Photocatalytic effect of carbon-modified n-TiO2 nanoparticles under visible light illumination

The present research focused on wet process synthesis of visible light active carbon-modified (CM)-n-TiO₂ nanoparticles and their photocatalytic activity. The CM-n-TiO₂ was synthesized by hydrolysis of TiCl₄ in the presence of tetrabutylammonium hydroxide and also in the presence of glucose and sodium hydroxide. UV–vis spectra, X-ray diffraction (XRD), and FT-IR were used to characterize these photocatalysts. It was found that the CM-n-TiO₂ nanoparticles synthesized by hydrolysis with tetrabutylammonium hydroxide or with sodium hydroxide and glucose when subjected to extended aging and subsequent calcinations absorb well into the visible to near infrared region up to 800 nm and exhibit enhanced visible light photocatalytic activity on degradation of 4-chlorophenol. CM-n-TiO₂ synthesized using glucose as the carbon source generated 13-fold increase in the initial rate of photodegradation of 4-chlorophenol compared to those by regular n-TiO₂, whereas, it increased only eight-fold when tetrabutylammonium hydroxide was used as the carbon source.     

Load combination analysis by ‘Directional simulation in the load space’

The reliability of structures subjected to multiple time-varying random loads is considered herein. It is well-known that the reliability of such systems may be evaluated by considering outcrossings of the load process vector out of a safe domain, and the contribution of individual loads to structural failure may be evaluated by considering outcrossings caused by combinations of one or more loads. In this paper the ‘Directional Simulation in the Load Space’ approach to reliability analysis is developed to consider explicitly outcrossings caused by all possible combinations of loads, during analysis of systems comprising stationary continuous Gaussian loads. To do this, the direction of the load process vector is ‘fixed’ at each point of outcrossing (to physically represent the particular combination of loads causing the outcrossing), and, by considering each possible load combination, all loads not causing an outcrossing are then held constant during radial integration (to model correctly that they do not contribute to each outcrossing). A numerical example demonstrating the validity of the proposed formulation is presented.     

A logical approach to multilevel security of probabilistic systems

Summary. We set out a modal logic for reasoning about multilevel security of probabilistic systems. This logic contains expressions for time, probability, and knowledge. Making use of the Halpern-Tuttle framework for reasoning about knowledge and probability, we give a semantics for our logic and prove it is sound. We give two syntactic definitions of perfect multilevel security and show that their semantic interpretations are equivalent to earlier, independently motivated characterizations. We also discuss the relation between these characterizations of security and between their usefulness in security analysis.     

New Thinking About the Enterprise

Geographic Information Systems in Business, James B. Pick, Editor; Hershey, PA: Idea Group Publishing (2005).

Sharing Expertise: Beyond Knowledge Management, Mark Ackerman, Volkmar Pipek, and Volker Wulf, Editors; Cambridge, MA: MIT Press (2003).

Innovations in Knowledge Management, Bonnie Montano, Editor; Hershey, PA: IRM Press (2005).

Business Intelligence for the Enterprise, by Mike Biere; Upper Saddle River, NJ: Prentice Hall, (2003).     

The effect of inaccurate volume calibrations on hydrogen uptake measured by the Sieverts method

The Sieverts technique is a popular method of measuring the uptake of gas on a sample and is an important tool for the characterisation of hydrogen uptake by potential hydrogen storage materials. An analysis of the consequences of errors in the calibration of volumes in this technique has been made using hydrogen absorption on an AB₂ alloy as an example. Trends in the error in the uptake as a function of errors in the volumes have been explained in terms of the equations for uptake. Significant advantages are found for calibration techniques for which the ratio of volumes is an intrinsic measurement.     

Cooking rice in excess water reduces both arsenic and enriched vitamins in the cooked grain

This paper reports the effects of rinsing rice and cooking it in variable amounts of water on total arsenic, inorganic arsenic, iron, cadmium, manganese, folate, thiamin and niacin in the cooked grain. We prepared multiple rice varietals both rinsed and unrinsed and with varying amounts of cooking water. Rinsing rice before cooking has a minimal effect on the arsenic (As) content of the cooked grain, but washes enriched iron, folate, thiamin and niacin from polished and parboiled rice. Cooking rice in excess water efficiently reduces the amount of As in the cooked grain. Excess water cooking reduces average inorganic As by 40% from long grain polished, 60% from parboiled and 50% from brown rice. Iron, folate, niacin and thiamin are reduced by 50–70% for enriched polished and parboiled rice, but significantly less so for brown rice, which is not enriched.     

Influence of texture and test velocity on the dynamic,high-strain,tensile behavior of zirconium

Experiments were conducted to characterize the influence of texture and impact velocity on the dynamic, high-strain, tensile extrusion of zirconium. Bullet-shaped samples were machined from a clock-rolled, highly textured Zr plate. Specimens in two orthogonal directions were tested: the extrusion direction aligned with either the in-plane (IP) rolling or the through-thickness (TT) direction of the plate. The post-extrusion microstructure and texture evolution were examined using electron backscatter diffraction microscopy and modeled using the viscoplastic self-consistent model. It was found that extrusion deformation was accomplished through a combination of twinning and slip with their relative activity greatly depending on the initial texture. In this regard, higher elongations in the IP samples as compared to the TT samples were observed at similar test velocities. This difference in ductility is discussed in terms of the material’s ability to accommodate plastic deformation. Due to the availability of a larger number of slip systems with relatively high Schmid factors in the IP samples under this configuration, plastic deformation by prismatic slip can be easily achieved, resulting in larger elongations. On the contrary, for TT samples, twinning preceded deformation by slip. This sequential deformation process, driven by the need to reorient the microstructure favorably to slip, led to diminished elongations to failure.