N.m.r. line shape-relaxation correlation analysis of bitumen and oil sands

The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent.     

Analysis of polar compound classes in SRC-II liquids: Comparison of non-aqueous titrametric,i.r. spectrometric and h.p.l.c. methods

Results for various types of polar compounds in SRC-11 coal-derived liquids and other fuels were obtained by one or more of the three analytical methods: non-aqueous titration, i.r. spectroscopy and h.p.l.c. Practical aspects as well as precision, accuracy and assumptions necessary for effective application of each of the methods are discussed. H.p.l.c. is applicable to the widest variety of compound types, is the most rapid, most sensitive and shows the best promise for increased development and improvement. Application and development of these techniques is a logical step toward improving process monitoring, catalyst development, toxicological screening and general fuel analysis.     

The Effect of Moisture Content in Epoxy Film Adhesives on their Performance. II. T-Peel and 105°C Lap Shear Strength

The benefits of adhesively bonded structures are well known. However, the most significant factor limiting the extensive application of metal bonding in primary aerospace structures is the prevailing lack of confidence in its long term durability under hostile environmental conditions.^1,2     

Graft copolymerization onto rubber. VII. Graft copolymerization of methyl methacrylate onto rubber using potassium peroxydisulfate catalyzed by silver ion

The graft copolymerization of methyl methacrylate onto natural rubber (NR) was carried out varying the concentration of monomer, initiator, thiourea, and silver nitrate over a wide range. The grafting reaction was temperature-dependent. From the Arrhenius plot, the overall energy of activation was computed. A suitable reaction scheme and rate expression for the rate of polymerization was suggested.     

Bridging the research traditions of task/ego involvement and intrinsic/extrinsic motivation: Comment on Butler (1987).

In an experiment on the effects of different feedback conditions on motivationally relevant variables, R. Butler (see record 1988-21628-001) tested the hypothesis that the effects of feedback on intrinsic motivation would depend on whether that feedback promotes a task-involving or ego-involving orientation. She interpreted the findings as they relate to J. G. Nicholls's (see record 1984-28719-001) theory of task/ego involvement and our cognitive evaluation theory (E. L. Deci and R. M. Ryan, 1985). Although the data were very interesting, Butler failed to review a series of highly relevant studies, she misportrayed cognitive evaluation theory, and she drew conclusions that were not necessarily warranted given her experimental manipulations and data. This article provides a commentary on that research and presents a discussion of the relation between the two theories that Butler claimed to have tested. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

NMR Line Shape-Spin-Lattice Relaxation Correlation Study of Portland Cement Hydration

The proton free induction decay of a portland cement paste in an advanced stage of hydration can be roughly divided into three main components: (1) a component with a very short spin-spin relaxation time, T², representing the protons of the solid OH groups and the water of crystallization, (2) a component with an intermediate T, representing the bonded water in the gel phase, and (3) a third component with a relatively long T² representing the water in the micropores and layers. The dependences of the intensities, T²'s, and spin-lattice relaxation times (T¹'s) of these three components on the cement hardening time have been determined. The proton spin-lattice relaxation time of the "solid" component increases with hardening time whereas T¹ decreases for the other two components. The observed time dependence of the diffusion coefficient, D, of water in a tricalcium silicate paste supports the findings of the above correlation study.     

Fractoemission from Lead Zirconate-Titanate

We present measurements of the electron, positive ion, and photon emission accompanying the fracture in vacuum of poly-crystalline 95/5 lead zirconate-titanate. The intensities of the charged-particle components of this fractoemission are shown to depend strongly on the direction (relative to the direction of fracture) and magnitude of polarization. The most intense emission is observed when the fracture surfaces are perpendicular to the polarization direction. The emission intensity increases monotonically with polarization. These results are interpreted in terms of a model involving charge separation on the fracture surfaces leading to a microdischarge during fracture. Implications to the interpretation of triboluminesence effects are discussed.     

The function of bleaching earths in the processing of palm,palm kernel and coconut oils

The results presented in the literature, which attempt to elucidate the mechanisms by which triglyceride oils are bleached by earths, are reviewed. The impact of this work and how the mechanistic proposals affect changes in oil properties are considered, with particular emphasis on the needs of the palm oil processor. Important properties include color, metals and phosphorus content and oxidative stability of the oil. Investigations made in our own laboratories have been aimed at elucidating the effect of varying physical and chemical properties of the bleaching earth on the quality of bleached and deodorized oils. Techniques used in this work are pore-size distribution, surface area, scanning and transmission electron microscopy and a variety of chemical and X-ray analysis methods. The ability to vary such parameters in montmorillonite clays by alteration of process conditions to give materials with specific performance characteristics is demonstrated. Comparisons are made between acid-activated montmorillonites and other clay types.