Compact spectrum splitting photovoltaic module with high efficiency

We have designed, fabricated, and tested a small, integrated photovoltaic module comprised of two separately‐contacted, high efficiency, multijunction solar cells and non‐imaging optics that both concentrate and spectrally split the incoming light. This hybrid design allows us to individually optimize the tandem cells and optical elements. The system has a measured module efficiency, including optical and packaging losses but not power combination losses, of 38.5 ± 1.9% under the AM1.5 direct terrestrial spectrum. The internal optics concentrate the light by a factor of approximately 20. We find excellent agreement between the modeled and measured performance. This is the highest confirmed conversion efficiency demonstrated for a photovoltaic module. Copyright © 2010 John Wiley & Sons, Ltd.     

Holographic interferometers with photorefractive recording media

We discuss two types of holographic interferometer that contain photorefractive recording media. The first type contains two beams interacting in a photorefractive medium. The second type utilizes a single beam and relies on self-pumped phase conjugation from a photorefractive crystal to make phase changes appear as intensity changes. We show both theoretically and experimentally that the first type can be analyzed in a straightforward manner; however, the second type cannot be approximated as simply a special case of the first type, as one may n?ively suspect.     

Sensitivity and optimization of a high-Q sapphire dielectric motion-sensing transducer

A high-Q sapphire dielectric motion sensing transducer that operates at microwave frequencies has been developed. The device uses cylindrical whispering gallery modes of quality factor greater than 10 (5) at room temperature and greater than 10(8) at 4 K. The tuning coefficient of the transducer resonance frequency with respect to displacement was measured to be of the order of a few MHz/mum. An electromagnetic model that predicts the resonant frequency and tuning coefficient has been developed and was verified by experiment. We implemented the model to determine what aspect ratio and what dielectric mode is necessary to maximize the sensitivity. We found that the optimum mode type was a TM whispering gallery mode with azimuthal mode number of about 7 for a resonator of 3 cm in diameter. Also, we determined that the tuning coefficients were maximized by choosing an aspect ratio that has a large diameter with respect to the height. By implementing a microwave pump oscillator of SSB phase noise -125 dBc/Hz at 1 kHz; offset, we have measured a sensitivity of order 10 (-16) m/ radicalHz. We show that this can be improved with existing technology to 10(-18) m/ radicalHz, and that in the near future this may be further improved to 10(-19) m/ radicalHz.     

Temperature-compensated cryogenic Fabry-Perot cavity

We show that temperature compensation based on differential thermal expansion between sapphire and fused silica can be used to create a Fabry-Perot cavity with an exceptionally low coefficient of thermal expansion at low temperatures. We describe the design of such a cavity that utilizes shaped fused silica mirrors and a sapphire spacer. The geometry of the fused silica mirror was designed using a finite element model to have a small platform, giving a frequency temperature turning point of 16.6 K. The measured turning point was 16.2 K and the curvature was 6 x 10(-10) K(-2), both of which were consistent with the model.     

Co-Evolution in the Successful Learning of Backgammon Strategy

Following Tesauro's work on TD-Gammon, we used a 4,000 parameter feedforward neural network to develop a competitive backgammon evaluation function. Play proceeds by a roll of the dice, application of the network to all legal moves, and selection of the position with the highest evaluation. However, no backpropagation, reinforcement or temporal difference learning methods were employed. Instead we apply simple hillclimbing in a relative fitness environment. We start with an initial champion of all zero weights and proceed simply by playing the current champion network against a slightly mutated challenger and changing weights if the challenger wins. Surprisingly, this worked rather well. We investigate how the peculiar dynamics of this domain enabled a previously discarded weak method to succeed, by preventing suboptimal equilibria in a meta-game of self-learning.     

Reactions of fuel-nitrogen compounds under conditions of inert pyrolysis

As part of a study of the chemical mechanisms involved in the conversion of fuel-nitrogen compounds to nitric oxide during combustion, fossil fuels and model nitrogen compounds were pyrolysed in helium in a small quartz flow reactor. Hydrogen cyanide was the major nitrogen-containing product obtained in all cases indicating that hydrogen cyanide is formed during the initial pre-flame stages of combustion and is the principal intermediate in the formation of fuel nitric oxide. At a nominal residence time of one second, 50% decomposition of pyrrole, quinoline, benzonitrile and pyridine occurs at 905, 910, 922 and 954 °C, respectively. The fraction of the nitrogen in pyridine that is converted to hydrogen cyanide increases from 40% at 960 °C to 100% at 1100 °C. Benzonitrile produces similar amounts of hydrogen cyanide (49 and 82%). The hydrogen cyanide yields from coals and residual fuel oils increase from the range of 15–25% at 950 °C to 23–42% at 1100 °C. It is not possible to determine from these single-stage experiments if most of the hydrogen cyanide forms in the primary pyrolysis process or in secondary reactions.     

The effect of coalescence on drop size distribution in an agitated liquid-liquid dispersion

A procedure involving high speed cine photography and novel optical probes has been used to study droplet interaction phenomena in liquid-liquid dispersions. Coalescence and breakup events were observed and the rate of coalescence was measured at various positions in a stirred tank for dispersions of methylisobutylketone in water. For the conditions studied, drop breakup occurred near the impeller and droplet coalescence predominated at other locations, as expected. However, the extent of this behavior was unexpected. Beyond distances from the impeller region of order of only $\text{1}\text{6}$ the impeller diameter, breakup was virtually nonexistent. Outside the impeller region, extensive coalescence measurements showed (1) collisions between droplets are extremely inefficient for this chemically equilibrated system—at most 10% of collisions result in a coalescence, (2) only binary coalescence occurs even at the highest dispersed phase concentration investigated, (3) coalescence rate shows little preference on drop size, and (4) the coalescence rate is directly proportional to turbulence level; that is, the highest coalescence rates occur closest to the impeller. On the basis of these measurements, drop balance methods and a circulation path model were used to relate the drop size distribution at various locations in the region where coalescence predominates. In this case good agreement was obtained between measured and predicted drop size distributions.     

Studies in the lightfastness of nitrodiphenylamine dyes

Studies of the photofading of nitrodiphenylamine dyes have been made in ethanolic solution. It has been shown that the presence of oxygen during photoirradiation of the solution acts as an inhibitor, causing an induction period before degradation commences. The results suggest that the intermediate in the degradation is a triplet state, and this is quenched by oxygen. The “deactivated” oxygen molecules, so formed, can be reactivated by collision with “normal” oxygen molecules. The enhancement of photodegradation in the presence of hydrogen donors suggests that the degradation mechanism is reductive in nature. The influence of the positions of the nitro-groups in the diphenylamine derivatives supports the postulate that the reaction proceeds via quinonoid forms. The absence of brown degradation products suggests that the mechanism of degradation is not the same as that occurring on solid substrates, although the order of dye stability is the same in both cases.     

Effects of increasing acidity on metal(loid) bioprecipitation in groundwater: column studies

Large-scale column experiments were carried out over a period of 545 days to assess the effect of increasing acidity on bacterial denitrification, sulfate reduction, and metal(loid) bioprecipitation in groundwater affected by acid mine drainage. At a groundwater pH of 5.5, denitrification and Cu2+ removal, probably via malachite (Cu2(OH)2CO3) precipitation, were observed in the ethanol-amended column. Sulfate reduction, sulfide production, and Zn2+ removal were also observed, with Zn2+ removal observed in the zone of sulfate reduction, indicating likely precipitation as sphalerite (ZnS). Se6+ removal was also observed in the sulfate reducing zone, probably as direct bioreduction to elemental selenium via ethanol/acetate oxidation or sulfide oxidation precipitating elemental sulfur. A step decrease in groundwater pH from 5.5 to 4.25 resulted in increased denitrification and sulfate reduction half-lives, migration of both these redox zones along the ethanol-amended column, and the formation of an elevated Cu2+ plume. Additionally, an elevated Zn2+ plume formed in the previous sulfate reducing zone of the ethanol-amended column, suggesting dissolution of precipitated sphalerite as a result of the reduction in groundwater pH. As Cu2+ passed through the zone of sphalerite dissolution, SEM imaging and EDS detection suggested that Cu2+ removal had occurred via chalcocite (Cu2S) or covellite (CuS) precipitation.