Public Relations: State of the Field

Public relations is both a professional practice and a subfield of communication with its own research and theory base. Public relations is relatively young as an academic field, however, having developed identifiable theory in only about the last 50 years. The field of public relations is developing into a theoretically based area of applied communication that has the potential to inform several areas of communication/mass communication and to offer theoretic and conceptual tools useful in health, risk, and political communication, among others. Because many readers are unfamiliar with public relations theory and research, this article first reviews and summarizes theory-related scholarship in public relations, then categorizes and explains the theoretic trends in the field. The article concludes by demonstrating how one of public relations' theoretic/conceptual tools, issues management, can apply across all areas of applied communication.     

Thermoelectric quantum-dot superlattices with high ZT

Following the experimentally observed Seebeck coefficient enhancement in PbTe quantum wells in Pb_1−xEu_xTe/PbTe multiple-quantum-well structures which indicated the potential usefulness of low dimensionality, we have investigated the thermoelectric properties of PbSe_xTe_1−x/PbTe quantum-dot superlattices for possible improved thermoelectric materials. We have again found enhancements in Seebeck coefficient and thermoelectric figure of merit (ZT) relative to bulk values, which occur through the various physics and materials science phenomena associated with the quantum-dot structures. To date, we have obtained estimated ZT values approximately double the best bulk PbTe values, with estimated ZT as high as about 0.9 at 300 K.     

Demonstration of multi-core photonic crystal fibre in an optical interconnect

A novel microstructured fibre has been created for use in an optical interconnection system. The fibre has low crosstalk with a high density of cores corresponding to 1150 channels/mm/sup 2/. A repeating pseudorandom binary sequence has been used to demonstrate a four-channel transmit/receive system using vertical cavity surface emitting lasers as both emitters and detectors.     

Extrusion of YAG Tubes Shows that Bottom‐up Processing is Not Always Optimal

Liquid‐feed flame spray pyrolysis provides easily dispersed, unaggregated nanopowders with average particle sizes of 20–70 nm depending on the processing conditions. Their chemical compositions can be controlled to ppm levels via control of the initial precursor solution. In this paper, Y₃Al₅O₁₂ composition nanopowders are produced that are atomically mixed but offer a hexagonal crystal structure rather than a YAG structure. Y₂O₃ and δ‐Al₂O₃ nanopowders are also produced and mixed to evaluate reactive sintering. It is shown that nanopowder/polymer mixtures permit the extrusion of tubes that retain their shape on debindering and sintering to ≥95% theoretical density. More importantly, the sintering behavior of hex‐Y₃Al₅O₁₂ is compared with that of tubes formed using 3:5 Y₂O₃:δ‐Al₂O₃ mixtures to test the so‐called bottom‐up paradigm, which suggests that mixing on the finest length scales should provide optimal control of sintering rates, final densities, and grain sizes. Instead, it is found that reactive sintering is faster and offers better control of final grain sizes. Dense sintered tubes are translucent, and dimensional uniformity is maintained from extrusion through sintering.     

Optical Communication Using Subcarrier PSK Intensity Modulation Through Atmospheric Turbulence Channels

This paper studies optical communications using subcarrier phase shift keying (PSK) intensity modulation through atmospheric turbulence channels. The bit error rate (BER) is derived for optical communication systems employing either on/off key (OOK) or subcarrier PSK intensity modulation. It is shown that at BER = 10^-6 and a scintillation level of sigma = 0.1, an optical communication system employing subcarrier BPSK is 3 dB better than a comparable system using fixed-threshold OOK. When sigma = 0.2, an optical communication system employing subcarrier BPSK achieves a BER = 10^-6 at SNR = 13.7 dB, while the BER of a comparable system employing OOK can never be less than 10^-4. Convolutional codes are discussed for optical communication through atmospheric turbulence channels. Interleaving is employed to overcome memory effect in atmospheric turbulence channels. An upper bound on BER is derived for optical communication systems employing convolutional codes and subcarrier BPSK modulation.     

Photon-assisted capacitance–voltage study of organic metal–insulator–semiconductor capacitors

The results are reported of a detailed investigation into the photoinduced changes that occur in the capacitance–voltage (C–V) response of an organic metal–insulator–semiconductor (MIS) capacitor based on the organic semiconductor poly(3-hexylthiophene), P3HT. During the forward voltage sweep, the device is driven into deep depletion but stabilizes at a voltage-independent minimum capacitance, C_min, whose value depends on photon energy, light intensity and voltage ramp rate. On reversing the voltage sweep, strong hysteresis is observed owing to a positive shift in the flatband voltage, V_FB, of the device. A theoretical quasi-static model is developed in which it is assumed that electrons photogenerated in the semiconductor depletion region escape geminate recombination following the Onsager model. These electrons then drift to the P3HT/insulator interface where they become deeply trapped thus effecting a positive shift in V_FB. By choosing appropriate values for the only disposable parameter in the model, an excellent fit is obtained to the experimental C_min, from which we extract values for the zero-field quantum yield of photoelectrons in P3HT that are of similar magnitude, 10^?5 to 10^?3, to those previously deduced for π-conjugated polymers from photoconduction measurements. From the observed hysteresis we deduce that the interfacial electron trap density probably exceeds 10¹⁶ m^?2. Evidence is presented suggesting that the ratio of free to trapped electrons at the interface depends on the insulator used for fabricating the device.     

Quantification of Temperature-Dependent Charge Separation and Recombination Dynamics in Non-Fullerene Organic Photovoltaics

Transient optical spectroscopy is used to quantify the temperature-dependence of charge separation and recombination dynamics in P3TEA:SF-PDI₂ and PM6:Y6, two non-fullerene organic photovoltaic (OPV) systems with a negligible driving force and high photocurrent quantum yields. By tracking the intensity of the transient electroabsorption response that arises upon interfacial charge separation in P3TEA:SF-PDI₂, a free charge generation rate constant of ≈2.4 × 10¹⁰ s⁻¹ is observed at room temperature, with an average energy of ≈230 meV stored between the interfacial charge pairs. Thermally activated charge separation is also observed in PM6:Y6, and a faster charge separation rate of ≈5.5 × 10¹⁰ s⁻¹ is estimated at room temperature, which is consistent with the higher device efficiency. When both blends are cooled down to cryogenic temperature, the reduced charge separation rate leads to increasing charge recombination either directly at the donor-acceptor interface or via the emissive singlet exciton state. A kinetic model is used to rationalize the results, showing that although photogenerated charges have to overcome a significant Coulomb potential to generate free carriers, OPV blends can achieve high photocurrent generation yields given that the thermal dissociation rate of charges outcompetes the recombination rate.     

Complex resonances of conducting spheres with lossy coatings

The electromagnetic scattering amplitude for metal objects coated with a lossless dielectric exhibits a large number of resonances versus real frequency. These resonances are a function of the object shape and size, coating thickness, and coating electrical properties. Previously, it was shown that for coated spheres and nonspherical bare objects, these resonances can be understood in terms of phase matched circumnavigating surface waves and the objects' complex eigenfrequencies. The effect of dielectric loss in the coating on the complex eigenfrequencies and phase velocities of these surface waves is presented for a metal sphere coated with a uniform homogeneous dielectric coating. It is seen that the positions of the complex resonance frequencies move away from the real frequency axis under the influence of dielectric loss in the coating. The effect of this is shown to correspond to the changes in the backscatter spectrum versus real frequency as computed using a Mie series expansion. The significant difference between the lossless and lossy dielectric-coated sphere cases is seen to be due to a modification of the phase velocities of surface waves, particularly the whispering gallery types, and the increased attenuation of the surface wave modes     

Mathematical analysis of lead field expansions

The solution to the bioelectromagnetic inverse problem is discussed in terms of a generalized lead field expansion, extended to weights depending polynomially on the current strength. The expansion coefficients are obtained from the resulting system of equations which relate the lead field expansion to the data. The framework supports a family of algorithms which include the class of minimum norm solutions and those of weighted minimum norm, including FOCUSS (suitably modified to conform to requirements of rotational invariance). The weighted-minimum-norm family is discussed in some detail, making explicit the dependence (or independence) of the weighting scheme on the modulus of the unknown current density vector. For all but the linear case, and with a single power in the weight, a highly nonlinear system of equations results. These are analyzed and their solution reduced to tractable problems for a finite number of degrees of freedom. In the simplest magnetic field tomography (MFT) case, this is shown to possess expected properties for localized distributed sources. A sensitivity analysis supports this conclusion.     

Asymptotic performance of single parity-check product codes

This article investigates the asymptotic performance of single parity-check (SPC) product codes (PCs) from a decoding point of view. Specifically, the probability of bit error is bounded before and after the decoding of each dimension, similar to the analysis of "iterated codes" by Elias (1954). It is shown that the asymptotic probability of bit error can be driven to zero as the number of dimensions, and hence the block length, increases at signal-to-noise ratios (SNRs) within 2 dB of capacity over the additive white Gaussian noise (AWGN) channel.