Improvement in hydrolytic procedure for GLC determination of non-indolyl glucosinolates in rapeseed as isothiocyanates

Some methods determine the non-indolyl glucosinolates content in rapeseed as their hydrolysates: the isothiocyanates and the oxazolidinethiones. These methods in their present form underestimate the amount of the glucosinolates content. In this investigation, a modified method was developed to give a better quantitative estimate, indicating a glucosinolate level five times that obtained by a typical existing method.     

Patients' preferences for pain treatment modalities in a multidisciplinary pain clinic.

44 male and 74 female patients (aged 22–78 yrs) in a multidisciplinary pain clinic rated their preferences for 9 pain treatment modalities: ice, transcutaneous electronic nerve stimulation (TENS), relaxation, group therapy, social work, physical therapy, massage, heat, and lectures. Relaxation, physical therapy, and ice were most liked; TENS, heat, and social work were least liked. Multiple regression analyses indicated that preference for relaxation was the best predictor of decreased pain ratings, while preference for heat was correlated with increased pain ratings. Liking for physical therapy predicted self-ratings at discharge of positive well-being and minor life disruption. Liking for heat predicted self-ratings of major life disruption and nurses' ratings of pain behavior at discharge. Results suggest that treatment regimens should take into account patients' moods and personality styles. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Future increase in harmful algal blooms in the North Sea due to climate change.

In temperate seas such as the North Sea harmful (toxic) algal blooms will probably increase as a result of climate change. This conclusion was reached after investigating the projected effect of climate change for the year 2100 in Dutch coastal waters (4 degrees C temperature rise and increased water column stratification) on the growth rates of six harmful and two non-harmful phytoplankton species. Micro algae form the basis of the marine food chain. However, toxin-producing species may seriously disrupt the food web and lead to fish kills and human intoxication. Two species with estimated doubled growth rates in 2100, F. japonica and C. antiqua, entered Europe via ship's ballast water or shellfish imports. This stresses the need to legally regulate such invasion routes in order to prevent the import of novel species. Future toxic phytoplankton blooms may further devaluate ecosystem deliverables such as fish production or recreational use. This devaluation can be estimated by monetary value assessments that are needed in cost-benefit analyses for policy guidance. The lack of understanding of future climate, ecosystem functioning and its response to climate change calls for a scientific effort to improve our knowledge on present day coastal ecosystem functioning and its resilience.     

Determination du coefficient d'extinction molaire de OH− dans les verres fluores a base de metaux lourds

The extinction coefficient ? at 2.9 μm for OH in fluoride glasses is measured by determining the amount of HF evolved during heating of the glass under steam and the corresponding intensity of the OH absorption band. This coefficient is respectively equal to 31 litre mole^?1 cm^?1 for BTYbZ glass (15 BaF₂ - 29 ThF₄ - 28 YbF₃ - 28 ZnF₂) and 19.5 litre mole^?1 cm^?1 for BALLA glass (34 BaF₂ - 57 ZrF₄ - 4 AlF₃ - 5 LaF₃).     

FATIGUE DAMAGE IN 1045 STEEL UNDER VARIABLE AMPLITUDE BIAXIAL LOADING

Abstract— During constant amplitude loading, two different types of crack systems have been reported In the high cycle fatigue (HCF) region, cracks nucleate on a small number of maxium shear strain amplitude planes One of these cracks becomes a dominant crack and leads to failure of the specimen In the low cycle fatigue (LCF) region, equally developed microcracks are observed over the entire gage section and grow during the majority of the life. The failure is due to a linking in which the microcracks join up during the last few cycles of the fatigue life.
To investigate the interaction of these two types of crack systems in biaxial fatigue, experiments were performed on thin-wall tubular specimens in tension, torsion and combined tension-torsion loading The test program included step loading and block loading in which two equivalent strain amplitudes were employed. One of the equivalent strain amplitudes is in the HCF region and the other was in the LCF region
Fatigue lives were predicted from constant amplitude damage curves when a single crack system dominated the fatigue process Two competitive crack systems were sometimes developed on the maximum shear strain amplitude planes in a single specimen under block loading This resulted in a conservative prediction of the fatigue life.     

High-resolution electron microscopy of the twinning and intergrowth in Ca4Al6SO16 and Ca3SrAl6SO16

The microstructures of unhydrated calcium aluminosulphate Ca₄Al₆SO₁₆ and Ca₃SrAl₆SO₁₆ have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca₃SrAl₆SO₁₆ and another phase, possibly Sr₃Al₂O₆ existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced.     

Waveband-switchable SOA ring laser constructed with a phase modulator loop mirror filter

An electrically tunable multiwavelength source has been developed using a birefringence-based optical comb filter in a semiconductor optical amplifier ring laser. The filter is constructed with an electrooptic phase modulator placed inside a fiber loop mirror. By controlling the birefringence of the modulator through the applied bias, the radio-frequency power, or the modulation frequency, we achieve a continuous shift of the spectral comb to access different interleaved wavebands. Electrical waveband switching has been successfully demonstrated for 21 wavelengths at 100-GHz grid spacing with an optical signal-to-noise ratio over 40 dB.     

Widely tunable bottom-emitting vertical-cavity SOAs

We present bottom-emitting tunable vertical-cavity semiconductor optical amplifiers (VCSOAs) with an effective wavelength tuning range of >20 nm. These devices utilize a high reflectivity micromechanically tunable Bragg mirror as the back reflector. Compared with our first generation tunable VCSOAs, the bottom-emitting devices exhibit a two-fold increase in the effective tuning range as well as a five-fold reduction in the required tuning voltage.