Critical Ratios for structural analysis of triacylglycerols using mass spectrometry

Recent developments have finally allowed fragment behaviors using APCI‐MS to be elucidated after twenty years of literature reports. Critical Ratios have been defined that correspond to various aspects of triacylglycerol (TAG) analysis, from overall degree of unsaturation to localization of fatty acids on the glycerol backbone (regioisomers), to grouping of unsaturated fatty acids. The same ratios also constitute a compact library of TAG mass spectra.     

Decision rules for determining terrestrial movement and the consequences for filtering high-resolution global positioning system tracks: a case study using the African lion (Panthera leo)

The combined use of global positioning system (GPS) technology and motion sensors within the discipline of movement ecology has increased over recent years. This is particularly the case for instrumented wildlife, with many studies now opting to record parameters at high (infra-second) sampling frequencies. However, the detail with which GPS loggers can elucidate fine-scale movement depends on the precision and accuracy of fixes, with accuracy being affected by signal reception. We hypothesized that animal behaviour was the main factor affecting fix inaccuracy, with inherent GPS positional noise (jitter) being most apparent during GPS fixes for non-moving locations, thereby producing disproportionate error during rest periods. A movement-verified filtering (MVF) protocol was constructed to compare GPS-derived speed data with dynamic body acceleration, to provide a computationally quick method for identifying genuine travelling movement. This method was tested on 11 free-ranging lions (Panthera leo) fitted with collar-mounted GPS units and tri-axial motion sensors recording at 1 and 40 Hz, respectively. The findings support the hypothesis and show that distance moved estimates were, on average, overestimated by greater than 80% prior to GPS screening. We present the conceptual and mathematical protocols for screening fix inaccuracy within high-resolution GPS datasets and demonstrate the importance that MVF has for avoiding inaccurate and biased estimates of movement.     

Reflexive learning in adaptive management: A case study of environmental water management in the Murray Darling Basin,Australia

Adaptive management is a structured approach for people who must act despite uncertainty and complexity about what they are managing and the impacts of their actions. It is learning‐by‐doing through deliberate cycles of experimentation, review, and synthesis. However, understanding the processes of learning and how they relate to achieving resource management goals is in its infancy. Reflexive learning—a process of identifying and critically examining assumptions, values, and actions that frame knowledge—is critical to the effectiveness of adaptive management. It involves adaptive feedbacks between stakeholders as they examine assumptions, values, and actions. Adaptive management has been applied to environmental flows because it offers a system for making decisions about tradeoffs. In the Murray Darling Basin (MDB), Australia, adaptive management is applied as a cycle of plan, do, monitor, and learn, facilitated by short‐ and long‐term learning among stakeholders. An alternative conceptualization of adaptive management as an integration of single‐, double‐, and triple‐loop learning across multiple levels of governance is presented. This is applied to environmental flows in the MDB to map adaptive feedbacks of reflexive learning. At the lowest level of governance (Water Resource Planning Area), goals are assessed as Thresholds of Potential Concern related to flow‐ecology responses, which are reviewed every 3–6 years. At the second level of governance (Basin‐States), Water Management Targets are the key goals; reviewed and reframed every 6–10 years. The highest level of governance (the MDB) is concerned with policy targets, with review and reframing over 8–15 years. Feedbacks that generate reflexive learning are complex and require commitment to move through the modes of single‐, double‐, and triple‐loop learning. Effective adaptive management of environmental water requires practitioners to situate themselves within a matrix of information flow across modes of learning, levels of governance, and components of a social‐ecological system, where reflexive learning drives the achievement of management goals.     

Eco-driving: the role of feedback in reducing emissions from everyday driving behaviours

Eco-driving has been proposed as an approach to significantly reduce greenhouse gas emissions arising from personal automobile use. Eco-driving is the adoption of a measured driving style, minimising unnecessary breaking and aggressive acceleration. Eco-driving can be seen as a low cost and immediate approach to emission reduction as it involves the modification of drivers’ behaviours as opposed to the development and implementation of newer, more efficient technology. Despite the proposed benefits of eco-driving, numerous challenges are faced in order to encourage the adoption of these behaviours and maintain them long term. This narrative review presents the concept of eco-driving, with a focus on the long-term maintenance of these behaviours, including training programmes and feedback devices. It is clear within current literature that, despite the economic and environmental benefits of adopting eco-driving, drivers require feedback on their actions in order to promote long-term, behavioural, change.     

Amplified spontaneous emission effects in semiconductor laseramplifiers

The analysis presented provides a quantitative method for predicting semiconductor laser amplifier performance in the presence of ASE (amplified spontaneous emission). It indicates that in order to increase the fraction of pump power that contributes to the amplification of the input laser field relative to that spent in overcoming internal losses, an amplifier should operate at as high an excitation level as possible. This may mean operating an amplifier above its free-running oscillation threshold. A limitation to the maximum pump power is the increase in ASE. With too high an excitation, ASE dominates over the amplified input laser field, resulting in a quenching of the amplifier gain, efficiency and coherence. ASE effects may be mitigated by increasing the input laser intensity, decreasing the amplifier facet reflectivities, or, in some cases, tuning the master oscillator so that it is resonant with the amplifier. The analysis indicates that minimizing the facet reflectivity is the most effective way to circumvent ASE limitations to power scaling semiconductor laser amplifiers     

Dramatic changes in the temporal trends of polybrominated diphenyl ethers (PBDEs) in herring gull eggs from the Laurentian Great Lakes: 1982-2006

DecaBDE is a current-use, commercial formulation of an additive, polybrominated diphenyl ether (PBDE) flame retardant composed of > 97% 2,2',3,3',4,4',5,5',6,6'-decabromoDE (BDE-209). Of the 43 PBDE congeners monitored, we report on the temporal trends (1982-2006) of quantifiable PBDEs, and specifically BDE-209, in pooled samples of herring gull (Larus argentatus) eggs from seven colonies spanning the Laurentian Great Lakes. BDE-209 concentrations in 2006 egg pools ranged from 4.5 to 20 ng/g wet weight (ww) and constituted 0.6-4.5% of sigma39PBDE concentrations among colonies, whereas sigma(octa)BDE and sigma(nona)BDE concentrations constituted from 0.5 to 2.2% and 0.3 to 1.1%, respectively. From 1982 to 2006, the BDE-209 doubling times ranged from 2.1 to 3.0 years, whereas for sigma(octa)BDEs and sigma(nona)BDEs, the mean doubling times ranged from 3.0 to 11 years and 2.4 to 5.3 years, respectively. The source of the octa- and nona-BDE congeners, e.g., BDE-207 and BDE-197, are the result of BDE-209 debromination, and they are either formed metabolically in Great Lakes herring gulls and/or bioaccumulated from the diet and subsequently transferred to their eggs. In contrast to BDE-209 and the octa- and nona-BDEs, congeners derived mainly from PentaBDE and OctaBDE mixtures, e.g., BDE-47, -99, and -100, showed rapid increases up until 2000; however, there was no increasing trend post-2000. The data illustrates that PBDE concentrations and congener pattern trends in the Great Lakes herring gull eggs have dramatically changed between 1995 and 2006. Regardless of BDE-209 not fitting the pervasive criteria as a persistent and bioaccumulative substance, it is clearly of increasing concern in Great Lake herring gulls, and provides evidence that regulation of DecaBDE formulations is warranted.