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排序方式: 共有1470条查询结果,搜索用时 15 毫秒
91.
Dheeraj Kumar Singh Till Fuchs Christian Krempaszky Boris Mogwitz Simon Burkhardt Felix H. Richter Jürgen Janek 《Advanced functional materials》2023,33(1):2211067
Enabling the lithium metal anode (LMA) in solid-state batteries (SSBs) is the key to developing high energy density battery technologies. However, maintaining a stable electrode–electrolyte interface presents a critical challenge to high cycling rate and prolonged cycle life. One such issue is the interfacial pore formation in LMA during stripping. To overcome this, either higher stack pressure or binary lithium alloy anodes are used. Herein, it is shown that fine-grained (d = 20 µm) polycrystalline LMA can avoid pore formation by exploiting the microstructural dependence of the creep rates. In a symmetric cell set-up, i.e., LiǀLi6.25Al0.25La3Zr2O12(LLZO)ǀLi, fine-grained LMA achieves > 11.0 mAh cm−2 compared to ≈ 3.6 mAh cm−2 for coarse-grained LMA (d = 295 µm) at 0.1 mA cm−2 and at moderate stress of 2.0 MPa. Smaller diffusion lengths (≈ 20 µm) and higher diffusivity pathway along dislocations (Dd ≈ 10−7 cm2 s−1), generated during cell fabrication, result in enhanced viscoplastic deformation in fine-grained polycrystalline LMA. The electrochemical performances corroborate well with estimated creep rates. Thus, microstructural control of LMA can significantly reduce the required stack pressure during stripping. These results are particularly relevant for “anode-free” SSBs wherein both the microstructure and the mechanical state of the lithium are critical parameters. 相似文献
92.
Alex Frano Eva Benckiser Yi Lu Meng Wu Miguel Castro‐Colin Manfred Reehuis Alexander V. Boris Eric Detemple Wilfried Sigle Peter van Aken Georg Cristiani Gennady Logvenov Hanns‐Ulrich Habermeier Peter Wochner Bernhard Keimer Vladimir Hinkov 《Advanced materials (Deerfield Beach, Fla.)》2014,26(2):258-262
93.
Direct injection of samples on high-resolving mass spectrometers is an effective way to maximize analytical throughput and yet allow analyte discrimination in complex samples by mass-to-charge ratio. We present a platform of flow injection electrospray-time-of-flight mass spectrometry to profile small molecules in >1400 biological extracts per day at native mass resolution. We comprehensively benchmark the performance with more than 5000 injections of chemically defined standards and Escherichia coli cellular extracts obtained from miniscale cultivations. For at least 90% of tested compounds, we attain a linear response over 3 decades of concentration, interday coefficient of variation of <20%, and a mass accuracy of <0.001 amu. In polar Escherichia coli fractions, we reproducibly detected >1500 distinct ions in each mode. The accurate mass and correlation analysis enabled one to assign with good confidence 400-800 ions to electrospray derivatives of metabolites listed in the genome-wide reconstruction of Escherichia coli metabolism. Hence, we attain a coverage of about one-quarter of the total number of compounds listed in the reconstruction. Finally, we present an exemplary screen with Escherichia coli deletion mutants to show the exquisite capacity of the platform to identify lesions in primary metabolism at high throughputs. 相似文献
94.
A suffix tree approach to anti-spam email filtering 总被引:1,自引:0,他引:1
We present an approach to email filtering based on the suffix tree data structure. A method for the scoring of emails using
the suffix tree is developed and a number of scoring and score normalisation functions are tested. Our results show that the
character level representation of emails and classes facilitated by the suffix tree can significantly improve classification
accuracy when compared with the currently popular methods, such as naive Bayes. We believe the method can be extended to the
classification of documents in other domains.
Editor: Tom Fawcett 相似文献
95.
This paper analyses the load influence on a d.c. drive motor servo system for all six degrees of freedom of industrial robots with an articulated configuration. Through the analyses, the analytical equations of total inertia and gravitation moments of an industrial robot servo system for external coordinate function were obtained. A mathematical model of an electro-mechanical industrial robot system was also developed. 相似文献
96.
Boris Krasovitski 《The Journal of Adhesion》2013,89(7-8):869-880
The adhesion of spheroidal particles to spherical drops is calculated and discussed in terms of an equilibrium-penetration index. The present study emphasizes the case of particles that are sufficiently large to affect the drop volume upon penetration. It is shown that the more elongated the particles, the steeper the dependence of the penetration index on the contact angle. The effect of line tension on nanoscale particles is considered. Positive line tensions increase the steepness of the dependence of penetration index on contact angle whereas negative line tensions decrease this dependence. In addition, the energy barrier caused by positive line tensions is presented and discussed. 相似文献
97.
Dr. Alessia Amore Kim Wals Evelyn Koekoek Rieuwert Hoppes Mireille Toebes Prof. Ton N. M. Schumacher Dr. Boris Rodenko Prof. Huib Ovaa 《Chembiochem : a European journal of chemical biology》2013,14(1):123-131
Incorporation of cleavable linkers into peptides and proteins is of particular value in the study of biological processes. Here we describe the synthesis of a cleavable linker that is hypersensitive to oxidative cleavage as the result of the periodate reactivity of a vicinal amino alcohol moiety. Two strategies directed towards the synthesis of a building block suitable for solid‐phase peptide synthesis were developed: a chemoenzymatic route, involving L ‐threonine aldolase, and an enantioselective chemical route; these led to α,γ‐diamino‐β‐hydroxybutanoic acids in diastereoisomerically mixed and enantiopure forms, respectively. Incorporation of the 1,2‐amino alcohol linker into the backbone of a peptide generated a conditional peptide that was rapidly cleaved at very low concentrations of sodium periodate. This cleavable peptide ligand was applied in the generation of MHC exchange reagents for the detection of antigen‐specific T cells in peripheral blood cells. The extremely low concentration of periodate required to trigger MHC peptide exchange allowed the co‐oxidation of methionine and disulfide residues to be avoided. Conditional MHC reagents hypersensitive to periodate can now be applied without limitations when UV irradiation is undesired or less practical. 相似文献
98.
Increasing Productivity through Integrated Production Engineering and Processing Expertise The future of production engineering is interdisciplinary. Between product innovation and product marketing there lies a design process which has to be optimised and which is interdisciplinary in character. The design process has to satisfy the demands of global markets on chemical products, which lead, for example, to shorter and shorter product life cycles, and to demands for low production costs, high and consistent product quality, and faster market launches. 相似文献
99.
Sub‐Terahertz Frequency‐Domain Spectroscopy Reveals Single‐Grain Mobility and Scatter Influence of Large‐Area Graphene 下载免费PDF全文
100.
New efficient intermetallide catalysts for hydrogen storage in reversible processes of aromatics hydrogenation and naphthene dehydrogenation were studied. These catalysts provide an enhanced activity in the dehydrogenation of saturated organic molecules, with no side reactions like cracking, hydrogenolysis, ring opening, or coke formation occurring on these catalysts. The use of intermetallides provides some hydrogen storage capacity in the low-temperature region, while their catalytic activity in the dehydrogenation affords the hydrogen supply in the high-temperature range. 相似文献