Electrochromic properties of tungsten-molybdenum oxide electrodes

Tungsten oxide and molybdenum doped tungsten oxide electrochromic films have been electrochemically prepared from a metal peroxide bath and experimentally tested. They were characterized by electrical and optical methods, using cyclic voltammograms and calculating the charge capacity as a function of the number of deposition cycles.The color of the electrochromic WO₃ film is strongly altered by doping it with molybdenum. Electrochromic W---Mo oxide films were fabricated by adding different percentages of molybdenum to tungsten oxide, ranging from 0.5% to 7% weight of deposition solution. Normal optical transmittance was also measured and evidence is given of different behavior if the switching for oxidation and reduction cycle, so that coloration occurs in a shorter time than the bleaching. The time constant of the process tends to increase as a function of the molybdenum oxide doping concentration.     

Analysis of a multiple-cell direct-sequence CDMA cellular mobileradio system

The performance of a multiple-cell direct-sequence code division multiple-access cellular radio system is evaluated. Approximate expressions are obtained for the area-averaged bit error probability and the area-averaged outage probability for both the uplink and downlink channels. The analysis accounts for the effects of path loss, multipath fading, multiple-access interference, and background noise. Two types of differentially coherent receivers are considered: a multipath rejection receiver and a RAKE receiver with predetection selective combining. Macroscopic base station diversity techniques and uplink and downlink power control are also topics of discussion     

An incomplete gauge formulation for 3D nodal finite-elementmagnetostatics

A method for imposing the gauge condition on the 3-D magnetic vector potential magnetostatic field computation using nodal finite elements is presented. In this method, the gauge A.w=0 is applied in the part of the problem that is not situated in the neighborhood of the materials interfaces that are tangential to w . This results in a formulation which maintains the discontinuous properties of the magnetic induction tangential components, reduces the number of unknowns, and improves the system matrix conditioning. The proposed formulation is compared with the Coulomb-gauge and ungauged formulations, showing that it results in better precision and worse conditioning than the Coulomb-gauge and has the same precision with a better conditioning than the ungauged formulation     

Preparation of Poly(D,L-Lactide/Glycolide) Nanoparticles of Controlled Particle Size Distribution: Application of Experimental Designs

This study investigates the use of the solvent evaporation method for preparing acid and glycolic acid-based copolymer nanoparticles. Initially, appropriate technological and formulation factors for elaboration of polymeric particles were selected by screening. Most favourable results were obtained using polyvinyl alcohol as a dispersing agent and a high pressure homogenizer to reduce the droplet size of the emulsion initially formed. On the basis of the conclusion thus drawn, a composite rotational experimental design was employed to evaluate the joint influence of three formulation variables (phase volume ratio of the emulsion formed, polymer concentration and homogenization pressure) on the micromeritic properties of the suspension finally obtained (mean particle size, coefficient of variation and polydispersity of the particle size distribution). Analysis of variance corresponding to the experimental design, showed a significant influence of the volume phase ratio and the polymer concentration on the mean particle size and the coefficient of variation, whereas the polydispersity is also affected by the homogenization pressure. Considering this information, a 3² experimental factorial design was then selected to investigate the possible interaction between the phase volume ratio and the concentration of polyvinyl alcohol in the aqueous phase. Analysis of variance and subsequent sequencial regression analysis evidenced last hypothesis providing the way to determine the experimental conditions required to achieve a specific particle size distribution.     

Quartz microbalance study of4He and H2 on sodium

A quartz microbalance technique has been used to study the growth of⁴He and H₂ adsorbed on sodium. In contrast to cesium, adsorption of⁴He and H₂ do occur on a sodium surface.     

Micro-Raman spectroscopy study of the process of microindentation in polymers

The residual deformation produced by Vickers microindentations in poly(3,3-dimethyl oxetane) (PDMO) was analysed by Raman microspectroscopy. Microstructural variations were observed as the Raman spectra were recorded at different positions along and out of the microindentation. A gradual distribution of the monoclinic and orthorhombic structures arises as the spectra were scanned from the centre to the edge of the impression area. This crystalline variation in PDMO, which reflects the degree of stress present on the surface of the sample, was utilized to obtain information on the distribution of pressure in and around the microindentation. In addition to the clear variation of pressure inside the permanently deformed region, no crystalline transformation was noted out of the impression area. Similar features were observed when the Raman spectra were recorded along one of the diagonals of the indentation.     

Air Filtration and Radon Decay Product Mitigation

Air cleaning as a means of mitigating the risks arising from exposure to indoor radon progeny has been evaluated in a single-family house in the north eastem US. using an automated, semi-continuous activity-weighted size distribution measurement system. The measurements included radon concentration, condensation nuclei count, and activity-weighted size distribution of radon decay products. Measurements were made in the house with and without an operating air filtration system and with various particle sources common to normal indoor activities operating. Aerosols were generated by running water in a shower, candle burning, cigarette smoking, vacuuming, opening doors, and cooking. Using a room model, the changes in attachment rates, average attachment diameters, and deposition rates of the unattached fraction with and without the air cleaning system were calculated. In the presence of active aerosol sources, the air filtration unit typically reduced the concentration of particles within the hour following the end of particle generation. After candle burning, cigarette smoking, and vacuuming in the bedroom, the reductions of PAEC by air filtration are about 60% with the air filtration system operating in the bedroom. During cooking in the kitchen, the reductions of PAEC in the bedroom with the air filtration system were about 40%. However, for all cases the dose reductions were smaller than the particle and PAEC reductions. For those particles that were generated within the bedroom, there was a 20% to 50% reduction in dose. In the case of cooking where the door was open and particles infiltrated from the rest of the house, the dose reduction was only 5% on average and appears to be insignificant. Thus, the dose reductions were h e r than the reductions in activity concentration, but there were no cases where the estimated dose actually increased.     

Evaluation of a commercial process for collection and cooling of beef offals by a temperature function integration technique.

The hygienic adequacy of a commercial process for the collection and cooling of beef offals was assessed by a temperature function integration technique. The diverse operations for collection of offals were inspected. The rates of product movement through those operations, and the temperatures of products at the time of their being packed, were determined. From that information, four of the nine product types were selected for examination of their temperature histories during the assembly and cooling of the cartoned products. The products selected encompassed product at near-body and near-air-ambient temperatures at the time of packaging, product in the largest and smallest cartons used in the process, and product with relatively short and long residence times in an unchilled carton stack assembly area. Twenty-one temperature histories were collected for each of the products, and the possible proliferation of an indicator organism, Escherichia coli, calculated for each temperature history. The results were assessed against a temperature function integration criterion derived from studies of beef carcass and cartoned meat cooling processes. Products packaged at near-ambient temperature readily met with the criterion, but products packed at near-body temperatures did not comply. The latter non-compliance was extreme for product packaged in large cartons. However, the principal cause of non-compliance was identified as highly variable cooling conditions in the carton freezing facility. A brief survey of air speeds and temperatures within that facility indicated means by which product cooling could be better controlled.