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51.
在变化的媒体世界中,宽带载体很快也参与了"围绕媒体内容的竞争",这对于从事印刷信息的企业也是如此.在新的条件下,把他们的品牌、甚至制作的内容以及多年的经验都运用在竞争的优势中.本文旨在介绍宽带的竞争,以激励德国出版业未来的发展情况. 相似文献
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Bernd-Michael Neumann Hans-Georg Henning Dieter Gloyna Margit Bandlow 《Advanced Synthesis \u0026amp; Catalysis》1976,318(5):823-834
Sydnone Ethylenes. I Stereoselective Synthesis of Sydnone Ethylenes from Sydnone Aldehydes Sydnones are formylated in 4-position by the VILSMEIER -HAAK reaction. N(3)-Methyl- and N(3)-(p-Anisyl)-sydnone-(4)-carboxaldehyde react stereoselectively to sydnone ethylenes with diethyl ethoxycarbonylmethanephosphonate by HORNER reaction and with arylmethylphosphonium salts by WITTIG reaction in the presence of strong bases. In the latter case, especially in the absence of lithium cations, Z-selectivity is observed which is explained by electronic interaction between the sydnone cyclus and the aromatic substituent of the phosphine ylid in the first step of the reaction. The configuration of the obtained Z- and E-sydnone ethylenes is determined by means of 1H-NMR- and IR-spectra. 相似文献
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Dr. Robert Kuhnert Dr. Lydia Kuhnert Dr. Menyhárt-B. Sárosi Sven George Dr. Dijana Draca Dr. Svetlana Paskas Dr. Bettina Hofmann Prof. Dr. Dieter Steinhilber Prof. Dr. Walther Honscha Prof. Dr. Sanja Mijatović Prof. Dr. Danijela Maksimović-Ivanić Prof. Dr. Evamarie Hey-Hawkins 《ChemMedChem》2022,17(1):e202100588
12-Lipoxygenase is crucial for tumour angiogenesis. 5,6,7-Trihydroxy-2-phenyl-4H-1-benzopyran-4-one (baicalein) is a suitable inhibitor for this enzyme but is rapidly metabolised in vivo. Thus, an improvement of the metabolic stability is necessary to enhance the therapeutic efficiency. An emerging approach to enhance metabolic stability of carbon-based pharmaceuticals is the use of metabolically stable, non-toxic boron clusters, such as dicarba-closo-dodecaborane(12)s (carboranes) as phenyl mimetics. Therefore, the unsubstituted phenyl ring of baicalein was replaced by meta-carborane, resulting in borcalein, the carborane analogue of baicalein. This substitution resulted in a decreased inhibitory activity toward 12-lipoxygenase, but led to increased toxicity in melanoma (A375, B16, B16F10) and colon cancer cell lines (SW480, HCT116, CT26CL25) with decreased tumour selectivity in comparison to baicalein. Surprisingly, borcalein displays a different mechanism of cytotoxicity with increased intracellular production of reactive oxygen species (ROS), reactive nitrogen species (RNS) and nitric oxide (NO). 相似文献
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Nasir Mahmood Asad Ullah Khan Klaus Werner Stöckelhuber Amit Das Dieter Jehnichen Gert Heinrich 《应用聚合物科学杂志》2014,131(11)
This article reports the preparation and characterization of multiwalled carbon nanotubes (MWCNTs)‐filled thermoplastic polyurethane–urea (TPUU) and carboxylated acrylonitrile butadiene rubber (XNBR) blend nanocomposites. The dispersion of the MWCNTs was carried out using a laboratory two roll mill. Three different loadings, that is, 1, 3, and 5 wt % of the MWCNTs were used. The electron microscopy image analysis proves that the MWCNTs are evenly dispersed along the shear flow direction. Through incorporation of the nanotubes in the blend, the tensile modulus was increased from 9.90 ± 0.5 to 45.30 ± 0.3 MPa, and the tensile strength at break was increased from 25.4 ± 2.5 to 33.0 ± 1.5 MPa. The wide angle X‐ray scattering result showed that the TPUU:XNBR blends were arranged in layered structures. These structures are formed through chemical reactions of ? NH group from urethane and urea with the carboxylic group on XNBR. Furthermore, even at a very low loading, the high degree of nanotubes dispersion results in a significant increase in the electrical percolation threshold. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40341. 相似文献
58.
Amna Youssef Ramzy Ahmed Mohammed Moneeb El‐Sabbagh Leif Steuernagel Gerhard Ziegmann Dieter Meiners 《应用聚合物科学杂志》2014,131(3)
The presented study investigates the flow length and the corresponding fiber content distribution in the injection‐moulded natural fiber reinforced thermoplastics and its relation to fiber type and processing parameters such as injection pressure, temperature, injection rate and mould tempering by increasing die temperature. In this research, polypropylene compounds with nominally 30 wt % hemp and sisal fibers are investigated. The influence of the injection pressure (500 and 1000 bar), melt temperature (180°C, 200°C, and 220°C), and die temperature (23°C and 80°C) on the fiber content distribution all over the sample is investigated. An increasing linear trend of fiber content along the spiral length is observed as an evidence of a fiber/polymer multiflow system. A pattern for fiber content distribution with respect to the fiber length along the injected spiral can be distinguished, where the longer fibers are usually found at the end of the injected part and the shorter fibers remain near mould entrance point. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39861. 相似文献
59.
Chemikalienfreie Bekämpfung von Holzschädlingen durch dielektrische Erwärmung mit Radiowellen und Mikrowellen 下载免费PDF全文
Christian Hoyer Christian Pfütze Dr. Rudy Plarre Dr. Ulf Trommler Steffen Steinbach Kerstin Klutzny Dr. Frank Holzer Carsten Rabe Björn Höhlig Prof. Frank‐Dieter Kopinke Prof. Detlef Schmidt Dr. Ulf Roland 《化学,工程师,技术》2014,86(8):1187-1197
Thermal pest control requires long treatment times due to the low thermal conductivity of wood and may lead to the formation of cracks. Here, the thermal treatment with radio waves as well as microwaves has been studied. The direct dielectric heating has the advantage of a good homogeneity. The obtained temperature profiles for radio waves were more homogeneous compared to microwaves. Detailed studies showed that elimination of pests was not related to the application of the electromagnetic field itself, but due to the temperature increase. 相似文献
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Poly(vinylidene fluoride) (PVDF) based nanocomposites with different surface-functionalized multi-walled carbon nanotubes (MWCNTs) were prepared by melt mixing in a small scale compounder. With the incorporation of commercial functionalized MWCNTs, the β-phase in PVDF can be directly achieved from melt cooling, as verified by results of Fourier transform infrared spectrum and X-ray diffraction. Interestingly, nanocomposites with amino group functionalized MWCNTs showed the highest percentage of β-phase (17.4%) formation in PVDF, followed by those with hydroxyl groups (11.6%) and unmodified MWCNTs (9.4%). However, the nanocomposites containing MWCNTs with carboxyl groups which were thought to be able to well interact with the dipoles on PVDF chains have the lowest amount of β-phase, i.e. 4.7%. The analysis on the mechanism of the influence of surface functionalization of MWCNTs on the formation of β-phase in PVDF shows that the combined effects of the dispersion of MWCNTs and the nanotube–polymer interactions account for the formation of the β-phase in PVDF. 相似文献