Application of K2CO3 catalysts in the coal gasification process using nuclear heat

Conventional gasification processes use coal not only as feedstock to be gasified but also for supply of energy for reaction heat, steam production, and other purposes. With a nuclear high temperature reactor (HTR) as a source for process heat, it is possible to transform the whole of the coal feed into gas. This concept offers advantages over existing gasification processes: saving of coal, as more gas can be produced from coal; less emission of pollutants, as the HTR is used for the production of steam and electricity instead of a coal-fired boiler; and a lower production cost for the gas. However, the process has the disadvantage that the temperature is limited to the outlet temperature (950 °C max) of the helium cooling gas of the HTR. Therefore the possibility of catalytic steam gasification was examined. Model calculations based on experimental results show that use of 3–4 wt% relative to coal of K²CO³ catalyst increases the throughput of a large scale nuclear gasification plant by ≈65%, while gas production costs decrease by ≈15%. Corrosion by catalysts is not significant at low concentration (< 5 wt%) and low temperature (< 900 °C).     

Compatibilization of inorganic particles for polymeric nanocomposites. Optimization of the size and the compatibility of ZnO particles

Summary The synthesis of in-situ hydrophobic functionalized ZnO nanoparticles via an emulsion process is systematically investigated. Different parameters are varied, such as precursor salt concentration and ultrasonification, to optimize the size and the size distribution of the ZnO particles. Particles with a size below 25 nm and surrounded by a hydrophobic polymer shell can be easily obtained. The influence of the polymeric shell on the compatibility with different polymeric matrices is described. Due to the small size of the inorganic particles and the excellent hydrophobization, highly transparent inorganic/organic nanocomposites can be obtained by spin-coating and extrusion.     

Gewissensfreiheit in der Apotheke

Background In recent years, it has been intensively debated whether and how the conscience must be protected in the context of pharmacies. Currently, Germany and Austria have no legal regulation regarding this problem. Objective The ethical framework for a coping strategy dealing with the problem of freedom of conscience in the pharmacy will be outlined. Method By applying legal ethics' principle of proportionality within German and Austrian constitutional law as well as the European Convention on Human Rights, the problem is analyzed on its individual, corporative, and societal level. Results On the individual level, the pharmacist's and the patient's stakes and rights (e.g., the freedom of conscience) are carefully balanced by using the principle of proportionality. On the corporative level, the autonomy granted by the fundamental right of freedom of religion and belief legitimatizes a pharmacy's ideological profile as an organization and may cause conflicts of loyalty within the pharmacy. On the societal level, four pro-active options of shaping the legal framework are available: a social-welfare, a libertarian, a professional, and a communitarian. How conflicts on the individual or the corporative level can be solved depends on the option(s) that are chosen on the societal level. Conclusion If the status quo is to be changed, this article argues for two approaches: a) the introduction of a qualified conscience clause for pharmacists (including duties to consult, refer, treat in emergencies, and inform); b) a ‘weak’ communitarian option, striving for a compromise between a pharmaceutical corporation (i.e., pharmacy or pharmaceutical professional association) with an ideological profile and the public healthcare system. Both approaches satisfy a careful balancing of legitimate goods.     

Oligomerization of phenyl glycidyl ether in the presence of ZnCl2

Summary In the presence of ZnCl₂ phenyl glycidyl ether reacts to different products owing to the ring-opening reaction of the oxirane and the cleavage of the ether bond. Using HPLC and offline mass spectrometry most of the reaction products could be identified.A reaction scheme and the supposed reaction mechanism were described involving the formation of chlorine — containing oligomers and low molecular weight by — products resulting from the cleavage of the ether bond of the monomer. Conclusions were drawn for original polyfunctional epoxy resin systems.     

In situ esterification of rice bran oil with methanol and ethanol

In situ esterifications of high-acidity rice bran oil with methanol and ethanol and with sulfuric acid as catalyst were investigated. In the esterification with methanol, all free fatty acids (FFA) dissolved in methanol were interesterified within 15 min, and it was possible to obtain nearly pure methyl esters. The amount of methyl esters obtained from a given rice bran was dependent on the FFA content of the rice bran oil. In the esterification with ethanol, it was not possible to obtain pure esters as in methanol esterification, because the solubilities of oil components in ethanol were much higher than those in methanol.     

Transverse mixing and heat transfer in horizontal rotary drum reactors

The transverse mixing of quartz sand (mean particle sizes 157, 323, 794 and 1038 μm) and sodium carbonate (soda) (mean particle size 137 μm) has been investigated in a laboratory rotary drum reactor of 300 mm length and 310 mm diam. Solid movement in the drum was observed by means of colored tracers and successive exposures as well as by means of hot tracers and recording the local temperature in the bulk of particles. Three different types of the particles and bulk behaviour could be observed for stickly particles. The time constant of the mixing was estimated as a function of the rotational speed of the drum. The “cooling-down” curves of the bulk of particles were measured in a laboratory oven of 250 mm diam. and 600 mm length. The temperature variation as a function of the time can be described by the Newtonian cooling law, from which the heat transfer coefficient at the wall α_w was estimated.The absolute value of α_w's and their dependence on the contact time and particle diameter cannot be calculated by the heat penetration model, which disregards the film resistance at the bulk/wall contact. By taking into account this resistance a good quality of fitting can be achieved.     

Perceptually enhanced blind single-channel music source separation by Non-negative Matrix Factorization

We propose a new approach that improves perceptual quality of the separated sources in blind single-channel musical source separation. It uses the advantages of subspace learning based on Non-negative Matrix Factorization (NMF) in which the bases represent the notes. The cost function is formulated in the form of weighted β-divergence by adopting the PEAQ auditory model defined in ITU-R BS.1387 into the source separation. The proposed perceptually weighted factorization scheme is integrated into the Non-negative Matrix Factor 2-D Deconvolution (NMF2D) and Clustered Non-negative Matrix Factorization (CNMF) to overcome the source clustering problem encountered in under-determined source separation. It is shown that the introduced perceptually weighted NMF schemes, named as PW-NMF2D and PW-CNMF, efficiently learn the bases that enable us to apply a simple resynthesis of the musical sources based on the temporal model stored in the encoding matrix. Source separation performance has been reported on musical mixtures where 1–2 dB improvement is achieved in terms of SDR, SIR and SAR compared to the state-of-the-art methods. Performance has also been evaluated by perceptual measures resulting an improvement of 2–5 in OPS, TPS, IPS and APS values.     

Developments in micro-electron beam welding

At the ISF (Joining and Welding Institute, RWTH Aachen University) the long-established electron beam (EB) welding process is investigated to meet the requirements of the field of micro-applications. A modified LEO ZEISS DSM 962 scanning electron microscope (SEM) is being used as a Micro-EB welding machine. The diameter of the beam in welding mode is about 20 μm, with a maximum beam power of 6 Watt at 30 kV acceleration voltage. The process-specific advantages, such as the inertia-free movement of the tool electron beam, the very small beam diameter, the clean room environment which is due to processing in a vacuum (no shielding gas needed) and the excellent applicability for visual quality control offer the best preconditions for hybrid micro-assembly purposes. If the technology is down-scaled to a micro-level, physical effects occur whose consequences must be met with new approaches of solution. Joining of micro-components presupposes optimal contact conditions. If the micro-components are of a flexible type, those optimal conditions are difficult to implement. The ratio of forces during the joining process and also the low stiffness of the components which is due to the small dimensions require, on the one hand, the application of a suitable handling technique or, on the other hand, a specific beam manipulation strategy. Especially in the field of micro-applications, the possibility to exert influence on the thermal distortion by symmetrical heating and solidification processes is of particular importance. Therefore, the reproducibility of the welded joints is one of the great challenges in the field of microwelding. The investigations and developments done at the ISF show successful results in joining stainless steel sheet materials down to 30 μm thickness and steel wire down to 50 μm in diameter, whereas other materials (Tungsten, Aluminum, Titanium, Nickel) are under investigation.     

Hand and foot purpura ("glove and sock" syndrome) caused by parvovirus B19 infection

After a period of general nonspecific symptoms (weakness; nocturnal sweating) for a few days a 29-year-old man suddenly developed a purpura-like rash on both hands and feet ("glove and sock") with mild itching and oedema. A blood count demonstrated leukopenia (2100/microliters) with neutropenia (1100/microliters), thrombocytopenia (81,000/microliters) and reticulocytopenia (1/1000), while haemoglobin content was normal. The bone-marrow showed almost complete reduction of erythropoiesis with the presence of giant proerythroblasts. Granulopoiesis and megakaryopoiesis were unremarkable. Positive tests for IgM and IgG antibodies against parvovirus B19 established the diagnosis of infection with this organism. The rash, blood picture and bone-marrow changes all regressed spontaneously, without any treatment, within a week. The petechial or purpuric "glove and sock" syndrome may be a special form of parvovirus B19 infection.