Effect of the addition of Fe2O3 and heat treatment duration on the magnetic susceptibility of V2O5-P2O5-B2O3 glass system

The effect of the addition of Fe₂O₃ and heat treatment duration on the magnetic susceptibility of vanadium borophosphate glass were studied. The magnetic susceptibility of glass samples was found to increase with increasing Fe₂O₃ content, which may be explained by the formation of the FeO₆ group and the change of Fe²⁺ to Fe³⁺ which has higher paramagnetic properties. No detectable changes in the magnetic susceptibility with heat treatment for the samples containing 0.0, 0.5 and 1.0 mol% Fe₂O₃ was observed. The magnetic susceptibility for the heat treated samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃ decreases sharply with increasing duration of heat treatment up to 6 h and then remains almost constant. The sharp decrease in magnetic susceptibility of 2.5 mol% Fe₂O₃ is attributed to the increase in the number of ferrous ions. The sharp decrease for samples containing 5.0 and 7.5 mol% Fe₂O₃ is attributed to the increase in the number of Fe³⁺ in tetrahedral co-ordination. The rate of crystallization owing to the heat treatment was calculated and was found to increase with increasing iron oxide content. The geometry of crystallization was found to be in three-, two-and one-dimension(s) for samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃, respectively.     

Detecting lamb waves with broadband acousto-ultrasonic signals in composite structures

Lamb waves can be produced and detected in ceramic matrix composites (CMC) and metal matrix composites (MMC) plates using the acousto-ultrasonic configuration employing broadband transducers. Experimental dispersion curves of lowest symmetric and lowest antisymmetric modes behave in a manner analogous to the graphite/polymer theoretical curves. In this study a basis has been established for analyzing Lamb wave velocities for characterizing composite plates. Lamb wave dispersion curves and group velocities were correlated with variations in axial stiffness and shear stiffness in MMC and CMC. For CMCs, interfacial shear strength was also correlated with the first antisymmetric Lamb mode.     

Competitive learning and soft competition for vector quantizerdesign

The authors provide a convergence analysis for the Kohonen learning algorithm (KLA) with respect to vector quantizer (VQ) optimality criteria and introduce a stochastic relaxation technique which produces the global minimum but is computationally expensive. By incorporating the principles of the stochastic approach into the KLA, a deterministic VQ design algorithm, the soft competition scheme (SCS), is introduced. Experimental results are presented where the SCS consistently provided better codebooks than the generalized Lloyd algorithm (GLA), even when the same computation time was used for both algorithms. The SCS may therefore prove to be a valuable alternative to the GLA for VQ design     

Failure analysis of a hot extrusion die used for Al-Li alloy processing

Al-Li alloys being developed as lighter, substitutes for conventional high strength Al alloys are to be processed by routine methods. During extrusion of a 8090 Al-Li alloy, the extrusion die container failed causing some alarm. This failed die container was analysed to examine if the failure was caused by interaction of Li diffusing out of Al-Li alloy with the carbides of die steel. The evidence, although not conclusive, is sufficient to exercise caution during such processing.     

Efficient wavelength conversion with high-power passivelyQ-switched diode-pumped neodymium lasers

Powerful CW diode-pumped Nd:YAG and Nd:YVO4 lasers Q-switched by Cr:YAG saturable absorbers demonstrate efficient (30%-60%) harmonic and parametric conversion, generating hundreds of milliwatts from ultraviolet to mid-infrared     

Prediction error method for second-order blind identification

Blind channel identification methods based on the oversampled channel output are a problem of current theoretical and practical interest. In this paper, we introduce a second-order blind identification technique based on a linear prediction approach. In contrast to eigenstructure-based methods, it will be shown that the linear prediction error method is “robust” to order overdetermination. An asymptotic performance analysis of the proposed estimation method is carried out, consistency and asymptotic normality of the estimates is established. A closed-form expression for the asymptotic covariance of the estimates is given. Numerical simulations and investigations are finally presented to demonstrate the potential and the “robustness” of the proposed method