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101.
Francesco Donsì Stefano Cimino Almerinda Di Benedetto Raffaele Pirone Gennaro Russo 《Catalysis Today》2005,105(3-4):551-559
The oxidative dehydrogenation of ethane is carried out in short contact time reactors over Pt and LaMnO3 based catalysts supported on a large number of different ceramic substrates (45, 60 and 80 ppi foam monoliths and 200, 400, 600, 900 and 1200 cpsi honeycomb monoliths). Experimental results, obtained under the same conditions at varying the C2H6/O2 ratio, showed that the highest performance in terms of ethylene selectivity and yield is always attained on LaMnO3 catalysts. Furthermore, the results are significantly influenced by the morphology and cell density of the support, with 45 and 60 ppi foams and 400 and 600 cpsi honeycombs giving the best performance. The experimental results are explained by means of geometrical and fluid dynamic considerations on the support, and by means of a 2D mathematical model, which clearly indicates an optimal intermediate cell density for maximising ethylene selectivity and yield. 相似文献
102.
唐红兵 《水电自动化与大坝监测》2006,30(1):69-71
决策支持系统是水库优化调度实用化的发展方向,对于提高水电站生产效益和水库调度管理水平具有重要意义。结合国电公司重点科技项目“天生桥梯级水电站联合调度决策支持系统”的开发,阐述了开发水电调度决策支持系统实现水库调度实用化的经验:正确反映用户需求、增强用户对系统的控制、用模拟仿真弥补优化调度的不足、用数据库技术扩展水库优化调度实用化功能。 相似文献
103.
政治共同民主为经济共同富裕提供制度基础和政治保障。其中,民主政治是实现共同富裕的前提,建立有效、灵活和合理的政府是关键,健全法制是实现共同富裕的保障。文化共同繁荣为共同富裕提供精神动力和智力支持。 相似文献
104.
In the world energy about 26% of all was dedved from coal combustion. Nearly 80% of the electricity produced in China is generated from coal. Coal will play the most important role in the coming 50 years as the past century in China. However one consequentially of the mining and combustion of coal is the mobilization of trace elements, especially trace metals, which have environmental and human health significance. Information on concentrations and distributions of potentially toxic elements in coal, and information On the modes of occurrence of these elements and the relations of the minerals in coal can help to predict the behavior of the potentially toxic trace metals dudng cleaning, combustion, weathering, and leaching. 相似文献
105.
106.
We have used two dimensional drift diffusion simulations to calculate the electrical properties of bottom contact pentacene based organic thin film transistor, taking into account field-dependent mobility and interface or bulk trap states. In order to derive from basic principles the transport properties of the organic semiconductor we have developed a Monte Carlo simulator to calculate the field dependent mobility. We analyzed the presence of trap states at the interface between organic material and gate insulator and we show the influence of trap states combined with the effect of field-dependent mobility on the transfer characteristic. Numerical calculations are also reported for the output characteristics of the device showing a very good agreement with the available experimental results. 相似文献
107.
108.
Emilio Marengo Valentina Longo Elisa Robotti Marco Bobba Fabio Gosetti Orfeo Zerbinati Silvana Di Martino 《应用聚合物科学杂志》2008,109(6):3975-3982
Principal component regression (PCR), partial least squares (PLS), StepWise ordinary least squares regression (OLS), and back‐propagation artificial neural network (BP‐ANN) are applied here for the determination of the propylene concentration of a set of 83 production samples of ethylene–propylene copolymers from their infrared spectra. The set of available samples was split into (a) a training set, for models calculation; (b) a test set, for selecting the correct number of latent variables in PCR and PLS and the end point of the training phase of BP‐ANN; (c) a production set, for evaluating the predictive ability of the models. The predictive ability of the models is thus evaluated by genuine predictions. The model obtained by StepWise OLS turned out to be the best one, both in fitting and prediction. The study of the breakdown number of samples to be included in the training set showed that at least 52 experiments are necessary to build a reliable and predictive calibration model. It can be concluded that FTIR spectroscopy and OLS can be properly employed for monitoring the synthesis or the final product of ethylene–propylene copolymers, by predicting the concentration of propylene directly along the process line. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
109.
A novel monomer containing pyridylazo-2-naphthoxyl group, 1-(1-(4-vinylbenzyloxy)naphthalen-2-yl)-2-(pyridin-2-yl)diazene (VBNPA), was successfully synthesized and copolymerized with styrene (St) in N,N-dimethyl formamide (DMF) via reversible addition–fragmentation chain transfer (RAFT) polymerization using 2-cyanoprop-2-yl-1-dithionaphthalate (CPDN) as RAFT agent. The polymerization behavior exhibited “living”/controlled characters. The obtained copolymer, poly(St-co-VBNPA), with pre-determinable molecular weight and narrow molecular weight distribution can be used as a carrier in metal ion detection and analysis via pre-concentration technique. The copolymer–metal ion (copper (Cu) and europium (Eu)) complexes were prepared and characterized. 相似文献
110.
介绍了国内外硝酸工业生产情况.分析已投运的国产"四合一"机组在运行中出现的问题,并对国产"四合一"机组和硝酸装置设计提出几点建议. 相似文献