On measuring nondeterminism in regular languages

It is well known that allowing nondeterminism in a finite automaton can produce in the most extreme case an exponential savings in the number of states required to recognize a regular language. This paper studies situations intermediate between forbidding nondeterminism and allowing it. The amount of nondeterminism used by a finite automaton is quantified, so that the decrease in the size of the state space that occurs as the amount of nondeterminism that is permitted increases in increments can be studied. These intermediate situations are shown always to lie between two extremes:(1) there are no savings as the amount of nondeterminism increases incrementally, so that savings occur only when the amount of nondeterminism becomes unlimited;(2) each increment of nondeterminism results in additional savings, the number s of states decreasing approximately as s^1/i, until exponential savings have been achieved after about i = logs/log log s increments.     

Transistor Paint: Environmentally Stable N‐alkyldithienopyrrole and Bithiazole‐Based Copolymer Thin‐Film Transistors Show Reproducible High Mobilities without Annealing

New solution processable 4‐(2‐hexyldecan)‐4H‐bisthieno[2,3‐d:3′,2′‐b]pyrrole and 4,4′‐dialkyl‐2,2′‐bithiazole‐based copolymers (PBTzDTPs) are synthesized with excellent FET performance. These novel copolymers have considerable potential in printable electronics as they have high charge carrier mobilities, excellent air stability, good solution processibility, and no requirement for post‐deposition thermal annealing, all requirements for this field of application. The thin film transistors fabricated from PBTzDTPs achieve field effect mobilities as high as 0.14 cm² V^?1 s^?1 with current on/off ratios up to 10⁶ without thermal annealing. In addition, the devices exhibit stable performance in air, showing no significant degradation over 60 days. Moreover, the polymers described here provide an excellent example of the systems in which higher mobility performance does not require higher crystalline, long‐range ordered structures. Such a system appears to be particularly promising for rapid fabrication techniques, where kinetic conditions usually prevent the development of long‐range order.     

Widely Tunable Morphologies in Block Copolymer Thin Films Through Solvent Vapor Annealing Using Mixtures of Selective Solvents

Thin films of block copolymers are extremely attractive for nanofabrication because of their ability to form uniform and periodic nanoscale structures by microphase separation. One shortcoming of this approach is that to date the design of a desired equilibrium structure requires synthesis of a block copolymer de novo within the corresponding volume ratio of the blocks. In this work, solvent vapor annealing in supported thin films of poly(2‐hydroxyethyl methacrylate)‐block‐poly(methyl methacrylate) [PHEMA‐b‐PMMA] by means of grazing incidence small angle X‐ray scattering (GISAXS) is investigated. A spin‐coated thin film of a lamellar block copolymer is solvent vapor annealed to induce microphase separation and improve the long‐range order of the self‐assembled pattern. Annealing in a mixture of solvent vapors using a controlled volume ratio of solvents, which are chosen to be preferential for each block, enables selective formation of ordered lamellae, gyroid, hexagonal, or spherical morphologies from a single‐block copolymer with a fixed volume fraction. The selected microstructure is then kinetically trapped in the dry film by rapid drying. This paper describes what is thought to be the first reported case where in situ methods are used to study the transition of block copolymer films from one initial disordered morphology to four different ordered morphologies, covering much of the theoretical diblock copolymer phase diagram.     

Chemikalienfreie Bekämpfung von Holzschädlingen durch dielektrische Erwärmung mit Radiowellen und Mikrowellen

Thermal pest control requires long treatment times due to the low thermal conductivity of wood and may lead to the formation of cracks. Here, the thermal treatment with radio waves as well as microwaves has been studied. The direct dielectric heating has the advantage of a good homogeneity. The obtained temperature profiles for radio waves were more homogeneous compared to microwaves. Detailed studies showed that elimination of pests was not related to the application of the electromagnetic field itself, but due to the temperature increase.     

Über die Verwendung von Glyoxal-bis(tert.-butylnitron) als Spin-Trap

On the Use of Glyoxal Bis (t-Butyl Nitron) as a Spin Trap Nitroxides derived from glyoxal bis(t-butyl nitrone), GBBN , have been studied by e.s.r. spectroscopy. Well resolved e.s.r. spectra exhibiting extra hyperfine splitting by magnetic active nuclei in γ-position have been recorded for the spin adducts of alkyl, as well as ^.N₃ and ^.CH₂Cl radicals. Enhanced stability was found for the spin adducts of halogen atoms. However, a wider application of this spin trap is limited by the strong superposition of the e.s.r. signals of different radical spin adducts which is directly related to almost identical conformations of these nitroxides.