Taylor’s Slope Stability Charts Revisited

Two design charts for computing the safety factor of soil slopes are presented here. The first one is for an undrained (?u = 0) soil slope, similar to the one proposed by Taylor, but with significant differences. Taylor’s work is based on three types of failure circles: toe circle, slope circle, and midpoint circle. It appears that there can also be compound circles that are made of two circular arcs separated by a straight line at the interface with the stiff stratum. These are incorporated in the proposed design chart. The second chart is for drained (c′-?′) soil slope that enables the users to compute the safety factor of the slope without any iterative procedures that are required with the Taylor’s chart. In c′-?′ soils, Taylor assumed that the failure occurs along toe circles. The analysis presented herein shows that when the slope is very shallow, it is possible to have midpoint circles. Both charts are quite simple and straightforward to use in engineering analysis of homogeneous slopes. Numerical examples are presented to illustrate the use of the two design charts.     

Localized in situ polymerization on graphene surfaces for stabilized graphene dispersions

We demonstrate a novel in situ polymerization technique to develop localized polymer coatings on the surface of dispersed pristine graphene sheets. Graphene sheets show great promise as strong, conductive fillers in polymer nanocomposites; however, difficulties in dispersion quality and interfacial strength between filler and matrix have been a persistent problem for graphene-based nanocomposites, particularly for pristine graphene. With this in mind, a physisorbed polymer layer is used to stabilize graphene sheets in solution. To create this protective layer, we formed an organic microenvironment around dispersed graphene sheets in surfactant solutions, and created a nylon 6, 10 or nylon 6, 6 coating via interfacial polymerization. Technique lies at the intersection of emulsion and admicellar polymerization; a similar technique was originally developed to protect luminescent properties of carbon nanotubes in solution. These coated graphene dispersions are aggregation-resistant and may be reversibly redispersed in water even after freeze-drying. The coated graphene holds promise for a number of applications, including multifunctional graphene-polymer nanocomposites.     

Fabrication and characterization of vertically aligned long ZnO nanorods on transparent substrate

Vertically aligned long ZnO nanorods (NRs) were grown by metal organic chemical vapor deposition (MOCVD) technique. Prior to the NRs growth Ga-doped ZnO (GZO) film was deposited by DC sputtering technique on glass substrates. The length and width of the NRs were 25 microm and 450-500 nm, respectively. Structural and optical properties of the NRs were investigated after the growth. The NRs were single crystalline in nature with the preferred growth along c-axis. The diffusion of Ga atoms in the bottom of the NRs during the growth is detected. A prominent near band edge emission of NRs was observed from room-temperature photoluminescence study. Electrical characteristics across the NRs-thin film hybrid structure were measured with UV exposure, where the rise and fall of the photocurrent was exponential in nature due to the desorption and adsorption of oxygen in the surface.     

Electrical conductivity measurements of nanofluids and development of new correlations

In this study the electrical conductivity of aluminum oxide (Al2O3), silicon dioxide (SiO2) and zinc oxide (ZnO) nanoparticles dispersed in propylene glycol and water mixture were measured in the temperature range of 0 degrees C to 90 degrees C. The volumetric concentration of nanoparticles in these fluids ranged from 0 to 10% for different nanofluids. The particle sizes considered were from 20 nm to 70 nm. The electrical conductivity measuring apparatus and the measurement procedure were validated by measuring the electrical conductivity of a calibration fluid, whose properties are known accurately. The measured electrical conductivity values agreed within +/- 1% with the published data reported by the manufacturer. Following the validation, the electrical conductivities of different nanofluids were measured. The measurements showed that electrical conductivity of nanofluids increased with an increase in temperature and also with an increase in particle volumetric concentration. For the same nanofluid at a fixed volumetric concentration, the electrical conductivity was found to be higher for smaller particle sizes. From the experimental data, empirical models were developed for three nanofluids to express the electrical conductivity as functions of temperature, volumetric concentration and the size of the nanoparticles.     

Electrical characterization and reliability study of integrated GaN power amplifier in multi-layer thin-film technology

In this work, the degradation of a GaN power amplifier (PA) integrated in a thin film multi-chip module (MCM-D) interconnect technology is investigated by means of DC and RF measurements. Failure analysis has demonstrated that improper thermal contact may cause the PA module performance degradation. Moreover, we have experimentally studied the thermal effects on the RF performance of MCM-D and low-temperature co-fired ceramic (LTCC) PAs. It shows that the device exhibits a higher output power density on a thinned MCM-D substrate than on an LTCC substrate with thermal vias, and also that the output power density can be further improved by reducing the heat spread distance between active devices and heat sink.     

A study on the adsorption mechanism of mercury on Aspergillus versicolor biomass

The adsorption behavior of mercury on Aspergillus versicolor biomass (AVB) has been investigated in aqueous solution to understand the physicochemical process involved and to explore the potentiality of AVB in pollution control management. This biomass has been successfully used for reducing the mercury concentration level in the effluent of chloralkali and battery industries to a permissible limit. The results establish that 75.6 mg of mercury is adsorbed per gram of biomass. The adsorption process is found to be a function of pH of the solution, with the optimum range being pH 5.0-6.0. The process obeys the Langmuir-Freundlich isotherm model. Scanning electron microscopic analysis demonstrates a conspicuous surface morphology change of the mercury-adsorbed biomass. A nearly uniform distribution of metal ions on the mycelial surface excepting a few aggregation points is revealed by X-ray elemental mapping profiles. The results of zeta potential measurement, Fourier transform infrared (FTIR) spectroscopy, and blocking of the functional groups by chemical modification reflect the binding of mercury on the biomass occurs through electrostatic and complexation reactions. The accumulation of mercury on the cell wall associated with negligible diffusion and or transportation into cytoplasm finds support from the results of adsorption kinetics and transmission electron micrographs. Mercury adsorption on biomass also leads to elongation of cells and cytoplasmic aggregation of spheroplast/protoplasts, indicating that the cell wall acts as a permeation barrier against this toxic metal.     

Simulation of core annular in return bends—A comprehensive CFD study

The present work reports a computational fluid dynamic analysis of core annular flow through return bends. Core annular flow of lubricating oil and water has been simulated using FLUENT 6.3.26. A satisfactory trend matching is observed between numerically obtained phase distribution and experiments. A comprehensive study has been made to generate the profiles of velocity, pressure, and volume fraction over a wide range of oil and water velocities. It has been observed that the oil core may foul the bend wall under certain operating conditions. Through computational simulations the operating zone safe from the risk of fouling has also been identified.     

Click chemistry for rapid labeling and ligation of RNA

The copper(I)-promoted azide-alkyne cycloaddition reaction (click chemistry) is shown to be compatible with RNA (with free 2'-hydroxyl groups) in spite of the intrinsic lability of RNA. RNA degradation is minimized through stabilization of the Cu(I) in aqueous buffer with acetonitrile as cosolvent and no other ligand; this suggests the general possibility of "ligandless" click chemistry. With the viability of click chemistry validated on synthetic RNA bearing "click"-reactive alkynes, the scope of the reaction is extended to in-vitro-transcribed or, indeed, any RNA, as a click-reactive azide is incorporated enzymatically. Once clickable groups are installed on RNA, they can be rapidly click labeled or conjugated together in click ligations, which may be either templated or nontemplated. In click ligations the resultant unnatural triazole-linked RNA backbone is not detrimental to RNA function, thus suggesting a broad applicability of click chemistry in RNA biological studies.     

Photoelectrochemical and photocatalytic activity of tungsten doped TiO2 nanotube layers in the near visible region

In the present work we study the effect of WO₃ doping on the photo-electrochemical behavior of self-organized TiO₂ nanotube layers. Mixed oxide nanotubes were grown by anodization of Ti–W alloys containing 0.2 and 9% W, with a thicknesses of the oxide nanotube layers adjusted to about 1.1–1.2 μm. We show that by WO₃ doping, the near visible photoresponse and photocatalytic performance can drastically be enhanced. While a content of 9 at% WO₃ in photoresponse experiments is most beneficial, in long term experiments a higher efficiency is observed for the 0.2 at% W content. This is due to a gradual leaching of WO₃ (dissolution into the electrolyte) for the higher WO₃ content. This demonstrates that under optimized WO₃ doping conditions a lasting visible light activation of TiO₂ nanotubes can be achieved.     

Folate receptor targeted, carboxymethyl chitosan functionalized iron oxide nanoparticles: a novel ultradispersed nanoconjugates for bimodal imaging

This article delineates the design and synthesis of a novel, bio-functionalized, magneto-fluorescent multifunctional nanoparticles suitable for cancer-specific targeting, detection and imaging. Biocompatible, hydrophilic, magneto-fluorescent nanoparticles with surface-pendant amine, carboxyl and aldehyde groups were designed using o-carboxymethyl chitosan (OCMC). The free amine groups of OCMC stabilized magnetite nanoparticles on the surface allow for the covalent attachment of a fluorescent dye such as rhodamine isothiocyanate (RITC) with the aim to develop a magneto-fluorescent nanoprobe for optical imaging. In order to impart specific cancer cell targeting properties, folic acid and its aminated derivative was conjugated onto these magneto-fluorescent nanoparticles using different pendant groups (-NH(2), -COOH, -CHO). These newly synthesized iron-oxide folate nanoconjugates (FA-RITC-OCMC-SPIONs) showed excellent dispersibility, biocompatibility and good hydrodynamic sizes under physiological conditions which were extensively studied by a variety of complementary techniques. The cellular internalization efficacy of these folate-targeted and its non-targeted counterparts were studied using a folate-overexpressed (HeLa) and a normal (L929 fibroblast) cells by fluorescence microscopy and magnetically activated cell sorting (MACS). Cell-uptake behaviors of nanoparticles clearly demonstrate that cancer cells over-expressing the human folate receptor internalized a higher level of these nanoparticle-folate conjugates than normal cells. These folate targeted nanoparticles possess specific magnetic properties in the presence of an external magnetic field and the potential of these nanoconjugates as T(2)-weighted negative contrast MR imaging agent were evaluated in folate-overexpressed HeLa and normal L929 fibroblast cells.