船舶钢板激光弯曲成形的实验研究

在对船舶钢板激光弯曲成形过程进行实验研究中，采用CO2激光器研究了激光功率、扫描速度、扫描次数以及钢板厚度对船舶钢板激光弯曲成形的影响规律。实验中实时测量了船舶钢板激光弯曲成形过程钢板弯曲角度和温度的变化。结果表明：钢板弯曲角度随激光功率的增加而增加，随激光束扫描速度的增加而减小，而且随着钢板厚度的增加，弯曲角度减小；激光工艺参数和钢板厚度都对钢板激光多次扫描成形产生影响，钢板的弯曲角度随着激光扫描次数的增加而增加。对于较薄的船舶钢板，钢板弯曲角度随扫描次数增加近似呈线性增加，而较厚的钢板，随扫描次数的增加，钢板弯曲角度的增加逐渐减小。     

Effects of phosphorus addition on the magnetic properties of sintered Fe-50 wt.% Ni alloys

Phosphorus was added to Fe-50 wt.% Ni in the form of a coated composite powder via an electroless plating process. Addition of phosphorus to Fe-50 wt.% Ni facilitated increases in density and grain size, both of which were beneficial to magnetic performance. Because of the homogeneous distribution of phosphorus in the powder, the optimal phosphorus addition was much lower than for those using Fe₃P as the phosphorus precursor. The optimal phosphorus addition was close to its maximum solubility in Fe-50 wt.% Ni (about 0.5 wt.%), above which precipitation of excessive phosphorus in the form of iron nickel phosphide, (Fe,Ni)₃P, effectively degraded the magnetic properties of Fe-50 wt.% Ni. Without the addition of phosphorus, good magnetic properties could be achieved only when the sintering temperature was high enough (>1200 °C) to result in a high sintered density and large grains in the sintered structure.     

锐钛型TiO2对尿素热解过程的影响

通过实验的方法收集了不同温度下纯尿素和尿素/TiO₂混合物热解后的固体残留物，使用红外光谱（IR）及气相色谱质谱联机（GC-MS）方法对这些热解残留物进行成分分析；使用热重-红外联机（TG-FTIR）技术研究尿素及三聚氰酸在有无催化剂TiO₂的情况下的热解特性及气体产物的生成规律；根据Coats-Renfern方法对尿素热解第一阶段的非等温热失重率曲线的数据进行动力学研究，建立动力学方程。结果表明，100~250℃的尿素热解残留物中主要为尿素和缩二脲，300~400℃的尿素热解残留物中主要为三聚氰酸等含氮杂环有机化合物；锐钛型TiO₂能促进尿素和三聚氰酸的热解反应，缩短其反应进程，HNCO与水蒸气在TiO₂表面易发生反应；尿素第一阶段热解的反应级数为2，单独热解时活化能为113.25kJ/mol，指前因子A为2.01×10¹¹min^-1，在催化剂TiO₂的作用下，活化能E为77.42kJ/mol，指前因子A为4.82×10⁷min^-1。     

Evaluation of wastewater reclamation processes in a high-tech industrial park

The objectives of this research were to evaluate two different processes using for wastewater reclamation in a hightech industrial park area in Taiwan. The major units of the first AC-RO-IE system included sand filter, an activated carbon (AC) bed, microfiltration module, a reverse osmosis (RO) membrane and ionic-exchange (IE) columns. The second DAF-AC-RO system was comprised of coagulation/flocculation, dissolved air flotation (DAF), an activated carbon bed, microfiltration module and reverse osmosis membrane units. This study was carried out at a pilot-scale plant in situ that operated for approximately 1 year. According to the long-term experimental results, both the AC-RO-IE and the DAF-AC-RO processes illustrated excellent performances on inorganic and organic contaminant removal. Comparing the removal efficiency of the filtration-AC units in the AC-RO-IE system with the coagulation-DAF-AC units in the DAF-AC-RO system, the removal efficiency of TDS, SiO₂ and COD increased by 19.8%, 70.1% and 44.4% in the latter system, respectively. In addition, the combination of PAC-coagulation and DAF units could improve hardness removal, modify the form of dissolved silica, and reduce the SDI and MFI values. It showed good potential as a pretreatment unit in wastewater reclamation processes. Therefore, based on the reclaimed wastewater quality and process operational stability, the DAF-AC-RO system was suggested as a potential process for further application.     

石墨粉镀银新工艺研究

研究了镀液中硝酸银浓度、石墨粉加入量和阴极电流密度等工艺条件对镀银石墨粉含银量和电镀效果的影响。用扫描电镜对镀银石墨粉的微观形貌和镀覆效果进行分析，通过X射线衍射仪对镀银石墨粉高温灼烧后的剩余物进行分析测试并计算镀银石墨粉的含银量。研究结果表明：采用惰性电极作为电镀阳极，在化学镀预处理过的石墨粉表面可成功镀覆一层银，其含银量达76%。     

Synthesis of the Silver Nanofluid by ASNSS Process

Arc Spray Nanoparticle Synthesis System (ASNSS) has been used to prepare the silver nanofluids in this study. The metal electrodes under the electrical discharge will melt and evaporate rapidly and condense to form the nanoparticles in the dielectric fluid at lower temperature and produce the suspended nanoparticle fluid. Thus, the mechanism of the ASNSS process is superheating the electrodes by plasma to form metallic nuclei and supercooling these nuclei by dielectric liquid to produce nanofluid. This study considers the different controlling parameters such as discharge current,discharge voltage, pulse-duration time, electrode diameter, and the temperature of dielectric liquid. The optimally operated parameters can be obtained to produce the finer particle size in nanofluid. The results indicate the silver electrodes in alcohol fluid will produce the spherical nanosilver particles. The mean particle size of silver in different dielectric liquid temperatures of-40, -20, 0, and 10℃ is about13.4, 15.8, 17.5, and 21.6 nm, respectively. This indicates that the well suspended fluid can be obtained by controlling the lower dielectric fluid temperature.     

Effect of incipient removal of hydrogen through palladium membrane on the conversion of methane steam reforming: Experimental and modeling

This paper presents a mathematical model based on the reaction rate expressions to describe the displacement of methane conversion in the steam reforming. The effect of several parameters including weight hourly space velocity (WHSV), load-to-surface ratio, reaction pressure, hydrogen partial pressure in permeate side and reaction temperature were investigated. Simulation and experimental results showed that a conversion higher than 80% could be achieved in a palladium membrane reactor at reaction temperature of 500 °C relative to 850 °C in a conventional fixed bed reactor (FBR). Besides, the yield of CO (<2%) in membrane reactor was much lower than that (>50%) in the FBR, which indicated the significant depression of CO production in use of membrane reactor.     

图的b-边染色数及b-边连续性研究

图染色及色数问题是图论中的一个重要内容,也是图论中的一个十分活跃的领域,同时有着深刻而丰富的理论结果和广泛的实际应用,其理论和方法在离散数学中占有重要地位.本文在图的b-染色数和b-连续概念的基础上提出图的b-边染色数及b-边连续的概念,给出了路图、圈图以及满n叉树图的b-边染色数,并且证明了这些图都是b-边连续的.     

La对CH_4-CO_2重整反应催化剂性能的影响

采用等体积浸渍法制备了Ni/γ-Al2O3和Ni/La2O3-γ-Al2O3系列催化剂,通过固定床反应、热重分析等方法,考察了催化剂的性能。结果表明：Ni质量分数为10%的Ni/γ-Al2O3催化剂具有较高的活性;稀土元素La的加入,提高了催化剂的抗积炭性能;在相同的反应条件下,10%Ni/3%La2O3-γ-Al2O3催化剂的积炭量比10%Ni/γ-Al2O3催化剂积炭量降低了40%,稳定性大大提高。以Ni/La2O3-γ-Al2O3催化剂中Ni质量分数10%,并且La质量分数3%为最佳,实验条件下制得的合成气CO/H2接近1/1。     

Mass transfer modelling for GS heavy water plants: Part 1: Point efficiency on GS sieve trays

A model that takes into account the gas-phase and liquid-phase resistance to mass transfer has been developed, where the overall mass transfer coefficient (K_OGa) is expressed as a function of the equivalent Sauter-mean bubble diameter. This parameter was back calculated from mass transfer measurements made at a pilot plant on single pass sieve trays of 0.311 m diameter. Hydraulic parameters were measured for these trays as well. Mean bubble diameters were then correlated as a function of active area F-factor and dispersion height for various tray geometries, and these correlations are used to predict point efficiencies on production plant trays up to 8.5 m in diameter.