LINKING RIVER MANAGEMENT TO SPECIES CONSERVATION USING DYNAMIC LANDSCAPE‐SCALE MODELS

Efforts to conserve stream and river biota could benefit from tools that allow managers to evaluate landscape‐scale changes in species distributions in response to water management decisions. We present a framework and methods for integrating hydrology, geographic context and metapopulation processes to simulate effects of changes in streamflow on fish occupancy dynamics across a landscape of interconnected stream segments. We illustrate this approach using a 482 km² catchment in the southeastern US supporting 50 or more stream fish species. A spatially distributed, deterministic and physically based hydrologic model is used to simulate daily streamflow for sub‐basins composing the catchment. We use geographic data to characterize stream segments with respect to channel size, confinement, position and connectedness within the stream network. Simulated streamflow dynamics are then applied to model fish metapopulation dynamics in stream segments, using hypothesized effects of streamflow magnitude and variability on population processes, conditioned by channel characteristics. The resulting time series simulate spatially explicit, annual changes in species occurrences or assemblage metrics (e.g. species richness) across the catchment as outcomes of management scenarios. Sensitivity analyses using alternative, plausible links between streamflow components and metapopulation processes, or allowing for alternative modes of fish dispersal, demonstrate large effects of ecological uncertainty on model outcomes and highlight needed research and monitoring. Nonetheless, with uncertainties explicitly acknowledged, dynamic, landscape‐scale simulations may prove useful for quantitatively comparing river management alternatives with respect to species conservation. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.     

A Stress and Coping Model of Medication Adherence and Viral Load in HIV-Positive Men and Women on Highly Active Antiretroviral Therapy (HAART).

The authors tested a structural model that incorporated age, time since diagnosis, social support, coping, and negative mood as predictors of medication adherence and HIV viral load on 188 men and 134 women on highly active antiretroviral therapy (HAART). The authors used psychosocial latent factors formed from baseline measures to predict latent factors of adherence, as assessed by electronic monitoring and self-report, and viral load defined by indicators assessed over a 15-month period. Results from the model indicate that greater negative mood and lower social support are related to greater use of avoidance-oriented coping strategies. Use of these coping strategies by patients on HAART is related to poorer medication adherence and, subsequently, higher viral load. This model advances researchers' understanding of the contribution of psychosocial variables in predicting treatment adherence and disease progression in HIV-positive men and women. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Cover Picture: Functionalized Gold Nanoparticles Mimic Catalytic Activity of a Polysiloxane‐Synthesizing Enzyme (Adv. Mater. 10/2005)

A system that acts as a biomimetic of the silica‐synthesizing enzyme found in a marine sponge is reported by Morse and co‐workers on p. 1234. Gold nanoparticles (GNPs) are functionalized with the same organic moieties that are found in the enzyme's catalytic site. Interaction between the nucleophilic (OH‐terminated) and hydrogen‐bonding (imidazole‐terminated) GNPs, as shown on the cover, is required for the hydrolysis of a silicon alkoxide precursor and subsequent polycondensation to form silica at a low temperature and near‐neutral pH. Replacement of either of the required functional groups by a non‐reactive methyl group abolishes catalysis in this synthetic system, as it does in the biological enzyme. Cover art provided by Peter Allen.     

An analytical framework for local feedforward networks

Interference in neural networks occurs when learning in one area of the input space causes unlearning in another area. Networks that are less susceptible to interference are referred to as spatially local networks. To obtain a better understanding of these properties, a theoretical framework, consisting of a measure of interference and a measure of network localization, is developed. These measures incorporate not only the network weights and architecture but also the learning algorithm. Using this framework to analyze sigmoidal, multilayer perceptron (MLP) networks that employ the backpropagation learning algorithm on the quadratic cost function, we address a familiar misconception that single-hidden-layer sigmoidal networks are inherently nonlocal by demonstrating that given a sufficiently large number of adjustable weights, single-hidden-layer sigmoidal MLPs exist that are arbitrarily local and retain the ability to approximate any continuous function on a compact domain.     

Comparative toxicity of nanostructured alumina and a commercial inert dust for Sitophilus oryzae (L.) and Rhyzopertha dominica (F.) at varying ambient humidity levels

The widespread concern for environmental and human health has raised the need for new reduced-risk control strategies and the search for new chemical classes of pesticides. Recently, a novel type of particulate material, nanostructured alumina (NSA) has been found to induce mortality in insects exposed to wheat treated with NSA dust. Preliminary studies have shown insecticidal activity of NSA particles on two insect species, Sitophilus oryzae (L.), and Rhyzopertha dominica, (F.), major pests of stored grain. We investigated the toxicity of NSA and Protect-It^® diatomaceous earth (DE) using dry dust applications at three different relative ambient humidity levels. Results showed that NSA was more effective in killing S. oryzae than Protect-It^® and was equally toxic to R. dominica. Treatment with both products also reduced progeny production. In addition, R. dominica was less susceptible to inert dusts than S. oryzae. Our results suggest that NSA might prove a good alternative or complement to DE based products, and encourage further testing with other insect pests and systems, plus experiments on delivery options to further enhance NSA products.     

Erratum to: Fe Oxides on Ag Surfaces: Structure and Reactivity

Topics in Catalysis -     

Temperature variation in stored maize and its effect on capture of beetles in grain probe traps

Seasonal and spatial distribution of Typhaea stercorea (L.) and Tribolium castaneum (Herbst) infesting farm-stored maize in South Carolina were studied by trapping with grain probe traps. Trap catch (numbers captured per week) and weekly mean grain temperature for each trap site were plotted against time and fitted to cubic polynomials, which adequately described seasonal trends. Spatial distribution of trap catch was examined by calculating the coefficient of variation, or dispersion (s²/m) and by constructing a contour map of trap catch values for each week. Seasonal trends in trap catch varied with species, farm, and storage season, and tended to parallel temperature trends, so that trap catch and temperature were positively correlated. Trap catch was highly aggregated except for weeks when few insects were captured. Residuals (observed-predicted values), calculated from the fitted trend curves, represent the spatial component of variation. When residuals were analyzed, the positive correlation between temperature and trap catch was usually reduced or abolished, indicating that spatial variability within any given week reflected the distribution of the population itself, rather than spatial variability in activity produced by temperature gradients. The number of insects captured by a trap is determined mainly by insect activity and the numbers present, but there are no rigorous methods for separating the immediate effect of temperature on activity from the delayed effect on population growth. However, by comparing trends in trap catch with those in temperature, it is sometimes possible to make inferences about changes in population density.     

Analysis of the stress and interfacial reactions in Pt/Ti/SiO2/Si for use with ferroelectric thin films

The microstructure of the Pt/Ti/SiO₂/Si structure has been investigated by scanning and transmission electron microscopy. Pt films of 100 nm thickness deposited by sputtering or evaporation onto unheated substrates gave complete coverage of the underlying Ti layer and showed a granular and faceted structure with grains ∼20 nm in diameter. They did not exhibit hillocks or surface TiO_x formation. X-ray diffraction was used to examine the film stress through use of the sin²ψ method with bulk values for the elastic constants (v=0.39, E=162 GPa). The as-deposited sputtered film had a compressive stress of ∼540 MPa, while the evaporated films had tensile stresses of ∼630 MPa. The films then received a 400°C rapid thermal anneal (RTA) for 90 s and a subsequent RTA of 650°C for 30s. Further investigation of the film stresses and microstructure were made after each annealing step. After the low temperature anneal, the film stress for the sputtered film became tensile. Plan-view sections examined by transmission electron microscopy (TEM) showed that the as-deposited sputtered films were dense but became porous after annealing. Initially, the evaporated films had a less dense microstructure, but were more stable with annealing. Little change in the stress for the evaporated film was observed after this initial low temperature annealing step. Additional annealing of the evaporated and sputtered samples caused complete consumption of the Ti layer including some TiO_x formation from the underlying SiO₂ layer and marked interaction with the Pt; however, little change in the stress was found. The surface of the Pt film revealed larger grains, but otherwise remained unaffected. The underlying phase changes were minimized once the Ti layer had reacted with the Pt. Due to the ratio of the layers, Pt:Ti of 2:1, the surface of the Pt was unaffected.