant suppressed phenanthrene adsorption on carbon nanotubes through solubilization and competition as examined by passive dosing technique

Adsorption of phenanthrene on carbon nanotubes (CNTs) was examined in the presence of pulmonary surfactant (Curosurf) and its main components, dipalmitoyl phosphatidylcholine (DPPC) and bovine serum albumin (BSA). A passive-dosing method based on equilibrium partitioning from a preloaded polymer was successfully employed to measure phenanthrene binding and speciation at controlled freely dissolved concentrations while avoiding phase separation steps. Curosurf, DPPC, and BSA could all linearly solubilize phenanthrene, and phenanthrene solubilization by Curosurf was 4 times higher than individual components (DPPC or BSA). In the presence of Curosurf, DPPC or BSA, adsorption of phenanthrene by multiwalled CNTs (MWCNTs) was suppressed, showing competitive adsorption between pulmonary surfactant (or DPPC, BSA) and phenanthrene. Competitive adsorption between Curosurf and phenanthrene was the strongest. Therefore, when phenanthrene-adsorbed CNTs enter the respiratory tract, phenanthrene can be desorbed due to both solubilization and competition. The bioaccessibility of phenanthrene adsorbed on three MWCNTs in the respiratory tract would be positively related to the size of their outer diameters. Moreover, the contribution of solubilization and competition to desorption of phenanthrene from MWCNTs was successfully separated for the first time. These findings demonstrate the two mechanisms on how pulmonary surfactants can enhance desorption and thus possibly biological absorption of phenanthrene adsorbed on CNTs.     

Dynamic relaxation characteristics of thermally rearranged aromatic polyimides

The glass–rubber and sub-glass relaxation characteristics of ortho-functionalized aromatic polyimides and thermally rearranged polymers were investigated by dynamic mechanical and dielectric methods. Soluble polyimides (HAB–6FDA; APAF–ODPA) were synthesized by chemical and thermal imidization and subject to thermal rearrangement at elevated temperature. For the thermal exposure histories investigated, mass loss studies indicated partial conversion of the polyimide precursor, suggesting the formation of TR copolymers containing both benzoxazole units and residual imide segments. Measurement of storage modulus and loss tangent was used to follow the thermal rearrangement process in-situ as reflected in the suppression of the polyimide glass transition as a function of precursor structure, the nature of the ortho functional groups and prior thermal exposure. In addition, changes in the position and intensity of local relaxations detected across the sub-glass temperature range were correlated with the degree of thermal rearrangement in these polymers.     

Regression verification: proving the equivalence of similar programs

Proving the equivalence of successive, closely related versions of a program has the potential of being easier in practice than functional verification, although both problems are undecidable. There are three main reasons for this claim: (i) it circumvents the problem of specifying what the program should do; (ii) the problem can be naturally decomposed and hence is computationally easier; and (iii) there is an automatic invariant that enables to prove equivalence of loops and recursive functions in most practical cases. Theoretical and practical aspects of this problem are considered. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of metallization characteristics on gold wire bondability of organic printed circuit boards

Organic printed circuit boards (PCBs) with Au/Ni plates on bond pads are widely used in chip-on-board (COB), ball grid array (BGA), and chip-scale packages. These packages are interconnected using thermosonic gold wire bonding. The wire bond yield relies on the bondability of the Ni/Au pads. Several metallization parameters, including elemental composition, thickness, hardness, roughness, and surface contamination, affect the success of the solid state joining process. In this study, various characterization and mechanical testing techniques are employed to evaluate these parameters for different metallization schemes with varying Ni and Au layer thicknesses. The pull force of Au wires is measured as a function of plasma treatment applied before wire bonding to clean the bond pads. Close correlations are established between metallization characteristics and wire bond quality.     

Organizing drug injectors against AIDS: Preliminary data on behavioral outcomes.

Describes a project based on organizing drug injectors to change their subculture in ways that promote lower risk behaviors. Initial and follow-up interviews were conducted with 368 Ss. Findings indicate a decline in high-risk behaviors such as renting or borrowing used syringes and an increase in risk-reducing behaviors such as using new syringes and condoms. Almost half the Ss entered drug abuse treatment during the follow-up period; 60% taught others to use bleach to decontaminate injecting equipment. Risk reduction was greater among Ss who attended group meetings. Thus, organizing drug injectors is a feasible intervention that should be adopted elsewhere. Drug injectors can take on responsibility in combating AIDS. All evaluations of interventions should measure Ss' efforts to spread the message to others. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Pure gas and vapor permeation properties of poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene] (PTMSDPA) and its desilylated analog, poly[diphenylacetylene] (PDPA)

The permeabilities of He, H₂, N₂, O₂, CO₂, CH₄, C₂H₆, C₃H₈, and n-C₄H₁₀ in poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene] (PTMSDPA) and poly[diphenylacetylene] (PDPA) are presented and compared to those of poly(1-trimethylsilyl-1-propyne) (PTMSP), poly(1-phenyl-1-propyne) (PPP), and polysulfone. Like PTMSP, PTMSDPA, a disubstituted glassy acetylene-based polymer, exhibits higher permeabilities to organic vapors than to permanent gases due to its rigid polyacetylene backbone and bulky side groups, which provide a relatively high fractional free volume (FFV) value of 0.26. Desilylation was performed on PTMSDPA. The resulting material, PDPA, is totally insoluble in common organic solvents, so it has much higher chemical resistance than PTMSDPA. Additionally, due to its insolubility in polymerization solvents, desilylation provides the only known route to high molar mass PDPA. The FFV of the resulting membrane (PDPA) is reduced by approximately 12% relative to that of PTMSDPA. This leads to a decrease in gas permeability values and selectivity of organic vapors relative to nitrogen. For example, the oxygen permeability is reduced from 1200 to 500 Barrers upon desilylation. The pure gas selectivities decrease from 9 to 3 for n-C₄H₁₀/N₂ and from 26 to 9 for C₃H₈/N₂.     

Experiences from the design, deployment, and usage of the UCSB MeshNet testbed

In this article we report on our effort and experience in designing, deploying, and using our 30-node wireless mesh testbed, the University of California at Santa Barbara (UCSB) MeshNet. Compared to simulation, the construction and utilization of a wireless mesh testbed poses many new challenges. We discuss the challenges with distributed testbed management, nonintrusive and distributed monitoring, and node status visualization. These are vital components in a sustainable wireless mesh testbed, but at the same time nontrivial to design and. realize. As a case study, we present the UCSB MeshNet architecture, including its management, monitoring, and visualization systems. We share our lessons learned from this effort and believe that they are valuable to other researchers who develop experimental wireless mesh networks.     

The privacy of dense symmetric functions

Ann argument function,f, is calledt-private if there exists a distributed protocol for computingf so that no coalition of at mostt processors can infer any additional information from the execution of the protocol. It is known that every function defined over a finite domain is [(n–1)/2]-private. The general question oft-privacy (fort[n/2]) is still unresolved.In this work, we relate the question of [n/2]-privacy for the class of symmetric functions of Boolean argumentsf: {0, 1} ⁿ {0, 1,...,n} to the structure of Hamming weights inf ^–1(b) (b{0, 1, ...,n}). We show that iff is [n/2]-private, then every set of Hamming weightsf ^–1(b) must be an arithmetic progression. For the class ofdense symmetric functions (defined in the sequel), we refine this to the following necessary and sufficient condition for [n/2]-privacy off: Every collection of such arithmetic progressions must yield non-identical remainders, when computed modulo the greatest common divisor of their differences. This condition is used to show that for dense symmetric functions, [n/2]-privacy impliesn-privacy.