NMR studies of a D2 single crystal in the ordered phase

We report the first experimental study of the NMR lineshape anisotropy in the orientationally ordered cubic phase of a D₂ single crystal. The para-D₂ concentration covered the range 0.72<X<0.82. The observed line shapes were obtained by means of Fourier transform techniques from the solid echoes recorded with a pulsed NMR spectrometer operating at 5.9 MHz. Theoretical line shapes and their second moments forp-D₂ (with angular momentumJ=1 and spinI=1) and foro-D₂ (withJ=0, I=2) were calculated as a function of the applied field direction from the theory by A. B. Harris. Good agreement was obtained for all directions, provided that, just as for solid H₂, a Gaussian function for the distribution of molecular axial alignment was assumed with an rms spreading angle of 6 deg forX=0.77. No change in the anisotropy of the second moment in the disordered phase was detected between the initial (hcp) crystal and after repeated thermal cyclings through the martensitic transition. This result implies no change in the orientation of the plane for the sliding nets during repeated passages through the transition. Furthermore, we report measurements of the longitudinal relaxation time for bothp-D₂ ando-H₂ versusT over the temperature range 0.5<T<3.5 K. The complex behavior reported previously for both H₂ and D₂ was confirmed. Measurements of the relaxation times as a function of the applied field direction in the ordered phase at 1.2 K showed no anisotropy within experimental error, and this result is discussed in the light of predictions by Hardy and Berlinsky. Finally, the polarization of theJ=0 molecules is studied as a function of the concentrationX of theJ=1 molecules and their state of orientational order over a wide range ofX andT in the ordered and disordered states. The results are compared with predictions of A. B. Harris and with previous data on polycrystalline samples.     

Thermal transport properties and size effects in very dilute superfluid mixtures of3He in4He

The effective thermal conductivity _eff has been measured for 1.6 K for mixtures with 10^–6–2. Both _eff and the derived impurity mass diffusion coefficient D_iso show an unexpected dependence on the height h of the fluid layer. A scaled representation of D_iso leads to a purely phenomenological model involving an effective length scale, proportional to X^–1 and temperature independent. The relations so obtained are consistent with the observations as well as with the observed transition curve Q_C(X) to non-linear behavior.     

多网融合方案在电力基建工程现场中应用研究

针对输变电工程陆续开展基建智慧工地,智慧物联系统平台建设已成为常态,目前建设思路主要是通过基于"大、云、物、移、智"开展新技术、新产品的应用,实现"人、机、料、法、环、测"等施工现场六要素的感知采集,以支撑智慧工地及基建信息化的业务开展.如何实现施工现场感知层数据、视频流数据以及业务数据三类数据的传输,并实现设备安装布设无线化、部署简易化,是重点思考和解决的方向,提出建设以5G(generation)专网为主,无线接入点(access point,AP)网络、远距离(long range,LoRa)通信网络为辅的多网融合方案,开展智慧工地网络层的建设,以支撑智慧工地物联网业务的开展,提供高质量、高体验的网络层支撑.     

高导热无溶剂绝缘漆的开发及性能研究

在环氧改性不饱和聚酯树脂中添加无机氧化物导热材料可提高绝缘漆的导热性能.研究了填料粒径、表面改性对绝缘漆沉降的影响,以及不同填料含量对绝缘漆导热系数、黏度的影响,在此研究基础上制备了高导热无溶剂绝缘漆并对其性能进行了表征.结果表明:对填料进行表面改性可以降低其沉降速度;当填料含量为40％时,绝缘漆的黏度为72 s,导热系数达到0.46 W/(m·K),40℃下静置6天无沉降,具有很好的实际应用价值.     

基于图形化编程语言LabVIEW的虚拟仪器开发

本文介绍了虚拟仪器的概念，组成特征和图形化编程语言LabVIEW，并用LabVIEW开发了位移测试和系统静态精度测试系统。     

中国化石能源生产的生命周期清单(Ⅰ)--能源消耗与直接排放

化石能源生产的生命周期清单不仅是开展化工产业及其产品生命周期分析的基础,也能阐明化石能源生产的基本环境行为.通过计算得到了2002年我国原煤、原油和天然气开采过程中直接相关的能源消耗和污染物排放,涉及到的污染物排放包括液态污染物、固体废弃物和CO2、SO2、NOx、CO、CH4、烟尘等气态排放物.     

飞行器电磁窗耐雨蚀复合涂层的制备

研制了电磁窗用耐雨蚀底漆和耐雨蚀面漆，介绍了该配套涂料体系的制备工艺，并列举了其性能指标。讨论了耐雨蚀面漆中聚酯树脂、多元醇和颜料对其性能的影响，施工工艺对耐雨蚀涂层与底涂层之间配套性能的影响。     

Oxidative flavour deterioration of fish oil enriched milk

The oxidative deterioration of milk emulsions supplemented with 1.5 wt‐% fish oil was investigated by sensory evaluation and by determining the peroxide value and volatile oxidation products after cold storage. Two types of milk emulsions were produced, one with a highly unsaturated tuna oil (38 wt‐% of n‐3 fatty acids) and one with cod liver oil (26 wt‐% of n‐3 fatty acids). The effect of added calcium disodium ethylenediaminetetraacetate (EDTA) on oxidation was also investigated. Emulsions based on cod liver oil with a slightly elevated peroxide value (1.5 meq/kg) oxidised significantly faster than the tuna oil emulsions, having a lower initial peroxide value (0.1 meq/kg). In the tuna oil emulsions the fishy off‐flavour could not be detected throughout the storage period. Addition of 5—50 ppm EDTA significantly reduced the development of volatile oxidation products in the cod liver oil emulsions, indicating that metal chelation with EDTA could inhibit the decomposition of lipid hydroperoxides in these emulsions. This study showed that an oxidatively stable milk emulsion containing highly polyunsaturated tuna fish oil could be prepared without significant fishy off‐flavour development upon storage, provided that the initial peroxide value was sufficiently low.     

硫代硫酸钠合成条件的优化

优化了亚硫酸钠与硫磺反应制备硫代硫酸钠的合成条件，最佳反应条件为：亚硫酸钠与硫磺质量比为7：2，亚硫酸钠与水质量比为1：1，溶液pH=10，反应时间30min，此时亚硫酸钠转化率为95．9％，产品纯度98．9％，收率94．5％。