New formulations for unsaturated polyester resins and their interactions with low-profile agents and glass fibres

Special anhydrides, such as hexahydrophthalic, methyl-hexahydrophthalic, nadic, methylnadic and methyl-tetrahydroxyphthalic, have been polycondensed with glycols such as propylene and di-propylene, to obtain new formulations for unsaturated polyesters. The properties of these resins, such as tensile behaviour and ultraviolet resistance, neat or mixed with anti-shrinkage additives have been examined and compared to standard polyester resins. Particular attention was paid to the study of the influence of low-profile agents on the resulting phase structures of cured systems. Moreover, the role played by the different phases on the fibre/matrix addition in composite materials reinforced with coated glass fibres was also investigated.     

Interrupted ultrasonic bolt load measurements using the pulsedphase-locked loop system

A method of reacquiring a previous phase lock-point using the pulsed phase-locked loop (PPLL) ultrasonic system in situations where the measurement is interrupted such as by removing and recoupling the transducer is developed. Operation of the PPLL is mathematically analyzed in the time domain rather than in the conventional frequency domain, providing a method of characterizing multiple lock-points. The general lock-point reacquisition method that follows from the model relies on measurement over a frequency range that spans several lock-points and is demonstrated to work well for interrupted measurements on threaded fasteners. The method is analyzed for sensitivity to signal noise, and an equation is derived, expressing the number of lock-points over which to measure for successful lock-point reacquisition as a function of signal noise level. Experimental verification on a glass block shows that theoretical values obtained with this model are in good agreement with measurements. Automation of the method presented has been demonstrated, showing that it offers a practical, objective approach to making interrupted load measurements, thereby greatly widening the range of applications of the PPLL     

Calibration and testing facility for resistance welding currentmonitors

The lack of uniform and traceable measurement of pulsed high currents (1-200 kA) utilized in the resistance welding process has long been a problem in the welding community. A testing facility utilizing equipment and knowledge gained in the Department of Energy programs is being made available to the American welding industry to solve these problems. Problems in making these measurements traceable to national standards and proposed solutions are presented. Test equipment and methods are described that will be used to evaluate current-sensing coils and weld-current monitors. Comparison of positional errors for various current-sensing coils is presented, including a recently developed, machinable Rogowski coil     

A Monte Carlo estimation of the marginal distributions in a problem of probabilistic dynamics

Modelling the effect of the dynamic behaviour of a system on its PSA study leads, in a Markovian framework, to a development at first order of the Chapman-Kolmogorov equation, whose solutions are the probability densities of the problem. Because of its size, there is no hope of solving directly these equations in realistic circumstances. We present in this paper a biased simulation giving the marginals and compare different ways of speeding up the integration of the equations of the dynamics.     

Unrestricted Hartree-Fock approximation of the extended emery model

We use an unrestricted self-consistent Hartree-Fock approach to calculate the nature of doping states in the three-band Hubbard model. It turns out that for physically relevant parameter values one hole is localized within a small spin-polarized region where five Cu spins are aligned in the same direction. The spin polarization and binding energy between these spinpolaronic states are investigated as a function of different parameters including a Holstein-type electron-phonon coupling on the Cu sites. At higher doping concentration we observe the occurrence of afmon states where the holes are localized in a ring-shaped area. Inside this ring the antiferromagnetic order parameter has inverse sign with respect to the residual antifer-romagnetically ordered plane.     

Increased production of reactive oxygen species by rat liver mitochondria after chronic ethanol treatment

Rat liver microsomes and, to a lesser extent, nuclei were previously shown to produce reactive oxygen species at elevated rates after chronic ethanol treatment. The ability of intact rat liver mitochondria to interact with iron and either NADH or NADPH, and the effects of ethanol treatment, on production of reactive oxygen intermediates was determined. In the presence of ferric-ATP, NADH or NADPH catalyzed mitochondrial lipid peroxidation. Rates were elevated two- to threefold with mitochondria from ethanol-fed rats with both reductants. Mitochondrial lipid peroxidation was insensitive to superoxide dismutase, catalase, or hydroxyl radical scavengers but was sensitive to GSH and anti-oxidants such as trolox. Mitochondrial generation of hydroxyl radical-like species (assayed by oxidation of chemical scavengers) was increased after chronic ethanol treatment, as was H2O2 production. Modifiers of mitochondrial metabolism such as rotenone, cyanide, or an uncoupling agent, had no effect on mitochondrial production of reactive oxygen intermediates. The membrane-impermeable thiol reagent, p-chloromercuribenzoate, was complete inhibitory with both mitochondrial preparations. The activity of the rotenone-insensitive NADH-cytochrome c reductase, an enzyme of the outer mitochondrial membrane, was increased 40 to 60% by the ethanol treatment. These results suggest that NADH acting via the outer membrane NADH reductase can catalyze an iron-dependent production of oxygen radicals by rat liver mitochondria. The outer mitochondrial membrane fraction, prepared by digitonin fractionation, displayed increased rotenone-insensitive NADH-cytochrome c reductase activity after ethanol treatment and was more reactive in catalyzing scission of pBR322 DNA from the supercoiled form to the open circular forms. Rates of oxygen radical production by mitochondria and the extent of increase produced by chronic ethanol treatment are similar to those previously found with microsomes when NADH is the cofactor. Oxidation of ethanol by alcohol dehydrogenase generates NADH, and NADH-dependent production of reactive oxygen species by various organelles is increased after chronic ethanol treatment. These acute metabolic interactions coupled to induction by chronic ethanol treatment may play an important role in the development of a state of oxidative stress in the liver by ethanol.     

Services and applications: requirements and realizations in theUMTS era

The ACTS program is moving the results of the R&D of the parent RACE program nearer to realization through technology and user trials. Particularly in the mobile domain of ACTS, several projects have been investigating the user dimension in the context of the third-generation Universal Mobile Telecommunications Service. Results so far suggest many opportunities to broaden participation, exploit the inherent benefits of the mobile environment, and take advantage of the enormous improvements in wireless communications to realize the potential of global multimedia mobility. This article considers the needs of users for mobile multimedia applications and the consequences of those needs on the equipment, supporting services and teleservices, and communications bearers     

The effect of spin fluctuations on thermal properties in strongly correlated fermion systems

The effect of spin fluctuations on the thermal properties of strongly correlated itinerant fermion systems is discussed based on the self-consistent renormalized (SCR) spin fluctuation model. Specific heat and magnetic susceptibility in the normal phase of liquid-³He and heavy electron compounds at finite temperatures are well described by the unified SCR picture including the mode-mode coupling of spin fluctuations beyond the random phase approximation (RPA).