Transient and steady-state analysis of catalyst poisoning and mixed potential formation in direct methanol fuel cells

The present dynamic model is developed to investigate the coupled reaction mechanisms in a DMFC and therein associated voltage losses in the catalyst layers. The model describes a complete five-layer membrane electrode assembly (MEA), with gas diffusion layers, catalyst layers and membrane. The analysis of the performance losses are mainly focused on the electrochemical processes. The model accounts for the crossover of both, methanol from anode to cathode and oxygen from cathode to anode. The reactant crossover results in parasitic internal currents that are finally responsible for high overpotentials in both electrodes, so-called mixed potentials. A simplified and general reaction mechanism for the methanol oxidation reaction (MOR) was selected, that accounts for the coverage of active sites by intermediate species occurring during the MOR. The simulation of the anode potential relaxation after current interruption shows an undershoot behavior like it was measured in the experiment [1]. The model gives an explanation of this phenomenon by the transients of reactant crossover in combination with the change of CO and OH coverages on Pt and Ru, respectively.     

Durability of Brick Lined Steel Ladles from a Mechanical Point of View

The refractory lining in steel ladles is exposed to chemical and mechanical loads during the heats. Mechanical loads develop from the thermal expansion of the refractories which is confined either by the steel construction or by regions of different temperature within the refractory material. The aim of this work was the investigation of factors influencing the mechanical durability of refractory steel ladle linings and the clarification of failure mechanisms. Especially irreversible strains at the hot face of the working lining caused by compressive stresses induce an opening of joints at the hot face. The irreversible strains reduce the compressive stresses in circumferential direction and increase the probability of tensile failure. A further effect of the irreversible strains is a reduced stability of the working lining. Of special interest in this context is a possible controlled expansion of bricks to counterbalance the irreversible compressive strains.     

The Fusion Science Research Plan for the Major U.S. Tokamaks

This is the May 1996 report of a subpanel of the US Department of Energy Fusion Energy Sciences Advisory Committee (FESAC), charged with conducting a review of the progress, priorities and potential near-term contributions of TFTR, DIII-D and Alcator C-MOD (and other facilities as appropriate) as part of the transition to a Fusion Energy Sciences Program and produce an optimum plan for obtaining the most scientific benefit from them.     

Doucet,Michel; Fleck,Klaus E. W.: Wörterbuch der Rechts- und Wirtschaftssprache,Teil 1: Französisch-Deutsch, 6. Aufl.

Ohne Zusammenfassung     

A new load cell for measuring normal and shear stresses

A special stress measuring device for determining the normal and shear stresses acting on silo walls was developed and tested. The load cell can be used for measuring simultaneously the normal stress as well as the intensity and direction of the shear stress.     

2-Amino-3-substituted-6-[(E)-1-phenyl-2-(N-methylcarbamoyl)vinyl]imid azo[1,2-a]pyridines as a novel class of inhibitors of human rhinovirus: stereospecific synthesis and antiviral activity

A series of 2-amino-3-substituted-6-[(E)-1-phenyl-2-(N-methylcarbamoyl)vinyl]+ ++imid azo[1,2-a]pyridines 1a-i, structurally related to Enviroxime and its analogous benzimidazoles, was designed and prepared for testing as antirhinovirus agents. The imidazo ring in this class of compounds was constructed starting from the aminopyridine after tosylation and subsequent treatment with the appropriate acetamides. The key steps in the synthesis include the development and use of a new Horner-Emmons reagent for the direct incorporation of methyl vinylcarboxamide. The reaction was stereospecific in the substrates 5a-f leading exclusively to the desired E-isomer and avoiding the use of reverse-phase preparative HPLC for the separation of both possible isomers before antiviral activity evaluation. The isopropylsulfonyl group, known as the best substituent at the 1-position in the benzimidazole SAR in terms of activity, was introduced in this new series of imidazo[1,2-a]pyridines via halogen-metal exchange and subsequent treatment with isopropyl isopropanethiolsulfonate. Compounds 1a-i were evaluated in plaque reduction assay and in a cytopathic effect assay. Compounds 1b-d,h exhibited a strong antirhinovirus activity, and no apparent cellular toxicity was visible. The substitution at the 3-position was required for activity. Surprisingly the isopropylsulfonyl in this family of compounds did not enhance the activity as in the case of benzimidazoles. Instead, compound 1i was 4 times less active than its phenyl and sulfide partners. The chemistry as well as the biological evaluation are discussed.     

Phase Transformation Modelling and Parameter Identification from Dilatometric Investigations

The goal of this paper is to propose a new approach towards the evaluation of dilatometric results, which are often employed to analyse the phase transformation kinetics in steel, especially in terms of continuous cooling transformation (CCT) diagram. A simple task of dilatometry is deriving the start and end temperatures of the phase transformation. It can yield phase transformation kinetics provided that plenty metallographic investigations are performed, whose analysis is complicated especially in case of several coexisting product phases. The new method is based on the numerical solution of a thermomechanical identification problem. It is expected that the phase transformation kinetics can be derived by this approach with less metallographic tasks. The first results are remarkably promising although further investigations are required for the numerical simulations.