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101.
Benjamín Escamilla‐Castillo Ren Varela‐Montellano Salvador A. Snchez‐Tovar Julio Alberto Solís‐Fuentes Carmen Durn‐de‐Bazúa 《European Journal of Lipid Science and Technology》2005,107(12):871-876
Rice bran is considered in Mexico as “waste”, useful only for feeds. As considerable amounts of oil are available in rice bran, it might be worthwhile to stabilize it and extract the edible oil before using it for feedstuffs. Precisely these oils are responsible for rice bran rapid deterioration, particularly in climatic conditions such as those prevalent in Mexico's tropical areas (high humidity and high temperature). This paper deals with the study of the effect of pH during extrusion of fresh rice bran in order to inactivate lipid‐breaking enzymes. Hydrochloric acid or calcium hydroxide, Ca(OH)2, were added at 0, 1, 5, 10% (dry basis), and moisture content of the bran samples was varied (20, 30, 40%, dry basis) in a 32 factorial design to corroborate its effect at acid and alkaline pH range. Free fatty acids (FFA) increase was the control variable. Extruded samples were stored at room temperature (between 20 and 28 °C) using a non‐extruded sample as control to assess the shelf life effects. Results indicate that in acid‐extruded samples, the increase in FFA concentration after 98 days was much less than in the unmodified‐pH or alkaline samples. The lowest FFA increase after 3 months of storage time was <10 mg FFA/g rice bran using extrusion with no water or chemicals added or using extrusion adding HCl, irrespective of the moisture content of rice bran. 相似文献
102.
Pilar Manglano María Jesús Lagarda María Dolores Silvestre Carmen Vidal Gonzalo Clemente Rosaura Farr 《European Journal of Lipid Science and Technology》2005,107(11):815-823
A study is made of the effects of storage (time and temperature) on the lipid fraction of four milk‐based adapted infant formulas with basically the same composition, though differing in the iron salt added (lactate or sulfate) and/or the vitamin E source (α‐tocopherol or α‐tocopherol acetate). Peroxide value, hydroperoxide C18 percentage and thiobarbituric acid‐reactive substance (TBARS) content were used as indicators of lipid peroxidation. Fat contents remained stable throughout storage. Peroxide values increased from the first storage month and were affected by storage time, although they exhibited irregular behavior. Storage time and temperature affected hydroperoxide percentage, which was seen to be the earliest indicator of lipid oxidation, being measurable in newly manufactured formulas. TBARS values were only affected by storage time. No statistically significant differences were found among the four infant formulas for any of the lipid oxidation indicators. 相似文献
103.
Amaia Bastero Aurora Ruiz Carmen Claver Antonio Bella Barbara Milani Beln Moreno‐Lara FlixA. Jaln BlancaR. Manzano 《Advanced Synthesis \u0026amp; Catalysis》2005,347(6):839-846
The CO/tert‐butylstyrene/ethylene terpolymerization catalyzed by Pd‐(N‐N′) complexes was studied. The results evidence that the olefin preferentially inserted in the terpolymer chain is strictly related to the nature of the nitrogen ligand, mainly to its steric constraints, and not to the kind of ligand. Indeed, slight variations in the backbone of the nitrogen ligands coordinated to palladium allow for the synthesis of terpolymers with a controlled composition. 相似文献
104.
Maria Lucia Iacovino Chiara Carmen Miceli Marco De Felice Biagio Barone Luca Pompella Francesco Chiancone Erika Di Zazzo Giuseppe Tirino Carminia Maria Della Corte Ciro Imbimbo Ferdinando De Vita Felice Crocetto 《International journal of molecular sciences》2022,23(3)
Muscle invasive bladder cancer (MIBC) is a widespread malignancy with a worse prognosis often related to a late diagnosis. For early-stage MIBC pts, a multidisciplinary approach is mandatory to evaluate the timing of neoadjuvant chemotherapy (NAC) and surgery. The current standard therapy is platinum-based NAC (MVAC-methotrexate, vinblastine, doxorubicin, and cisplatin or Platinum–Gemcitabine regimens) followed by radical cystectomy (RC) with lymphadenectomy. However, preliminary data from Vesper trial highlighted that dose-dense NAC MVAC is endowed with a good pathological response but shows low tolerability. In the last few years, translational-based research approaches have identified several candidate biomarkers of NAC esponsiveness, such as ERCC2, ERBB2, or DNA damage response (DDR) gene alterations. Moreover, the recent consensus MIBC molecular classification identified six molecular subtypes, characterized by different sensitivity to chemo- or targeted or immunotherapy, that could open a novel procedure for patient selection and also for neoadjuvant therapies. The Italian PURE-01 phase II Trial extended data on efficacy and resistance to Immune Checkpoint Inhibitors (ICIs) in this setting. In this review, we summarize the most relevant literature data supporting NAC use in MIBC, focusing on novel therapeutic strategies such as immunotherapy, considering the better patient stratification and selection emerging from novel molecular classification. 相似文献
105.
Marco Maspero Prof. Clelia Dallanoce Prof. Dr. Björn Wängler Prof. Dr. Carmen Wängler Dr. Ralph Hübner 《ChemMedChem》2022,17(8):e202100739
In the present study we describe and explain an aberrant behavior in terms of receptor binding profile of a fluorescein-based multimodal imaging agent for gastrin releasing peptide receptor (GRPR) visualization by elucidating a chelating mechanism on sodium ions of its fluorescent dye moiety. This hypothesis is supported by both biological results and spectroscopic analyses of different fluorescein-carrying conjugates and an equally charged set of analogous tartrazine-based GRPR-binding imaging agents. Fluorescein interacts with sodium which reduces the overall negative charge of the dye molecule by one. This reduction in apparent total net charge explains the exceptional behavior found for the fluorescein-based multimodal bioconjugate in the context of the charge-cell binding correlation hypothesis. 相似文献
106.
Sigal Meirovitch Zvi Shtein Tal Ben-Shalom Shaul Lapidot Carmen Tamburu Xiao Hu Jonathan A. Kluge Uri Raviv David L. Kaplan Oded Shoseyov 《International journal of molecular sciences》2016,17(9)
The fabrication of cellulose-spider silk bio-nanocomposites comprised of cellulose nanocrystals (CNCs) and recombinant spider silk protein fused to a cellulose binding domain (CBD) is described. Silk-CBD successfully binds cellulose, and unlike recombinant silk alone, silk-CBD self-assembles into microfibrils even in the absence of CNCs. Silk-CBD-CNC composite sponges and films show changes in internal structure and CNC alignment related to the addition of silk-CBD. The silk-CBD sponges exhibit improved thermal and structural characteristics in comparison to control recombinant spider silk sponges. The glass transition temperature (Tg) of the silk-CBD sponge was higher than the control silk sponge and similar to native dragline spider silk fibers. Gel filtration analysis, dynamic light scattering (DLS), small angle X-ray scattering (SAXS) and cryo-transmission electron microscopy (TEM) indicated that silk-CBD, but not the recombinant silk control, formed a nematic liquid crystalline phase similar to that observed in native spider silk during the silk spinning process. Silk-CBD microfibrils spontaneously formed in solution upon ultrasonication. We suggest a model for silk-CBD assembly that implicates CBD in the central role of driving the dimerization of spider silk monomers, a process essential to the molecular assembly of spider-silk nanofibers and silk-CNC composites. 相似文献
107.
Franco Fernndez Generosa Gmez Carmen Lpez Ana Santos 《Advanced Synthesis \u0026amp; Catalysis》1989,331(1):15-21
Friedel-Crafts acetylation of phenanthrene ( 1a ) in sym-tetrachloroethane yields mixtures of 2-, 3- and 9-acetylphenanthrenes ( 2a, 3a, 4 ). The distribution of isomers is found to depend strongly upon the method of mixing the reagents. Acetylation of 9-chlorophenanthrene ( 1b ), performed by a variety of methods and solvents, led mainly to 3-acetyl-9-chlorophenanthrene ( 3b ) (≥85%). Previously unreported 2-acetyl-9-chlorophenanthrene ( 2b ) was found to form up to a maximum 11% in nitrobenzene. 相似文献
108.
Fitó M Covas MI Lamuela-Raventós RM Vila J Torrents L de la Torre C Marrugat J 《Lipids》2000,35(6):633-638
The protective effect of phenolic compounds from an olive oil extract, and of olive oils with (extra-virgin) and without (refined)
phenolic components, on low density lipoprotein (LDL) oxidation was investigated. When added to isolated LDL, phenolics [0.025–0.3
mg/L caffeic acid equivalents (CAE)] increased the lag time of conjugated diene formation after copper-mediated LDL oxidation
in a concentration-dependent manner. Concentrations of phenolics greater than 20 mg/L inhibited formation of thiobarbituric-acid
reactive substances after AAPH-initiated LDL oxidation. LDL isolated from plasma after preincubation with phenolics (25–160
mg/L CAE) showed a concentration-dependent increase in the lag time of conjugated diene formation after copper-mediated LDL
oxidation. Refined olive oil (0 mg/L CAE) and extra-virgin olive oil (0.1 and 0.3 mg/L CAE) added to isolated LDL caused an
increase in the lag time of conjugated diene formation after copper-mediated LDL oxidation that was related to olive oil phenolic
content. Multiple regression analysis showed that phenolics were significantly associated with the increase in lag time after
adjustment for effects of other antioxidants; α-tocopherol also achieved a statistically significant effect. These results
indicate that olive oil phenolic compounds protect LDL against peroxyl radical-dependent and metal-induced oxidation in vitro and could associate with LDL after their incubation with plasma. Both types of olive oil protect LDL from oxidation. Olive
oil containing phenolics, however, shows more antioxidant effect on LDL oxidation than refined olive oil. 相似文献
109.
Pedro J. Sánchez-Soto María del Carmen Jiménez de Haro Luis A. Pérez-Maqueda Ignacio Varona José L. Pérez-Rodríguez 《Journal of the American Ceramic Society》2000,83(7):1649-1657
The present study examined the effects of dry grinding, using ball-milling, on the structure of reference well-crystallized (KGa-1) and poorly crystallized (KGa-2) kaolinite powders from Georgia. Grinding produced a strong structural alteration, mainly along the c axis, resulting in disorder and total degradation of the crystal structure of the kaolinite and the formation of an amorphous product. The surface area increased with grinding time, mainly in KGa-2 (maximum value 50.27 m2 /g), a result associated with particle-size reduction. These particles became more agglomerated with grinding, and the surface area decreased after 30 min, as confirmed by scanning electron microscopy and particle-size-distribution analysis. There was a limit to particle-size reduction with grinding time. When grinding time was increased, the original endothermic differential thermal analysis (DTA) effects of dehydroxylation in both samples shifted to lower temperatures, decreased in intensity, then disappeared completely after 120 min of grinding. The temperature of the characteristic first exothermic effect shifted slightly to lower temperatures with grinding, although the DTA effects did not increase with grinding time in either kaolinite sample, at least up to 325 min. The amorphous, mechanically activated kaolinite converted into low-crystalline mullite nuclei at a lower temperature than did the unground samples, as deduced by thermal and X-ray observations. This effect was especially important for the KGa-2 sample. Grinding did not seem to influence the formation of silicon-aluminum spinel from kaolinite. The present results may explain why ground kaolinite samples prepared via different routes—e.g., with differences in grinding—behave differently during high-temperature transformations, as reported in the related literature. 相似文献
110.
Beatriz de Rivas Rubn Lpez-Fonseca Carmen Sampedro Jos I. Gutirrez-Ortiz 《Applied catalysis. B, Environmental》2009,90(3-4):545-555
In the present paper the thermal deactivation of a series of Ce/Zr mixed oxides (CeO2, Ce0.8Zr0.2O2, Ce0.68Zr0.32O2, Ce0.5Zr0.5O2, Ce0.15Zr0.85O2 and ZrO2) was investigated. In order to simulate long-term operation, samples were calcined at three different temperatures, namely 550, 750 and 1000 °C in air for 4 h. Structural, morphological and physico-chemical changes caused by high-temperature treatment were analysed by X-ray diffraction, BET measurements, NH3-temperature-programmed desorption and temperature-programmed reduction with hydrogen, and the behaviour in the oxidation of chlorinated volatile organic compounds (1,2-dichloroethane and trichloroethylene). The catalytic properties of Ce/Zr mixed oxides could be accounted for on the basis of their promoted redox, as characterised by the percentage of oxygen vacancies, and acidic properties due to the incorporation of zirconium in the ceria lattice. An increase in the calcination temperature led to a progressive decrease in the catalytic activity as a result of the modifications provoked by induced thermal aging (decrease in surface area, larger crystal sizes, reducibility at higher temperatures and loss of acid sites). Ce0.15Zr0.85O2 and Ce0.5Zr0.5O2 showed the best resistance to deactivation with combustion temperatures still notably lower in comparison with the homogeneous reaction even after calcination at 1000 °C. Also slight changes in selectivity were evident resulting in favoured yields of hydrogen chloride, which was environmentally beneficial, and incomplete combustion products such as carbon monoxide and chlorinated intermediates. 相似文献