根本技术创新产品需求的获取及评价研究

根本技术创新对企业的发展具有决定性的意义。并对工程作为现代产品开发中新发展的系统化方法，在应用其对根本技术创新产品需求搜集及评价时，出现了满足顾客需求和创造顾客需求、资源需求与技术创新、理性决策与非理性决策、企业文化与技术创新等之间的矛盾。本文对产生这些矛盾的原因进行了分析，提出了相应的解决办法。     

对绿色技术内涵与类别的再思考

在分析不同国际组织、机构对环境友好技术概念的不同界定方法及其特点的基础上,以系统性、层次性和可操作性为原则,以环境亲和程度为标准,从基础绿色技术、创新绿色技术和生态绿色技术三个层次对绿色技术的涵义和类别进行了界定。     

采动覆岩中关键层运动对围岩支承压力分布的影响

运用数值模拟方法,主要分析了关键层的破断、关键层相对位置及采深等对围岩支承压力的影响;同时,研究了采空区支承压力的分布规律.研究结果对采场围岩的控制提供了一定的理论依据.     

聚苯乙烯溴代并接技聚二甲基硅氧烷

聚苯乙烯（PS）在苯溶液中与溴代丁二酰亚胺（NBS）反应，经分离提纯得到了固体溴代聚苯乙烯（PSB）。将所得PSB溶于苯并与低分子量的聚二甲基硅氧烷硅醇锂（PDMSOLi）反应，经分离提纯得到固体的溴代聚苯乙烯接枝聚二甲基硅氧烷（PSB－g-PDMSO),所得PSB-g-PDMSO的结构经^1H-NMR、IR及TEM表征。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

高压乙烯压缩机出入口管线振动分析及改造

为减轻高压乙烯压缩机出入口管线的振动,采用有限元建模方法,对管线结构固有频率及各阶振型进行分析计算,详细讨论了在管线同一位置加不同约束和在不同位置加同一约束的情况对管线振动的影响.最后,结合测试数据和现场实际情况提出了改造方案.实际使用结果证明改造措施有效,达到了预期的防振效果.     

不同粒度松散煤体的氧扩散特性实验研究

以自行研制的煤对氧扩散特性测试装置为实验手段,在常温环境条件下测试了不同粒度松散煤体对氧的自由扩散特性.实验结果表明:煤样粒度的变化对取气腔氧浓度流出曲线的影响表现出2个极限值,煤样粒度在20～100目之间时,取气腔氧气浓度梯度随煤样粒度的增大而增大;当煤样粒度<20目或>100目时,煤样粒度的再变化对氧浓度流出曲线的影响则微乎其微;取气腔氧浓度曲线流形基本符合指数曲线的变化规律.     

Microstructure and fatigue characteristics of direct chill cast and electromagnetic cast 2024 Al alloy ingots

The distinct advantages of the electromagnetic casting (EMC) process consist in the presence of stirring motions in the melt, which lead to significant grain size reduction in solidified ingot. Furthermore, surface and subsurface qualities are improved due to the absence of ingot mold. However, it is impossible to achieve the aforementioned advantages in conventional direct chill casting (DCC). In order to contrast the before and after heat treatments of the microstructural and mechanical characteristics of EMC and DCC 2024 aluminium alloys, optical microscopy, scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffractions (XRD), differential scanning calorimetry (DSC), etc. were carried out. Compared with the DCC ingot, the EMC ingot has better mechanical properties not only in the ascast condition but also in the as-aged condition. The DSC curves show that the EMC specimens have high enthalpy, i.e., the thermal kinetic energy to form precipitates during the aging treatment process. Despite heat treatments applied to the DCC ingot, it fails to attain the same mechanical properties as the EMC ingot. Moreover, considering the expernsive scalping operation for DCC ingots, the EMC technique, which offers a lower manufacturing cost, is one of the best manufacturing methods used in obtaining the ingots of wrought aluminum alloys.     

钕电解阳极过电位的测定

用慢扫描示波法测定了钕电解的阳极过电位 .考察了温度、阳极电流密度、Nd2 O3添加量、电解质组成等因素对阳极过电位的影响 ,探讨了降低阳极过电位的可能途径 .结果表明 ,阳极过电位随阳极电流密度的增加而增大 ,随温度的升高而减小 ,一定范围内 ,阳极过电位与阳极电流密度的对数呈线性关系 ,满足塔菲尔方程 ;电解质中LiF和Nd2 O3浓度增加 ,阳极过电位降低 ;适当控制阳极电流密度、升高温度、增加电解质中LiF和Nd2 O3的浓度并尽可能减小极间距 ,均有利于降低阳极过电位     

溶胶-凝胶生物玻璃多孔材料显微结构和生物活性的扫描电镜及红外光谱分析

本文利用溶胶．凝胶法制备了CaO-P2O5-SiO，系统生物活性玻璃，并以其为原料制备了用于骨修复及骨组织工程支架的块状生物活性材料。利用体外实验方法(invitro)结合x射线衍射(XRD)、扫描电子显微镜(SEM)和傅立叶变换红外光谱分析(FTIR)技术对不同烧结工艺制备的材料结构、晶相和生物活性的影响进行了分析研究。研究表明，经800℃和1100℃烧结5min的两种材料均有硅磷酸钙Ca5(PO4)2SjO4微晶相析出。烧结温度越高，析出微晶相的体积比例越大，材料的生物活性则越低。在模拟生理溶液中碳酸羟基磷灰石(HCA)只在烧结体中的玻璃颗粒表面形成，而在其硅磷酸钙Ca5(PO4)2SiO4微晶相表面未发现HCA形成。