Significantly Enhanced Photoluminescence of Doped Polymer‐Metal Hybrid Nanotubes

We report on the significantly enhanced photoluminescence (PL) of hybrid double‐layered nanotubes (HDLNTs) consisting of poly(3‐methylthiophene) (P3MT) nanotubes with various doping levels enveloped by an inorganic, nickel (Ni) metal nanotube. From laser confocal microscopy PL experiments on a single strand of the doped‐P3MT nanotubes and of their HDLNTs, the PL peak intensity of the HDLNT systems increased remarkably up to ～350 times as the doping level of the P3MT nanotubes of the HDLNTs increased, which was confirmed by measurements of the quantum yield. In a comparison of the normalized ultraviolet and visible absorption spectra of the doped‐P3MT nanotubes and their HDLNTs, new absorption peaks corresponding to surface‐plasmon (SP) energy were created at 563 and 615 nm after the nanoscale Ni metal coating onto the P3MT nanotubes, and their intensity increased on increasing the doping level of the P3MT nanotube. The doping‐induced bipolaron peaks of the HDLNTs of doped‐P3MT/Ni were relatively reduced, compared with those of the doped‐P3MT nanotubes before the Ni coating, due to the charge‐transfer effect in the SP‐resonance (SPR) coupling. Both energy‐transfer and charge‐transfer effects due to SP resonance contributed to the very‐large enhancement of the PL efficiency of the doped‐P3MT‐based HDLNTs.     

多注速调管TM410 模同轴输出腔的研究

研究了多注速调管TM₄₁₀ 模同轴输出腔中出现的外观品质因数高,模式频率间隔小以及工作模式场分布的均匀性差等问题,提出了一种设置短路杆和金属环的输出腔结构,从而改善了TM₄₁₀ 模输出腔上述三个方面的性能。通过分析发现,适当设置短路杆和重入环不仅可以使外观品质因数降低,还可以改善工作模式的场分布;设置重入环还可以增大工作模式和邻近模式的频率间隔。利用CST-MWS 软件,对X 波段具有短路杆和金属环的多注速调管TM₄₁₀模同轴输出腔进行了模拟计算,其工作模式（TM₄₁₀模）的外观品质因数降低了42.7%（从540.4 降至309.6）,TM₄₁₀ 模与邻近模式的频率间隔均达到了1.3 GHz 以上,工作模式的场分布也变得均匀。     

Resource efficiency improved approach for shared path protection in EONs

For improving the resource efficiency of dynamic shared path protection in elastic optical networks, a survivable RSA (SRSA)-based heuristic algorithm is proposed in the paper. In SRSA, an adaptive adjustment link cost function is devised to effectively select working and protection paths. The cost function sufficiently considers available spectrum resources and the length of light paths for both working and protection paths. In order to achieve high resource efficiency, a spectrum allocation strategy named minimal cost stable set is proposed to allocate spectrum for protection paths with respect to the resource efficiency in the link cost function. And the graph coloring algorithm is introduced to select the shared protection path with the highest resource efficiency for the request. Compared with the shared path protection and dynamic load balancing shared path protection, simulation results show that the proposed SRSA decreases bandwidth blocking probability and achieves high resource efficiency.     

A Study of the Parasitic Properties of the Schottky Barrier Diode

In this paper, we present a newly designed parameter extraction method of the Schottky barrier diode (SBD) with the purpose of measuring and studying its parasitic properties. This method includes three kinds of auxiliary configurations and is named as three-configuration parameter extraction method (TPEM). TPEM has such features as simplicity of operation, self-consistence, and accuracy. With TPEM, the accurate parasitic parameters of the diode can be easily obtained. Taking a GaAs SBD as an example, the pad-to-pad capacitance is 7 fF, the air-bridge finger self-inductance 11 pH, the air-bridge finger self-resistance 0.6 Ω, and the finger-to-pad capacitance 2.1 fF. A more accurate approach to finding the value of the series resistant of the SBD is also proposed, and then a complete SBD model is built. The evaluation of the modeling technology, as well as TPEM, is implemented by comparing the simulated and measured I-V curves and the S-parameters. And good agreements are observed. By using TPEM, the influence of the variation of the geometric parameters is studied, and several ways to reduce the parasitic effect are presented. The results show that the width of the air-bridge finger and the length of the channel are the two largest influencing parameters, with the normalized impact factors 0.56 and 0.29, respectively. By using TPEM and the modeling technology presented in this paper, a design process of the SBD is proposed. As an example, a type of SBD suitable for 500–600 GHz zero-biased detection is designed, and the agreement between the simulated and measured results has been improved. SBDs for other applications could be designed in a similar way.     

Porous Iron–Cobalt Alloy/Nitrogen‐Doped Carbon Cages Synthesized via Pyrolysis of Complex Metal–Organic Framework Hybrids for Oxygen Reduction

Efficient and stable nonprecious metal electrocatalysts for oxygen reduction are of great significance in some important electrochemical energy storage and conversion systems. As a unique class of porous hybrid materials, metal–organic frameworks (MOFs) and their composites are recently considered as promising precursors to derive advanced functional materials with controlled structures and compositions. Here, an “MOF‐in‐MOF hybrid” confined pyrolysis strategy is developed for the synthesis of porous Fe–Co alloy/N‐doped carbon cages. A unique “MOF‐in‐MOF hybrid” architecture constructed from a Zn‐based MOF core and a Co‐based MOF hybrid shell encapsulated with FeOOH nanorods is first prepared, followed by a pyrolysis process to obtain a cage‐shaped hybrid material consisting of Fe–Co alloy nanocrystallites evenly distributed inside a porous N‐doped carbon microshell. Of note, this strategy can be extended to synthesize many other multifunctional “nanosubstrate‐in‐MOF hybrid” core–shelled structures. Benefiting from the structural and compositional advantages, the as‐derived hybrid cages exhibit superior electrocatalytic performance for the oxygen reduction reaction in alkaline solution. The present approach may provide some insight in design and synthesis of complex MOF hybrid structures and their derived functional materials for energy storage and conversion applications.     

有限流保护功能的霍尔电流传感器

简单介绍了闭环式霍尔电流传感器的工作原理,在其基础上提出了一种限流保护电路,使得霍尔电流传感器原边电流过载时输出电流钳位,保障其满足3倍甚至更高倍过载要求,并通过了试验验证.     

pin硅波导在1550 nm波段的光电流雪崩增强效应实验研究

The photocurrent effect in pin silicon waveguides at 1550 nm wavelength is experimentally investigated. The photocurrent is mainly attributed to surface-state absorption,defect-state absorption and/or two-photon absorption.Experimental results show that the photocurrent is enhanced by the avalanche effect.A pin silicon waveguide with an intrinsic region width of 3.4μm and a length of 2000μm achieves a responsivity of 4.6 mA/W and an avalanche multiplication factor of about five.     

Photocurable 3D Printing of High Toughness and Self-Healing Hydrogels for Customized Wearable Flexible Sensors

Currently, most customized hydrogels can only be processed via extrusion-based 3D printing techniques, which is limited by printing efficiency and resolution. Here, a simple strategy for the rapid fabrication of customized hydrogels using a photocurable 3D printing technique is presented. This technique has been rarely used because the presence of water increases the molecular distance between the polymer chains and reduces the monomer polymerization rate, resulting in the failure of rapid solid-liquid separation during printing. Although adding cross-linkers to printing inks can effectively accelerate 3D cross-linked network formation, chemical cross-linking may result in reduced toughness and self-healing ability of the hydrogel. Therefore, an interpenetrated-network hydrogel based on non-covalent interactions is designed to form physical cross-links, affording fast solid-liquid separation. Poly(acrylic acid (AA)-N-vinyl-2-pyrrolidone (NVP)) and carboxymethyl cellulose (CMC) are cross-linked via Zn²⁺-ligand coordination and hydrogen bonding; the resulting mixed AA-NVP/CMC solution is used as the printing ink. The printed poly(AA-NVP/CMC) hydrogel exhibited high tensile toughness (3.38 MJ m⁻³) and superior self-healing ability (healed stress: 81%; healed strain: 91%). Some objects like manipulator are successfully customized by photocurable 3D printing using hydrogels with high toughness and complex structures. This high-performance hydrogel has great potential for application in flexible wearable sensors.     

某分离用固体小火箭工作故障分析及设计改进

为解决某分离用固体小火箭在高温55℃环境试验中,出现壳体失强与较高点火压力峰的问题,分析了发生该工作故障的可能原因。通过对装药结构及挡药板结构进行改进设计,以期扩大燃气通道;通过对点火药盒结构进行改进设计,并调节点火药药量,以期降低点火压力峰值。验证试验表明,改进措施切实有效,点火压力峰值满足设计要求,提高了小火箭工作的可靠性与安全性。     

装备的环境腐蚀效应抑制技术

从我国的环境特征和军事需求出发,分析了装备面临的环境、装备的环境腐蚀效应及危害,叙述了如何从环境抑制、增强装备耐蚀品质和加强维护保养与维修三个方面加强装备的环境腐蚀效应抑制,为提高装备环境适应性提供工程解决方案.