High-frequency SPICE model of anisotropic conductive film flip-chipinterconnections based on a genetic algorithm

This paper firstly reports on the high-frequency SPICE model of the ACF flip-chip interconnections up to 13 GHz. The extraction process is based on an optimization procedure, called a genetic algorithm, which is known as a robust optimization tool. The proposed equivalent circuit model of the ACF interconnection can readily be used in SPICE circuit simulations for signal integrity analysis of high-frequency packages. Two different ACF interconnections were studied using the Au-coated polymer ball and Ni-filled ball. The extracted models of the two ACFs were found strongly dependent on not only size and rigidity of the conducting balls, but also on their magnetic permeability     

Noise in a point-contact dc SQUID

Measurements of five variations of a toroidal point-contact dc superconducting quantum interference device (SQUID) are presented. The energy resolution and other parameters of these SQUIDs are examined and compared with the predictions of the Resistively Shunted Junction model. For these SQUIDs, the measured minimum energy resolution was approximately 2×10^–30 J/Hz. Excess noise in the point contacts was found to limit the energy resolution of the SQUIDs. A comparison between the typical junction parameters and noise obtained for our niobium-niobium point contacts and those of others is given. TheI–V characteristics of the junctions showed the effects of Joule heating. The white voltage noise spectral density was found to have an approximately parabolic dependence on the average voltage for bias currents larger than the critical current. While this parabolic dependence is consistent with heating effects in the junctions, the amplitude of the noise cannot be explained in terms of a heating model. The low-frequency noise of the point contacts has also been investigated.     

Dissolution and reprecipitation of barium at the particulate BaTiO3-aqueous solution interface

The electrokinetic behavior of BaTO₃ particles in an aqueous medium exhibited a hysteresis loop with titration direction. As BaTiO₃ suspension was titrated toward acidic pH, the amount of Ba²⁺ dissolution strongly increased, and in the subsequent titration toward alkaline pH, Ba²⁺ adsorbed and/or reprecipitated on the Ba-depleted BaTiO₃ surface. This dissolution-reprecipitation cycle results in the observed hysteresis behavior. An attempt was made to identify the responsible species of the adsorbed/reprecipitated compound by XPS in conjunction with electrokinetic titrations.     

多孔钢板在双轴受压与边缘剪力荷载共同作用下的极限强度

作为作者系列研究成果[Paik J K．Ultimate strength of perforated steel plates under edge shear loading．Thin-Walled Structures，2007，45：301-6，Paik J K．Ultimate strength of perforated steel plates under axial compressive loading along short edges．Ships Offshore Struct，2007，2（3）：（inpress）]的终结篇，与前期论文在边缘剪力或单轴压力荷载方面进行了对比，目的是研究双轴受压和边缘剪力作用下多孔钢板的极限强度特点，这是船舶和船舶型海洋结构在货物和水压作用下的一个典型受力模式。板的约束考虑为四边简支，中心区域为圆形孔。一系列ANSYS非线性有限元分析中考虑了不同的板尺寸（厚度）。在有限元分析基础上，推导出组合荷载下多孔板的极限强度交互关系公式，可用于可靠性分析或规范中极限强度的预测。     

Structural estimation of particle arrays at air–water interface based on silica particles with well‐defined and highly grafted poly(methyl methacrylate)

Silica nanoparticles with well‐defined, highly grafted dense poly(methyl methacrylate) (MMA) were prepared by surface‐initiated activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP) of methyl methacrylate with an initiator‐fixed silica particle in the presence of air. Two different polymerizations of MMA were carried out under the same conditions using tris[2‐(dimethylamino)ethyl]amine (Me₆TREN) and N,N,N′,N′,N″‐pentamethyldiethylene‐triamine (PMDETA) as the ligand, respectively. In the CuCl₂/PMDETA system, polymerization appeared to be more controlled with a lower polydisperisty compared with the CuCl₂/Me₆TREN system. The monolayer of these particles was formed at the air–water interface using Langmuir‐Blodgett (LB) technique. Multilayers of the particles were fabricated by repetition of LB depositing. A surface pressure–area (π–A) measurement and SEM observation were used to characterize the particle arrays. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers     

Interfacial Structure of Ordered Domains in Barium Lanthanum Magnesium Niobate

Microstructural studies on the interfacial boundaries of 1:1 and 1:2 ordered domains in (Ba_0.9La_0.1)(Mg_0.37Nb_0.63)O₃ were conducted using high-resolution transmission electron microscopy and X-ray diffractometry. Both 1:2 and 1:1 ordered domains coexisted in a fully ordered single grain. Each ordered domain occupied its own region, and the interfaces were atomically sharp and coherent. The wavelength of the superlattice modulation was ∼0.47 nm in the 1:1 ordered domain and ∼0.71 nm in the 1:2 ordered domain. The transition from the 1:2 ordered region to the 1:1 ordered region was clearly shown at the interface. These observations well support the structural models that have been previously presented.     

Discoloration mechanism of polymer surface in contact with air–water interface

The white-colored inner surface of a polypropylene (PP) material containing water discolored and turned yellow. The discoloration occurred selectively on the surface at the point of contact with the air–water interface. Since the polymer surface was exposed to water in darkness at room temperature, no sign of deterioration or degradation of the polymer at the discolored surface was confirmed. This study conducts an in-depth analysis of the discoloration mechanism of the polymer surface. A variety of technical approaches, including microscopic, spectroscopic, and chromatographic analysis techniques, were used to investigate the nature of discoloration and the root cause. From the analysis results, the discoloration was ascribed principally to a phenol transformation compound having the structure of a quinone methide, which was identified as a degradation product of a primary antioxidant. Based on the observations and experimental results, a plausible discoloration mechanism was proposed.     

Physicochemical,microbial, and sensory evaluation of cook-chilled Korean traditional rice cake (<Emphasis Type="Italic">Backseolgi</Emphasis>) during storage via various packaging methods

Backseolgi is a Korean traditional rice cake, which is prepared by steaming the rice flour. After cook-chilling processing, backseolgi samples packaged by a modified atmosphere package (MAP), top sealing package (TSP), and linear low density-polyethylene package (LDPA; control) were evaluated in regard to microbial safety and sensory characteristics during storage. During storage at 30°C, the cell numbers of aerobic, psychrophilic, and anaerobic bacteria for the MAP sample increased to below 2 log CFU/g for 10 days, whereas the control and TSP samples increased more than 5.0 log CFU/g after 4 days. After 50 days of storage at 3°C, the cell numbers in the MAP sample were below 1.0 log CFU/g, whereas they were approximately 3.0 log CFU/g in the control and TSP samples. In the case of the sensory evaluation, the MAP sample score was above 5.0, whereas the scores of the CON and TSP samples were 1.0. As a result, MAP was identified as the most effective packaging method for increasing microbial safety while maintaining the sensory characteristics of the cook-chilled backseolgi.     

Effects of Anisotropic Conductive Film Viscosity on ACF Fillet Formation and Chip-On-Board Packages

In this paper, the effects of anisotropic conductive film (ACF) viscosity on ACF fillet formation and, ultimately, on the pressure cooker test (PCT) reliability of ACF flip chip assemblies were investigated. The ACF viscosity was controlled by varying the molecular weight of the epoxy materials. It was found that the ACF viscosity increased as the increase of molecular weight of the epoxy materials. However, there was little variation of the thermomechanical properties among the evaluated ACFs with different viscosites. Also, the results showed that the ACFs have no differences in moisture absorption rate, die adhesion strength, and degree-of-cure. In scanning electron microscopy images, the lower ACF viscosity resulted in the smoother ACF fillet shape and the higher fillet height. From the results of PCT, the ACF flip chip assembly with the smoother fillet shape showed better reliability in terms of contact resistance changes. After 130 h of PCT, the flip chip assembly with lower ACF viscosity also showed a lesser degree of delamination at the ACF/chip interface.