n-Channel Si-gate process for MNOS EEPROM transistors

An n-channel Si-gate process has been developed to fabricate MNOS EEPROM transistors and fast logic circuits on one chip. The technology proposed involves low thermal oxidation temperatures ≤900°C after nitride deposition, two LOCOS process steps and application of self-aligned overlapped poly-Si contacts. The MNOS memory transistors obtained have been programmed by ±25 V pulses with a write time of t_w = 10 ms and an erase time of t_e = 100 ms.The retention data have been found to be dependent on nitride thickness and threshold voltage shift, but independent of channel length and channel doping. For devices with a nitride thickness of 30.5 nm the short-term decay rate of 0.6 V/(decade of time) has been determined. Endurance testing using up to 10⁷ pulses of ±25 V, 100 μs corresponding to approx. 10⁴ write/erase cycles showed no time dependence for the decay rate over the time of 10⁵ min in which retention measurements were made.     

Rolling-Contact Studies with Four Refractory Materials to 2000 F

Four refractory materials were tested in the five-ball fatigue tester to study their behavior under repeated stresses applied in rolling contact: hot-pressed alumina, cold-pressed-and-sintered alumina, self-bonded silicon carbide, and nickel-bonded titanium carbide cermet. The failures that developed in all four materials were shallow, eroded areas of apparent surface origin unlike fatigue spalls found in bearing steels. The load capacity of hot-pressed alumina was the highest of the four materials tested but was only about 7% of that of a typical bearing steel. Preliminary tests at elevated temperatures indicated that hot-pressed alumina is capable of rolling-contact operation at temperatures up to 2000 F without gross wear or plastic deformation.     

Fixed-structure discrete-time H 2 / H ∞ controller synthesis using the delta operator

This paper considers the fixed-structure, discrete-time mixed H 2 / H X controller synthesis problem in the delta operator (difference operator) framework. The differential operator and shift operator versions of the problem are reviewed for comparison, and necessary conditions are derived for all three formulations. A quasi-Newton/continuation algorithm is then used to obtain approximate solutions to these equations. Controllers are synthesized for two numerical examples, and the performance of the algorithm on the differential, difference and shift operator versions of the problems is compared.     

One‐Step Fast Synthesis of Li4Ti5O12 Particles Using an Atmospheric Pressure Plasma Jet

A one‐step process to fabricate crystalline Li₄Ti₅O₁₂(LTO) particles directly from solution using an atmospheric pressure plasma jet (APPJ) is reported. This process uses Ti and Li ions‐containing salt solutions as the precursor, which is ultrasonically nebulized and then transported to the downstream of the APPJ using a carrier gas. With an extremely short contact time (<0.1 s) between the precursor droplets and the plasma jet, crystalline LTO can be fabricated in one step without additional rinse and postannealing steps. The LTO particle size can be effectively controlled using a preheater, the precursor solution composition and concentration, and the carrier gas flow rate. By properly adjusting the operating condition, particles of diameters from 100 nm to few μm with various morphologies can be obtained. When used as an electrode material, the resulting LTO powders fabricated under selected conditions show specific capacities over 100 mAh/g even at 50 C rate.     

Rolling Bearing Service Life Based on Probable Cause for Removal—A Tutorial

In 1947 and 1952 G. Lundberg and A. Palmgren developed what is now referred to as the Lundberg-Palmgren model for rolling bearing life prediction based on classical rolling-element fatigue. Today, bearing fatigue probably accounts for less than 5% of bearings removed from service for cause. A bearing service life prediction methodology and tutorial indexed to eight probable causes for bearing removal, including fatigue, are presented that incorporate strict series reliability; Weibull statistical analysis; available published field data from the Naval Air Rework Facility; and ～224,000 rolling-element bearings removed for rework from commercial aircraft engines. Bearing service life L_serv can be benchmarked and calculated to the bearing L₁₀ fatigue life as follows: L_serv = X^1/m L₁₀, where X is the number of bearings removed from service because of fatigue divided by the total of all bearings removed from service regardless of cause and m is the Weibull modulus of the bearings removed from service. The most conservative bearing L₁₀ service life calculation is obtained assuming an exponential distribution where m = 1.1. Of the ～224,000 commercial engine bearings removed from service for rework, 1,977 or 0.88% were rejected because of fatigue. From the Naval Air Rework Facility bearing data, eliminating rolling–element fatigue as a cause for removal, the L₁₀ service life of these bearings would increase by approximately 3%.     

The isotopic distribution conundrum

Although access to high-resolution mass spectrometry (MS), especially in the field of biomolecular MS, is becoming readily available due to recent advances in MS technology, the accompanied information on isotopic distribution in high-resolution spectra is not used at its full potential, mainly because of lack of knowledge and/or awareness. In this review, we give an insight into the practical problems related to calculating the isotopic distribution for large biomolecules, and present an overview of methods for the calculation of the isotopic distribution. We discuss the key events that triggered the development of various algorithms and explain the rationale of how and why the various isotopic-distribution calculations were performed. The review is focused around the developmental stages as briefly outlined below, starting with the first observation of an isotopic distribution. The observations of Beynon in the field of organic MS that chlorine appeared in a mass spectrum as two variants with odds 3:1 lie at the basis of the first wave of algorithms for the calculation of the isotopic distribution, based on the atomic composition of a molecule. From here on, we explain why more complex biomolecules such as peptides exhibit a highly complex isotope pattern when assayed by MS, and we discuss how combinatorial difficulties complicate the calculation of the isotopic distribution on computers. For this purpose, we highlight three methods, which were introduced in the 1980s. These are the stepwise procedure introduced by Kubinyi, the polynomial expansion from Brownawell and Fillippo, and the multinomial expansion from Yergey. The next development was instigated by Rockwood, who suggested to decompose the isotopic distribution in terms of their nucleon count instead of the exact mass. In this respect, we could claim that the term "aggregated" isotopic distribution is more appropriate. Due to the simplification of the isotopic distribution to its aggregated counterpart, Rockwood was able to use the convolution for the calculation of the "aggregated" isotopic distribution. Convolution methods are computationally efficient and economic in their memory usage. We spend a section on the work introduced by Rockwood during the 1990s. Due to recent breakthroughs in mass spectrometric technology and the widespread high-resolution instruments (e.g., FTICR-MS, FTOrbitrap-MS, and TOF-MS) that provide high-resolution, isotope-resolved, accurate mass data, there is an emerging need for algorithms that can calculate isotopic distributions for large biomolecules. The number of recent publications on this topic does witness this trend. The new methods are mostly based on complex mathematical developments such as, for example, cellular automata (Meija and Caruso [2004]. J Am Soc Mass Spectrom, 15(5):654-658), dynamic programming (Snider [2007]. J Am Soc Mass Spectrom, 18:1511-1515), and hierarchical models (Li et al. [2008] J Am Soc Mass Spectrom, 19:1867-1874). We also comment on the ideas to use Punnet squares and Pascal's triangle to introduce the concept of the isotopic distribution for educational and didactic purposes.     

Validation of a supervisory control system for energy savings in membrane bioreactors

The application of fixed operational protocols and settings for membrane bioreactors (MBR) often leads to suboptimal filtration conditions due to the dynamic nature of mixed liquor characteristics. With regard to process optimization and energy savings, the potential benefits of a dynamic control system, enabling to adapt fouling control actions (ACS outputs) in an automated way to the actual mixed liquor fouling propensity, are thus obvious. In this paper, the pilot-scale validation of such an advanced control system (ACS) is elaborated. A specific on-line fouling measurement method, the MBR-VFM (VITO Fouling Measurement), was used for the evaluation of the mixed liquor’s reversible fouling propensity, which was used as a primary ACS input parameter. A first series of tests with a gradual increase in complexity of the selected input and output parameters indicated the functionality of the ACS and demonstrated a substantial reduction of aeration, however sometimes at the expense of a higher fouling rate. The ACS was further fine-tuned and subsequently tested for a longer period under more dynamic operating conditions. A significant correlation was found between the reversible fouling potential measured by the MBR-VFM and the on-line permeability, indicating that the MBR-VFM is a suitable ACS input. Furthermore, an average 22% reduction in aeration flow to the membranes could be achieved without any obvious negative effect on filtration performance. This indicates that this approach is promising to optimize energy consumption in MBRs.     

‘Land for infrastructure’ in Ho Chi Minh City: land-based financing of transportation improvement

This paper explores how land-based financing mechanisms are currently used in Ho Chi Minh City as a public-private funding strategy. The Land-for-Infrastructure (LFI) mechanism appears as a solution to produce infrastructures. We found that the implementation of the LFI mechanism remains difficult, but eventually can lead to success. By ‘trial-error-transcend,’ the City managed to build two essential roads while the developers received attractive investment opportunities in urban development. This mechanism cannot, however, be seen as a panacea for the local authorities due to constraints to replicate it and potential undesired ‘side effects.’     

Measurement of birefringence for optical recording of disk substrates

We experimentally investigate the birefringence of bare and coated substrates for magneto-optical recording, using ellipsometry at wavelengths of 632.8 and 780 nm. The polarization rotation and ellipticity of reflected or transmitted light are measured for different incident angles and for different orientations of the incident linear polarization. The measured data are then fitted by the MULTILAYER computer program, which solves the Maxwell equations for a plane wave propagating in a multilayer structure. This approach makes it possible to determine, with high accuracy, the orientations of the principal axes of the substrate and the corresponding refractive indices. The results show that one of the principal axes is always along the substrate's normal direction, but the orientations of the in-plane principal axes can be much different from the radial and track directions. A special feature of the ellipsometers that were used is that a glass hemisphere is placed in contact with the substrate to eliminate refraction of the incident beam. This enables a maximum propagation angle of 70° (with respect to the normal) in the substrate and hence increases the measurement sensitivity. Certain anomalies have been observed, which we believe are associated with the variation of birefringence properties along the thickness direction.