Effect of precyclic loading on stress-corrosion-cracking initiation in an X-65 pipeline steel exposed to near-neutral pH soil environment

A study was carried out to understand the effect of precyclic loading on stress-corrosion-crack initiation in an X-65 pipeline steel exposed to a near-neutral-pH soil environment. The test specimens were precyclically loaded before corrosion exposure to represent a service history of up to about 20 years, depending on the severity of pressure fluctuation. Microcracks had initiated on the polished surface of the X-65 pipeline steel after long-time exposure at open-circuit potential (OCP) in a near-neutral-pH synthetic soil solution. These microcracks were mostly initiated from pits at metallurgical discontinuities such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed along planes of the banded structures in the steel. The selective corrosion attack at these metallurgical discontinuities is attributed to the galvanic nature of those areas to their neighbors. Cyclic loading prior to corrosion exposure had significant effects on microcrack initiation and propagation during subsequent corrosion exposure. Cyclic loading prior to corrosion exposure either reduced or increased the probability of crack initiation and the rate of crack propagation, depending upon the magnitude of the stress cycles. The largest reduction was seen at a peak cyclic stress of about 0.8 of the yield strength. This cyclic-loading-dependent cracking behavior might be related to the alteration of the substructures and the residual stress in the steel as a result of precyclic loading.     

Narcissism, sexual refusal, and aggression: Testing a narcissistic reactance model of sexual coercion.

Laboratory analog studies investigated the theory that narcissism and reactance contribute to causing rape. In Study 1, narcissism correlated positively with rape-supportive beliefs and negatively with empathy for rape victims. In Study 2, narcissists reported more enjoyment than other men of film depictions that presented consensual, affectionate activity followed by rape (but not in response to either affection or rape alone). In Study 3, narcissists were more punitive than other men toward a female confederate who refused to read a sexually arousing passage aloud to them. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Metal-containing intermacromolecular complexes: Electrochemical and viscometric studies in DMF-methanol mixture

Summary Multicomponent intermacromolecular complexes have been prepared from some typical phenolic copolymers with a non-ionic polymer (e.g. PVP), and a polyelectrolyte (e.g. PAA). Some transition metal ions (e.g. Cu(II) and Ni (II)) have been incorporated in the complex through its unreacted co-ordinating groups. The formation of these complexes has been studied by several techniques, such as viscometry, conductometry, potentiometry, IR and UV spectrophotometry. A scheme has been presented to explain the mode of interaction of the various components.     

SURFACE ALLOYING OF MILD STEEL BY LASER MELTING OF AN ELECTROLESS NICKEL DEPOSIT CONTAINING CHROMIUM CARBIDES

It is possible to realize surface alloys by laser melting an electroless nickel layer containing chromium carbide particles predeposited on a mild steel substrate. By this way the surface alloy is expected to have not only a high nickel content but also an important chromium content in order to improve the corrosion resistance. The presence of chromium in solid solution results from the dissolution or melting of the carbide particles. Typical laser solidification microstructures are obtained. Dendrites consist of an austenitic Fe-Ni-Cr solid solution and interdendritic regions are constituted by an eutectic mixture containing the same austenitic solid solution and complex Fe, Ni, Cr carbides and phosphides. In comparison with a surface alloy obtained by laser melting of an electroless nickel layer without carbide particles, the corrosion resistance was slightly improved in saline aqueous solutions. The limited effect was due to the fact that the final chromium content in the present experimental conditions was not as high as that initially expected.     

Improved HF modem using convolutional coding

The paper describes the design of a digitally implemented modem for use over HF (2-30 MHz) radio channels. As a completely digital approach offers the prospect of a number of significant improvements, a new digital multifrequency-shift-keying (MFSK) modem has been developed that employs a novel digital processing procedure termed code-assisted bit synchronisation (CABS). Signal detection is achieved via a set of noncoherent correlators, whilst symbol synchronisation and error correction are performed using a soft-decision Viterbi decoder. Practical tests of modem show that it operates effectively under both additive white Gaussian noise and real HF channel conditions     

Effect of magnesium content on the ageing behaviour of water-chilled Al-Si-Cu-Mg-Fe-Mn (380) alloy castings

A study of the effect of magnesium concentration on the ageing behaviour as measured by the hardness of 380 alloy was conducted for three levels of magnesium, namely 0.06 (base alloy), 0.33 and 0.5 wt%, for water-chilled castings (dendrite arm spacing ∼ 10–15 μm). Differential scanning calorimetry analysis of as-cast samples was carried out to determine the changes in the reactions of the phases obtained during alloy solidification, employing heating rates of 0.1 and 1.0°Cs⁻¹, up to approximately 700°C. Two heat treatments were applied to the as-cast alloys: T5 comprising ageing at 25 (room temperature), 155, 180, 200 and 220°C, for times up to 200 h, and T6 comprising solution heat treatment at 480 °C or 515°C for 8 h, followed by quenching in warm water at 60°C, followed by immediate artificial ageing at 155 or 180°C for varying times up to 100h. The results show that the higher hardness values obtained with T6 treatment can be explained by the excess precipitation of magnesium-containing phases in the as-solidified alloys. This precipitation could be eliminated under the high cooling-rate conditions prevalent in die-casting operations so that T5 treatment may be used to replace T6 treatment to produce the same hardness values. In addition, solution heat treatment in the low-temperature range (480–515°C) is adequate to produce the required changes in silicon morphology and dissolution of magnesium in the matrix. No significant difference in hardness behaviour was observed when the magnesium content was increased beyond 0.3 wt%.     

The visual control of reaching and grasping: Binocular disparity and motion parallax.

The primary visual sources of depth and size information are binocular cues and motion parallax. Here, the authors determine the efficacy of these cues to control prehension by presenting them in isolation from other visual cues. When only binocular cues were available, reaches showed normal scaling of the transport and grasp components with object distance and size. However, when only motion parallax was available, only the transpont component scaled reliably. No additional increase in scaling was found when both cues were available simultaneously. Therefore, although equivalent information is available from binocular and motion parallax information, the latter may be of relatively limited use for the control of the grasp. Binocular disparity appears selectively important for the control of the grasp. (PsycINFO Database Record (c) 2010 APA, all rights reserved)