0D/2D Heterostructures Vertical Single Electron Transistor

Mixed-dimensional heterostructures formed by the stacking of 2D materials with nanostructures of distinct dimensionality constitute a new class of nanomaterials that offers multifunctionality that goes beyond those of single dimensional systems. An unexplored architecture of single electron transistor (SET) is developed that employs heterostructures made of nanoclusters (0D) grown on a 2D molybdenum disulfide (MoS₂) channel. Combining the large Coulomb energy of the nanoclusters with the electronic capabilities of the 2D layer, the concept of 0D–2D vertical SET is unveiled. The MoS₂ underneath serves both as a charge tunable channel interconnecting the electrode, and as bottom electrode for each v-SET cell. In addition, its atomic thickness makes it thinner than the Debye screening length, providing electric field transparency functionality that allows for an efficient electric back gate control of the nanoclusters charge state. The Coulomb diamond pattern characteristics of SET are reported, with specific doping dependent nonlinear features arising from the 0D/2D geometry that are elucidated by theoretical modeling. These results hold promise for multifunctional single electron device taking advantage of the versatility of the 2D materials library, with as example envisioned spintronics applications while coupling quantum dots to magnetic 2D material, or to ferroelectric layers for neuromorphic devices.     

About the allotropic transformations of PbSnF4

Microcalorimetric and dilatometric studies of PbSnF₄ give evidence of several allotropic forms for PbSnF₄. The complex thermal behaviour may be summarized as follows :

.The crystallographic data of the detected allotropic forms have been determined by investigations on single crystals. All structures derive from the fluorite-type. The obtained results confirm a previous work of the authors, new more precise techniques bringing further information.     

Development of new Cu0–ZnII/Al2O3 catalyst supported on copper metallic foam for the production of hydrogen by methanol steam reforming

Topics in Catalysis - Copper metallic foam with thermal conductive properties, manufactured by S.C.P.S., has been investigated as a support for catalysts to improve thermal exchange inside the...     

Influence of Porosity on Friction and Wear of Tetragonal Zirconia Polycrystal

Sliding wear properties of ultra-fine-grained (180 nm) yttria-doped tetragonal zirconia (Y-TZP) ceramics were examined with porosities from 1.5% to 7%. On a pin-on-plate tribometer under dry-N₂ conditions, e.g., wear rates of the material increase by a factor of 5 by increasing porosity with a factor of 5 (from 1.5 to 7.0 vol%). In all cases no (irreversible) phase transformation to monoclinic zirconia took place during wear tests. The results for the relatively dense nanostructured materials showed significant evidence of plastic deformation and less microcrack formation. The morphology of the wear tracks in these ceramics indicate that the degree and amount of microcracks on the contact surface increased with porosity. A change in wear mechanism is observed.     

Synthesis and properties of a new polyether ketone

Summary A new polyether ketone has been synthesized (via addition polymerization) by reacting N,N-bispropargyl-4,4-diaminobenzophenone and Bisphenol A. The polymer is soluble in both polar and ketonic solvents. The inherent viscosity data indicates the molecular weight of the polymer to be low and thermogravimetric analysis suggests it to be a fairly thermostable polymer.     

Reducibility of supported gold (III) precursors: influence of the metal oxide support and consequences for CO oxidation activity

The origin of CO oxidation performance variations between three different supported Au catalysts (Au/CeO₂, Au/Al₂O₃, Au/TiO₂) was examined by in situ XAFS and DRIFTS measurements. All samples were prepared identically, by deposition-precipitation of an aqueous Au(III) complex with urea, and contained the same gold loading (~1 wt %). The as-prepared supported Au(III) precursors exhibited different reduction behaviour during exposure to the CO/O₂/He reaction mixture at 298 K. The reducibility of the Au(III) precursor was found to decrease as a function of the support material in the order: titania > ceria > alumina. The as-prepared samples were inactive catalysts, but Au/TiO₂ and Au/CeO₂ developed catalytic activity as the reduction of Au(III) to metallic Au proceeded. Au/Al₂O₃ remained inactive. The developed catalytic CO oxidation activity at 298 K varied as a function of the support as follows: titania > ceria > alumina ~ 0. The EXAFS of samples pretreated in air at 773 K and in H₂ at 573 K reveals the presence of only metallic particles for Au/TiO₂ and Au/Al₂O₃. Au(III) supported on CeO₂ remains unreduced after calcination, but reduces during the treatment with H₂. CO oxidation experiments performed at 298 K with the activated samples show that the presence of metallic gold is necessary to obtain active catalysts (Au/CeO₂ is not active after calcination) and that the reducible supports facilitate the genesis of active catalysts, while metallic gold particles on alumina are not active.     

Effect of Calcination on the Sintering of Gel-Derived, Zirconia-Toughened Alumina

The densification behavior of ZrO₂ (+ 3 mol% Y₂O₃)/85 wt% Al₂O₃ powder compacts, prepared by the hydrolysis of metal chlorides, can be characterized by a transition- and an α-alumina densification stage. The sintering behavior is strongly determined by the densification of the transition alumina aggregates. Intra-aggregate porosity, resulting from calcination at 800°C, partly persists during sintering and alumina phase transformation and negatively influences further macroscopic densification. Calcination at 1200°C, however, densifies the transition alumina aggregates prior to sintering and enables densification to almost full density (96%) within 2 h at 1450°C, thus obtaining a microstructure with an alumina and a zirconia grain size of 1 μm and 0.3–0.4 μm, respectively.     

Microstructure-based multiscale modeling of elevated temperature deformation in aluminum alloys

A multiscale model for predicting elevated temperature deformation in Al–Mg alloys is presented. Constitutive models are generated from a theoretical methodology and used to investigate the effects of grain size on formability. Flow data are computed with a polycrystalline, microstructure-based model which accounts for grain boundary sliding, stress-induced diffusion, and dislocation creep. Favorable agreement is found between the computed flow data and elevated temperature tensile measurements. A creep constitutive model is then fit to the computed flow data and used in finite-element simulations of two simple gas pressure forming processes, where favorable results are observed. These results are fully consistent with gas pressure forming experiments, and suggest a greater role for constitutive models, derived largely from theoretical methodologies, in the design of Al alloys with enhanced elevated temperature formability. The methodology detailed herein provides a framework for incorporation of results from atomistic-scale models of dislocation creep and diffusion.     

New approach to gas pressure profile prediction for high temperature AA5083 sheet forming

A new theoretical approach to the prediction of gas pressure profiles that vary smoothly with time in high temperature forming of fine-grained AA5083 sheet is presented. The required pressure-flow stress relationship, which couples the gas pressure profile and the material constitutive model, was implemented in ABAQUS implicit. Forming of a rectangular pan in a die with variable entry radii was simulated with a single creep mechanism model that accounts for hardening/softening in AA5083. Predicted sheet thickness and thinning in a die entry radius region at the end of forming are examined in detail. Results are compared with those from two additional gas pressure schemes. One of these is taken directly from experiments and the other is based upon an algorithm that is internal to ABAQUS. The effect of friction on forming time is explored in the absence of a stability criterion for necking.